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排序方式: 共有218条查询结果,搜索用时 156 毫秒
1.
XianaiaoLiu HuizhouLiu JianminXing YuepingGuan ZhiyaMa GuobinShan chengliYang 《中国颗粒学报》2003,1(2):76-79
Superparamagnetic poly(styrene-divinylbenzene-glycidyl methacrylate) (Pst-DVB-GMA) microparticles were prepared via a modified suspension polymerization process. A magnetic fluid was first prepared by a chemical co-precipitation method. Then magnetic microparticles were produced by mixing the monomers and the magnetic fluid with water in the presence of a stabilizer poly(vinyl pyrrolidone) (PVP) to form a suspension, and finally benzoyl peroxide was added to initiate the co-polymerization. The morphology and magnetic properties of the microparticles were examined by TEM and VSM. The spherically shaped microparticles, with a size range of 4 to 7 pm, showed distinct superparamagnetic characteristics. XRD was used to investigate the structure of the magnetite particles dispersed in the polymer matrix. The microparticles with epoxy groups on their surface can be applied directly to the seoaration of biomolecules. 相似文献
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Experimental and theoretical study of the nonlinear response of agiant magnetostrictive rod 总被引:1,自引:0,他引:1
In this paper, a magnetomechanical coupling constitutive relation of the giant magnetostrictive material was investigated
experimentally and theoretically. A grain-oriented magnetostrictive rod of iron and rare earth was tested under a combined
magnetomechanical loading. Two types of experimental curves were obtained, i.e., the magnetostrictive curve of the extensional
strain vs the magnetic field, and the curve of the magnetic polarization intensity vs the pre-stress. A new theoretical constitutive
model, based on the density of domain switching, is developed. Comparison of the theoretical predictions with the experimental
results indicates that this model can capture the main characteristics of the magnetoelastic coupling deformation of a giant
magnetostrictive rod.
The project supported by the National Natural Science Foundation of China (10025209, 10132010, 10102007) 相似文献
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With the improvement of high-tech and emergence of crossing and new fields,lanthanide-transition(Ln–M) heterometallic coordination polymers have attracted much attention of many researchers,which exhibit novel structures and unique properties with potential applications in the nonlinear optical materials,fluorescent materials,superconducting materials,magnetic materials,catalysis,bio-simulation,adsorption and separation,and so on.It is thus necessary to summarize Ln–M heterometallic coordination polymers.According to the transition metal ions,those coordination polymers are divided into six parts to explore the current applications and future developments. 相似文献
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以溴代丙二酸二乙酯、丙烯酸钠为原料合成了聚丙烯酸双(乙氧羰基)甲酯(PEOCMA),并制备了其相应的与稀土金属Gd3+、Nd3+以及过渡金属Ni2+的高分子螯合物.利用FTIR、1H-NMR、GPC对聚合物和高分子螯合物的结构进行了表征,通过电感耦合等离子质谱仪(ICP)测得了高分子螯合物中的金属含量,借助多功能材料物理特性测试系统(PPMS,physical property measurement system)测定螯合物的磁性能.结果表明这些高分子螯合物具有较高的磁饱和强度,在低温下呈现出一定的铁磁相互作用,且为软磁性材料. 相似文献
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采用原位聚合方法制备了膨胀石墨/聚苯胺(EG/PANI)复合材料,将Fe_3O_4负载于EG/PANI表面,得到具有电磁吸收性能的EG/PANI/Fe_3O_4复合材料.通过扫描电子显微镜(SEM)、X射线衍射仪(XRD)、傅里叶变换红外光谱仪(FTIR)及矢量网络分析仪(VNA)等对复合材料的形貌、成分和吸波性能进行了研究.吸波性能分析结果表明,当掺杂浓度为0.05 mol/L,匹配厚度d=2 mm时,样品的最小反射损耗(RLmin)在8.64 GHz处达到-37 dB.随着掺杂浓度的增加,最小反射损耗峰向低频移动,对应的匹配厚度逐渐变厚.材料的介电弛豫极化、涡流损耗及λ/4模型的干涉相消现象出现的双峰,使EG/PANI/Fe_3O_4复合材料在电磁波吸收领域有一定的应用前景. 相似文献
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