| In[(C2H5O)2PS2]3配合物的合成及晶体结构研究 |
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| 引用本文： | 刘兴芝,薛红,赵瑾,宋玉林,臧树良.In[(C2H5O)2PS2]3配合物的合成及晶体结构研究[J].高等学校化学学报,1999,20(2):196-198. |
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| 作者姓名： | 刘兴芝 薛红 赵瑾 宋玉林 臧树良 |
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| 作者单位： | 辽宁大学稀散元素化学研究所, 沈阳 110036 |
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| 基金项目： | 辽宁省教育委员会基金,辽宁省科委基金 |
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| 摘 要： | 稀散元素材料已成为当代高新技术领域的重要支撑材料,其中铟应用于液晶材料(ITO)的研究与开发1,2].烷基二硫代磷酸酯具有优良的配位性能,可用作石油添加剂和高聚物防老化剂3,4].因此,目前对稀散元素烷基硫代配合物研究十分活跃.
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| 关 键 词： | 铟 二(2-乙基)二硫代磷酸酯 单斜晶系 C2/c空间群 |
| 收稿时间： | 1998-01-14 |
Synthesis and Crystal Structure of In[(C2H5O)2PS2]3 |
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| LIU Xing-Zhi,XUE Hong,ZHAO Jin,SONG Yu-Lin,ZANG Shu-Liang.Synthesis and Crystal Structure of In[(C2H5O)2PS2]3[J].Chemical Research In Chinese Universities,1999,20(2):196-198. |
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| Authors: | LIU Xing-Zhi XUE Hong ZHAO Jin SONG Yu-Lin ZANG Shu-Liang |
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| Institution: | Research Institute of Rare and Scatter Elements, Liaoning University, Shenyang, 110036 |
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| Abstract: | The complex In 3 was synthesised and characterized by IR,
MS, TGDTA and elementary analysis. The crystal structure was determined and indicated that
In 3 is monoclinic, space group C2/c with a=0816 0(2) nm, b=1878 5(4) nm, c=1792 9(4) nm,
==9000(0), =9215(3), V=2986(1) nm3, Z=4, Dx=1538 g/cm3, F(000)=1 360. The structure was
refined to R=0059 and Rw=0063. There are four chemical units in each crystal cell in which In()
ion coordinates with six sulfur atoms and the number of coordination is 6. The molecular
contiguration of crystal is octahedral. |
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| Keywords: | Indium Di(2ethyl)dithiophosphato Monoclinic system Space group C2/c |
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