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Reactions of 9,10-phenanthrenequinone and its nitro derivatives with acetone in the presence of Al2O3
Authors:Linko  R V  Belsky  V K  Varlamov  A V  Zaitsev  B E  Chernyshev  A I
Institution:(1) Russian University of People"s Friendship, 6 ul. Miklukho-Maklaya, 117198 Moscow, Russian Federation;(2) State Research Center of the Russian Federation ldquoL. Ya. Karpov Research Physicochemical Institute,rdquo, 10 ul. Vorontsovo Pole, 103064 Moscow, Russian Federation
Abstract:The addition of acetone to 9,10-phenanthrenequinone and 2-nitro-, 2,7-dinitro-, and 2,4,7-trinitro-9,10-phenanthrenequinones in the presence of Al2O3 affords mono- and bisadducts. The crystal structures of 10-hydroxy-10-(2-oxopropyl)-2-nitro-9,10-dihydrophenanthren-9-one and 9,10Prime:10,9Prime-bishemiketal of 9,10-dihydroxy-2-nitro-9,10-bis(2-oxopropyl)-9,10-dihydrophenanthrene were determined.
Keywords:9  10-phenanthrenequinone  nitro-9  10-phenanthrenequinones  10-hydroxy-10-(2-oxopropyl)-9  10-dihydrophenanthren-9-ones  (9  10-dihydroxy)nitro-9  10-bis(2-oxopropyl)-9  10-dihydrophenanthrenes  9  10Prime:10" target="_blank">gif" alt="Prime" align="MIDDLE" BORDER="0">:10  9Prime-bishemiketals" target="_blank">gif" alt="Prime" align="MIDDLE" BORDER="0">-bishemiketals  acetone  alumina  X-ray diffraction analysis  IR spectroscopy  1Í  NMR spectroscopy
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