| 负载型烯烃聚合催化剂合成的新方法 |
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| 引用本文： | 王文钦,王立.负载型烯烃聚合催化剂合成的新方法[J].化学学报,2002,60(11):1899-1908. |
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| 作者姓名： | 王文钦 王立 |
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| 作者单位： | 浙江大学高分子科学与工程系,杭州(310027) |
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| 基金项目： | 国家自然科学基金 (No .2 0 172 0 45 )资助项目 |
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| 摘 要： | 介绍了负载型烯烃聚合催化剂合成的新方法，探讨了不同载体负载的Ziegler- Natta催化剂各组分之间的相互作用机理及活性中心的形成途径。对负载茂金属催 化剂的新型载体及新的负载方法进行了评述。
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| 关 键 词： | 烯烃 聚合 齐格勒纳塔催化剂 金属茂络合物 |
| 修稿时间： | 2002年6月6日 |
Novel Synthetic Methods of Supported Catalysts for Olefin Polymerization |
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| Wang Wenqin,Wang Li.Novel Synthetic Methods of Supported Catalysts for Olefin Polymerization[J].Acta Chimica Sinica,2002,60(11):1899-1908. |
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| Authors: | Wang Wenqin Wang Li |
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| Institution: | Department of Polymer Science and Engineering, Zhejiang University, Hangzhou(310027) |
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| Abstract: | In this paper, the novel synthetic methods of supported catalysts for olefin polymerization are introduced. In the Ziegler Natta catalysts supported on different carrier systems, the mechanism of interaction among different components and the formation process of active sites are discussed. Some novel carriers and new supporting methods of supported metallocene catalysts are introduced. |
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| Keywords: | supported polyolefin catalyst interaction mechanism active site metallocene |
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