Laser-induced reactions of NO2 in the visible region |
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| Authors: | M E Umstead M C Lin |
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| Institution: | (1) Chemistry Division, Naval Research Laboratory, 20375-5000 Washington, DC, WA, USA |
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| Abstract: | The 488 nm laser-induced reaction of NO2 with CO has been investigated and the results computer-modeled. Two reaction mechanisms were considered:1) the direct reaction of vibronically excited NO2 (NO
2
* 
) with CO to form CO2, and 2), the reaction of an intermediate NO3 radical formed by the reaction of NO
2
*
with NO2 followed by NO3+CO NO2+CO2. The modeling results strongly support the former as the dominant mechanism.Federal Junior Fellow (1980–1984) |
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| Keywords: | 82 30 82 50 |
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