Synthesis and properties of new orange red light‐emitting hyperbranched and linear polymers derived from 3,5‐dicyano‐2,4,6‐tristyrylpyridine |
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Authors: | Hongli Wang Zhen Li Zuoquan Jiang Yanke Liang Hui Wang Jingui Qin Gui Yu Yunqi Liu |
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Abstract: | Two new orange red light‐emitting hyperbranched and linear polymers, poly(pyridine phenylene)s P1 and P2, were prepared by the Heck coupling reaction. In particular, an A2 + B3 approach was developed to synthesize conjugated hyperbranched polymer P2 via one‐pot polycondensation. The polymers were characterized by NMR, Fourier transform infrared, ultraviolet–visible, and elemental analysis. They showed excellent solubility in common solvents such as tetrahydrofuran, CH2Cl2, CHCl3, and N,N‐dimethylformamide and had high molecular weights (up to 6.1 × 105 and 5.8 × 105). Cyclic voltammetry studies revealed that P2 had a low‐lying lowest unoccupied molecular orbital energy level of ?3.22 eV and a highest occupied molecular orbital energy level of ?5.43 eV. The thin film of P2 emitted strong orange‐red photoluminescence at 595 nm. A double‐layer light‐emitting diode fabricated with the configuration of indium tin oxide/P2/tris(8‐hydroxy‐quinoline)aluminum/Al emitted orange‐red light at 599 nm, with a brightness of 662 cd/m2 at 7 V and a turn‐on voltage of 4.0 V; its external quantum efficiency was calculated to be 0.19% at 130.61 mA/cm2. This indicated that this new electroluminescent polymer (P2) based on 3,5‐dicyano‐2,4,6‐tristyrylpyridine could possibly be used as an orange‐red emitter in polymer light‐emitting displays. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 493–504, 2005 |
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Keywords: | 3 5‐dicyano‐2 4 6‐tristyrylpyridine electroluminescence hyperbranched light‐emitting diodes (LED) orange‐red triphenylamine photoluminescence |
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