热耦合型二级高频脉冲管制冷机实验研究

降低制冷温度至4 K温区是高频脉冲管制冷机的最新发展要求。本文介绍了一套热耦合型二级高频脉冲管制冷机的性能特性,它可以达到低于15 K以下的最低温度,是目前报道的高频二级脉冲管制冷机能获得的最低温度．通过对制冷机一级预冷、二级输入功率、二级冷量、室温条件等影响的分析,从实验角度揭示了该二级制冷系统的复杂影响,为进一步的深入分析和改进提供了基础。     

Cochran's statistical theorem for outer inverses of matrices and matrix quadratic forms

We extend the matrix version of Cochran's statistical theorem to outer inverses of a matrix. As applications, we investigate the Wishartness and independence of matrix quadratic forms for Kronecker product covariance structures.     

On the Solvability of the Multidimensional Version of the First Darboux Problem for a Model Second-Order Degenerating Hyperbolic Equation

A multidimensional version of the first Darboux problem is considered for a model second-order degenerating hyperbolic equation. Using the technique of functional spaces with a negative norm, the correct formulation of this problem in the Sobolev weighted space is proved.     

Gradient- and Sensitivity-Enhanced TOCSY Experiments

A pulsed field gradient version of the sensitivity-enhanced 2D TOCSY experiment is proposed which yields high-quality spectra with improved sensitivity and a minimum of two scans pert₁increment. For rapid acquisition of 1D TOCSY spectra, the 1D DPFGSE–TOCSY experiment was modified to include phase-encoded multiple-selective excitation followed by a simple spectral editing. Combination of these two building blocks is used in a sensitivity-enhanced 2D analog of the 3D TOCSY–TOCSY experiment which provides an efficient tool for resolving severely overlapped signals of oligomers in short experimental time.     

On a Multivalued Version of the Sharkovskii Theorem and its Application to Differential Inclusions

Motivated by the applications to differential equations without uniqueness conditions, we separately prove multivalued versions of the celebrated Sharkovskii and Li–Yorke theorems. These are then applied, via multivalued Poincaré operators, to Carathéodory differential inclusions. Thus, besides another, infinitely many subharmonics of all integer orders can be obtained. Unlike in the single-valued case, for example, period three brings serious obstructions. Three counter-examples, related to these complications, are therefore presented as well. In a multivalued setting, new phenomena are so exhibited.     

Approximation by Algebraic Polynomials on Rectangles

A direct theorem for approximation by algebraic polynomials in two variables with different degrees in each variable in L_p-metric (1 p ) on rectangles is proved, and the dependence of the constants on various parameters is studied.     

Limit theorems for random processes with random time substitution

In this paper we prove a theorem on sufficient conditions for the convergence in the Skorokhod space D[0, 1] of a sequence of random processes with random time substitution. We obtain almost sure versions of this theorem.     

单板机在气轨实验的在线时间测量

在气轨实验中，采用Z80单板机设计单板数字毫秒仪，精确测量在线时间。     

Synthesis, spectroscopic characterization, DFT studies and biological assays of a novel gold(I) complex with 2-mercaptothiazoline

A new gold(I) complex with 2-mercaptothiazoline (MTZ) with the coordination formula [AuCN(C₃H₅NS₂)] was synthesized and characterized by chemical and spectroscopic measurements, DFT studies and biological assays. Infrared (IR) and ¹H, ¹³C and ¹⁵N nuclear magnetic resonance (NMR) spectroscopic measurements indicate coordination of the ligand to gold(I) through the nitrogen atom. Studies based on DFT confirmed nitrogen coordination to gold(I) as a minimum of the potential energy surface with calculations of the hessians showing no imaginary frequencies. Thermal decomposition starts at temperatures near 160 °C, leading to the formation of Au⁰ as the final residue at 1000 °C. The gold(I) complex with 2-mercaptothiazoline (Au-MTZ) is soluble in dimethyl sulfoxide (DMSO), and is insoluble in water, methanol, ethanol, acetonitrile and hexane. The antibacterial activities of the Au-MTZ complex were evaluated by an antibiogram assay using the disc diffusion method. The compound showed an effective antibacterial activity against Staphylococcus aureus (Gram-positive) and Escherichia coli and Pseudomonas aeruginosa (Gram-negative) bacterial cells. Biological analysis for evaluation of the cytotoxic effect of the Au-MTZ complex was performed using HeLa cells derived from human cervical adenocarcinoma. The complex presented a potent cytotoxic activity, inducing 85% of cell death at a concentration of 2.0 μmol L⁻¹.     

Numerical study of the HP version of mixed discontinuous finite element methods for reaction‐diffusion problems: The 1D case

This article studies the stability and convergence of the hp version of the three families of mixed discontinuous finite element (MDFE) methods for the numerical solution of reaction‐diffusion problems. The focus of this article is on these problems for one space dimension. Error estimates are obtained explicitly in the grid size h, the polynomial degree p, and the solution regularity; arbitrary space grids and polynomial degree are allowed. These estimates are asymptotically optimal in both h and p for some of these methods. Extensive numerical results to show convergence rates in h and p of the MDFE methods are presented. Theoretical and numerical comparisons between the three families of MDFE methods are described. © 2003 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 19: 525–553, 2003