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烯烃亲电加成反应的教学研究
引用本文:赵三虎,贾晓丽,赵明根,孙金鱼.烯烃亲电加成反应的教学研究[J].化学通报,2011,74(4):380-384.
作者姓名:赵三虎  贾晓丽  赵明根  孙金鱼
作者单位:赵三虎,赵明根,孙金鱼,Zhao Sanhu,Zhao Minggen,Sun Jinyu(忻州师范学院化学系,忻州,034000);贾晓丽,Jia Xiaoli(忻州师范学院附属外国语中学,忻州,034000)
基金项目:有机化学山西省省级精品课程项目
摘    要:烯烃的典型反应是亲电加成反应.大学有机化学教学目标要求学生掌握并能熟练应用烯烃亲电加成反应的区域选择性、立体选择性以及烯烃的反应活性解决实际问题.具体包括:(1)使用区域选择性预测加成主副产物;(2)使用立体选择性判断加成产物立体结构;(3)综合考虑电子效应,熟练比较各种烯烃的反应活性.由于烯烃亲电加成反应底物多、影响...

关 键 词:区域选择性  立体选择性  反应活性  电子效应  构型

Teaching Research on the Reactions of Electrophilic Addition to Alkenes
Zhao Sanhu,Jia Xiaoli,Zhao Minggen,Sun Jinyu.Teaching Research on the Reactions of Electrophilic Addition to Alkenes[J].Chemistry,2011,74(4):380-384.
Authors:Zhao Sanhu  Jia Xiaoli  Zhao Minggen  Sun Jinyu
Institution:Zhao Sanhu1,Jia Xiaoli2,Zhao Minggen1,Sun Jinyu1(1Department of Chemistry,Xinzhou Teachers University,Xinzhou 034000,2 Xinzhou Teachers University Subsidiary Foreign Language School,Xinzhou 034000)
Abstract:Electrophilic addition reaction is one of typical reaction of alkenes.As one of teaching goals of organic chemistry in university,students should master the knowledge of the regioselectivity,stereoselectivty and reactivity of the electrophilic addition reaction of alkenes and used skillfully to solve practical problems.It includes that the students can predict the major and the minor product of the addition reaction by using regioselectivity;judge the configuration of product by using the stereoselectivity;...
Keywords:Regioselectivity  Stereoselectivty  Reactivity  Electronic effect  Configuration  
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