Isothermal crystallization behavior and unique banded spherulites of hydroxyapatite/poly(L-lactide) nanocomposites |
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Authors: | Jun-chao Wei Jing-ru Sun Hai-juan Wang Xue-si Chen Xia-bin Jing |
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Institution: | State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China Graduate School of Chinese Academy of Sciences, Beijing 100039, China |
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Abstract: | Hydroxyapatite/poly(L-lactide) (HA/PLLA) nanocomposites were prepared by the solvent mixing method. The isothermal crystallization behavior was studied by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). The results show that the crystallization behavior of HA/PLLA composites was strongly affected by the content of HA and crystallization temperature, and the addition of HA could promote nucleation and enhance the crystallization rate. When isothermal crystallization was carried out at 110℃, the HA/PLLA nanocomposite with 1% HA content crystallized most rapidly among all the composites and the half crystallization time was only 1.0 min. Banded spherulites were observed for the HA/PLLA composites, but no banded spherulites were seen in the crystals of PLLA under the same condition. |
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Keywords: | Hydroxyapatite Polylactide Crystallization Nanocomposites Spherulites |
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