Novel organic–inorganic hybrid materials from renewable resources: Hydrosilylation of fatty acid derivatives |
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Authors: | G Lligadas L Callau J C Ronda M Gali V Cdiz |
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Institution: | G. Lligadas,L. Callau,J. C. Ronda,M. Galià,V. Cádiz |
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Abstract: | Novel hybrid organic–inorganic materials were prepared from 10‐undecenoyl triglyceride and methyl 3,4,5‐tris(10‐undecenoyloxy)benzoate via hydrosilylation. 1,4‐Bis(dimethylsilyl)benzene, tetrakis(dimethylsilyloxy)silane, and 2,4,6,8‐tetramethylcyclotetrasiloxane were used as crosslinkers. The hydrosilylation reaction was catalyzed by Karstedt's catalyst Pt(0)–divinyltetramethyldisiloxane complex]. The networks were structurally characterized by Fourier transform infrared spectroscopy, 13C NMR, and 29Si magic‐angle‐spinning NMR. The thermal properties of these hybrids were studied with differential scanning calorimetry, thermogravimetric analysis, and dynamic mechanical analysis. The obtained materials showed good transparency and promising properties for optical applications. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 6295–6307, 2005 |
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Keywords: | crosslinking heteroatom‐containing polymers renewable resources |
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