| 镧系离子同乙酰水杨酸和1,10-二氮杂菲三元配合物的研究 |
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| 引用本文： | 牛选军,钱博,高改玲,王立达,成淑英.镧系离子同乙酰水杨酸和1,10-二氮杂菲三元配合物的研究[J].无机化学学报,1994,10(1):97-99. |
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| 作者姓名： | 牛选军 钱博 高改玲 王立达 成淑英 |
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| 作者单位： | 陕西师范大学化学系, 西安, 710062,陕西师范大学化学系, 西安, 710062,陕西师范大学化学系, 西安, 710062,陕西师范大学化学系, 西安, 710062,陕西师范大学化学系, 西安, 710062 |
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| 摘 要： | 合成了镧系离子（Ｌｎ＾３＋）同乙酰水杨酸（Ａｓａ）和１．１０－二氮杂菲（Ｐｈｅｎ）的三元配合物并确定其组成为Ｌｎ（ａｓａｌ）３·ｐｈｅｎ。考查了三元配合物的红外光谱、热稳定性和溶解性及其乙醇－水溶液的电子光谱和荧光光谱。
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| 关 键 词： | 乙酰水杨酸 络合物 稀土金属 |
| 收稿时间： | 1/7/1993 12:00:00 AM |
STUDY ON TERNARY CooRDINATION COMPOUNDS OF LANTHANIDES WITH ACETYLSALICYLIC ACID AND o-PHENANTHROLINE |
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| Niu Xuanjun,Qian Bo,Gao Gailing,Wang Lida and Cheng Shuying.STUDY ON TERNARY CooRDINATION COMPOUNDS OF LANTHANIDES WITH ACETYLSALICYLIC ACID AND o-PHENANTHROLINE[J].Chinese Journal of Inorganic Chemistry,1994,10(1):97-99. |
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| Authors: | Niu Xuanjun Qian Bo Gao Gailing Wang Lida and Cheng Shuying |
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| Institution: | Department of Chemistry, Shanxi Normal University, Xian, 710062,Department of Chemistry, Shanxi Normal University, Xian, 710062,Department of Chemistry, Shanxi Normal University, Xian, 710062,Department of Chemistry, Shanxi Normal University, Xian, 710062 and Department of Chemistry, Shanxi Normal University, Xian, 710062 |
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| Abstract: | He solid state ternary coordination compounds of lanthanides with acetylsalicylic acid(Asal) and o-phenanthroline (Phen) have been synthesized. The composition of thecoordination compounds determined by spectrophotometry and clemental analysis is Ln(asal)3. phen, where Ln stands for La, Co, Pr, Nd, Sm, Eu. The electronic absorption spectraof Nd3+, Ho3+ and Er3+ with Asal and Phen were investigated in ethanolic-water solvent system. The fluorescence spectra, infrared spectra, thermostability and solubility of thecoordination compounds were studied also. |
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| Keywords: | acetylsalicylic acid o-phenanthroline coordination compound of lanthanou hypersensitive transition |
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