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Polymerization under a magnetic field. VI. Triplet dye-sensitized photopolymerization of acrylamide and methyl methacrylate
Authors:Dibyendu S Bag  Sukumar Maiti
Abstract:Methylene blue sensitized photopolymerization of acrylamide (AM) and methyl methacrylate (MMA) using triethanolamine or the sodium salt of EDTA as a reducing agent has been investigated under the influence of a magnetic field (0–7.3 kG). There was no effect of the magnetic field (MF) on the polymerization of AM and MMA in aqueous medium. However, in the water–methanol mixture (1 : 1) the yield of polymer decreases and the molecular weight increases in both cases under MF. This has been explained on the basis of the triplet mechanism. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 1509–1513, 1998
Keywords:methylene blue  dye-sensitized photopolymerization  magnetic field  triplet state  acrylamide  methyl methacrylate
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