环氧乙烷亲核开环的区域选择性规则在有机化学教学中的应用

环氧乙烷亲核开环的区域选择性规则是有机化学中典型脂肪三元杂环亲核性开环的选择性规则,具有普遍性。本文以非对称环氧乙烷的亲核性开环为核心,从开环反应过渡态稳定性的角度讨论了决定环氧乙烷亲核开环区域选择性的原因。介绍了该区域选择性规则在经过三元杂环正离子中间体的非对称烯烃亲电加成反应区域选择性教学中的应用。加强学生对不同反应的机理和选择性的联系,起到教学中融会贯通的作用,可以提高教学效率和效果。     

集团统一审计、审计风险与组成部分重要性水平

针对集团审计的特性,运用贝叶斯定理构建集团审计模型GUAM,并用伽玛概率分布函数表示先验函数、后验函数与似然函数,用于规范集团各组成部分的重要性水平核算,将模型从单一组织扩展到集团层面的审计,并建立了各组成部分重要性水平与相对可变成本的计算公式,通过各组成部分的资产等标准分配权重,进而确定合适的先验水平使得集团整体的可变成本降低,以达到提高集团审计效率,通过集团层面的控制,使得在完成集团整体目标置信水平的基础上达到最佳审计效果的目的.     

关于定积分近似计算中矩形法的误差估计

利用拉格朗日中值定理给出复合矩形法的误差估计,并指出复合矩形法只有在等分的次数很大的时候才能比较精确的估计所求定积分的值.最后,给出复合矩形法、复合梯形法及复合抛物线法的误差估计实例.     

On the use of fuzzy inference techniques in assessment models: part I—theoretical properties

An assessment model is a mathematical model that produces a measuring index, either in the form of a numerical score or a category to a situation/object, with respect to the subject of measure. From the numerical score, decision can be made and action can be taken. To allow valid and useful comparisons among various situations/objects according to their associated numerical scores to be made, the monotone output property and the output resolution property are essential in fuzzy inference-based assessment problems. We investigate the conditions for a fuzzy assessment model to fulfill the monotone output property using a derivative approach. A guideline on how the input membership functions should be tuned is also provided. Besides, the output resolution property is defined as the derivative of the output of the assessment model with respect to its input. This derivative should be greater than the minimum resolution required. From the derivative, we suggest improvements to the output resolution property by refining the fuzzy production rules.     

Hadamard's inequality and Trapezoid Rules for the Riemann-Stieltjes integral

We obtain Midpoint and Trapezoid Rules for the Riemann-Stieltjes integral which engender a natural generalization of Hadamard's integral inequality. Error terms are then obtained for this Riemann-Stieltjes Trapezoid Rule and other related quadrature rules.     

命题逻辑系统L*的有效集

针对命题逻辑系统L*,以及增加一元联结词△后的系统L*△,研究了该逻辑系统有效集的特征,进而以有效集为工具得到公式集F(S)的一类分划,即可将L*与L*△中的公式集F(S)分别分为16和20个等价类;最后给出了L*中对M P规则封闭的有效集的特征。     

基于目标信息系统学习的多准则决策方法

给出目标信息系统学习的多准则决策方法，建立多准则决策的规则学习模型，讨论该模型的性质。该模型优于Z．Pawlak方法，将规则提取与信息融合为一体。也优于AHP等模型，具有简洁性．通过实例计算，取得了满意结果。     

基于模糊集相容性的模糊控制规则优化方法

在简要介绍模糊模型的完备性和相容性的基础上 ,根据模糊集贴近度 ,提出模糊集相容性的概念 ;通过对模糊控制规则表特征的分析 ,进一步完善规则相容性概念及其定量评价方法 ;最后给出模糊控制规则模型自寻优优化方法。仿真结果表明 ,该方法可以大大提高控制系统的控制性能。     

Level shift operators for open quantum systems

Level shift operators describe the second-order displacement of eigenvalues under perturbation. They play a central role in resonance theory and ergodic theory of open quantum systems at positive temperatures. We exhibit intrinsic properties of level shift operators, properties which stem from the structure of open quantum systems at positive temperatures and which are common to all such systems. They determine the geometry of resonances bifurcating from eigenvalues of positive temperature Hamiltonians and they relate the Gibbs state, the kernel of level shift operators, and zero energy resonances. We show that degeneracy of energy levels of the small part of the open quantum system causes the Fermi Golden Rule Condition to be violated and we analyze ergodic properties of such systems.