| FREE STANDING FILM OF POLYANILINE |
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| 作者姓名： | 万梅香 曹镛 李军朝 周维侠 李素珍 |
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| 作者单位： | Institute of Chemistry，Academia Sinica，Beijing，Institute of Chemistry，Academia Sinica，Beijing，Institute of Chemistry，Academia Sinica，Beijing，Institute of Chemistry，Academia Sinica，Beijing，Institute of Chemistry，Academia Sinica，Beijing |
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| 摘 要： | A free standing film of polyaniline as large as 18 cm×18cm×0.002 cm can be obtained by evaporation of a solution of the chemically synthesized base in NMP. Its structure was examined by the elemental analysis, IR, U.V.-visible spectra, XPS, DSC, SEM and X-ray scattering and its conducting behavior as well as electrochemical properties were studied. Results show that the composition, structure of main chain, physical properties of the free standing film of polyanilme is similar to that of the powder. However, some differences in its electronic structure, conductivity at room temperature and potential of redox couple between the flee standing film and powder are observed, which may be due to cross-linking of the film of polyaniline.
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| 收稿时间： | 1990-04-10 |
FREE STANDING FILM OF POLYANILINE |
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| WAN Meixiang,CAO Yong,LI Junchao,ZHOU Weixia,LI Suzhen.FREE STANDING FILM OF POLYANILINE[J].Chinese Journal of Polymer Science,1991,0(3):209-219. |
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| Authors: | WAN Meixiang CAO Yong LI Junchao ZHOU Weixia LI Suzhen |
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| Institution: | Institute of Chemistry; Academia Sinica; Beijing |
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| Abstract: | A free standing film of polyaniline as large as 18 cm×18cm×0.002 cm can be obtained by evaporation of a solution of the chemically synthesized base in NMP. Its structure was examined by the elemental analysis, IR, U.V.-visible spectra, XPS, DSC, SEM and X-ray scattering and its conducting behavior as well as electrochemical properties were studied. Results show that the composition, structure of main chain, physical properties of the free standing film of polyanilme is similar to that of the powder. However,some differences in its electronic structure,conductivity at room temperature and potential of redox couple between the free standing film and powder are observed,which may be due to cross-linking of the film of polyaniline. |
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| Keywords: | Conducting polymers Conductivity Polyaniline Free-standing Film The protonation state |
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