The concept of dual roles design in clean organic preparation

Herein we summarized some clean preparation examples to emphasize the concept of dual roles design (or named as “two birds one stone strategy”) in green and sustainable chemistry. In those examples, the reactants and/or solvent play dual roles rendering a cleaner organic preparation process. Consequently, both the chemical waste and manufacturing cost could be reduced.     

Turbulent Channel Flow with an Artificial Two-Dimensional Wall Layer

Turbulent flow of an incompressible fluid in a plane channel with parallel walls is considered. The three-dimensional time-dependent Navier-Stokes equations are solved numerically using the spectral finite-difference method. An artificial force which completely suppresses lateral oscillations of the velocity is introduced in the near-wall zone (10 % of the channel half-width in the neighborhood of each wall). Thus, the three-dimensional flow zone, in which turbulent oscillations can develop, is separated from the wall by a fluid layer. It is found that the elimination of three-dimensionality in the neighborhood of the walls leads to a significant reduction in the drag. However, complete laminarization does not occur. The flow in the stream core remains turbulent and can be interpreted as a turbulent flow in a channel with walls located on the boundary of the two-dimensional layer and traveling at the local mean-flow velocity. The oscillations developing inside the two-dimensional layer, which have significant amplitude, distort the flow only in the adjacent zone. Beyond this zone the distributions of the mean characteristics and the structure of instantaneous fields completely correspond to ordinary turbulent flow in a channel with rigid walls. The results obtained confirm the hypothesis of the unimportance of the no-slip boundary conditions for the fluctuating velocity component in the mechanism of onset and self-maintenance of turbulence in wall flows.     

指数分布在概率统计教学中的纽带作用

讨论指数分布在概率统计教学中的作用.从指数分布的定义及特征出发,分五个方面提出指数分布的知识点连接教学法,以此说明指数分布在概率统计教学中的纽带作用.     

聚乙烯吡咯啉酮对稀土变色酸双偶氮类试剂显色反应的褪色作用

研究了非离子型表面活性剂聚乙烯吡咯啉酮（ＰＶＰ）、（ＮＨ４）２ＳＯ４对ＲＥ（Ⅲ）、Ｆｅ（Ⅲ）、Ｚｒ（Ⅳ）、Ｔｈ（Ⅳ）、Ｃｕ（Ⅱ）等离子与变色酸双偶氮类试剂显色反应的影响。建立了大量稀土存在下测定微量Ｆｅ（Ⅲ）的新方法。纯稀土中Ｆｅ（Ⅲ）的测定，回收率在９８．０％～１０１．０％；对矿样测定，６次测定ＲＳＤ为１．７９％。     

混合多属性决策问题中的权重研究

针对属性值以精确数、区间数、直觉梯形模糊数给出的混合多属性决策问题,提出一种基于属性的可靠性、属性对决策的影响度和决策者对属性的重视程度这三个维度给权重赋值的方法。首先对属性的可靠性进行定义,并计算出属性的可靠性;接着根据属性内部差异最大化求出属性对决策的影响度;随后利用直觉梯形模糊数之间的距离求出决策者对属性的重视程度,并用投影模型将这三个维度进行集成,得到最终的权重值。该方法能够使权重的获取更加全面,最后利用算例证明了本文方法的可行性。     

A study on the distribution of adsorbed nanoparticles

We use Monte Carlo simulation to calculate the distributions of particles under adsorption force near planar and cylindrical surfaces,respectively.Both hard sphere interaction and repulsive Yukawa (screened coulomb) interaction are employed in our simulations.We study the influence of the inter-particle potentials.The difference between the MC simulation results and the analytical results of ideal gas model shows that the interaction between particles plays an important role in the density distribution under external fields.Moreover,the 2-dimensional constructions of particles close to the surface are studied and show relations of the interaction between particles.These results may indicate us how to improve the methods of building nanoparticle coatings and nano-scale patterns.     

基于Web的图书馆管理系统访问控制策略

针对基于Web的图书馆管理系统资源访问控制的动态性问题，提出了一种基于角色的访问控制策略描述方案．通过对基于Web的图书馆管理系统访问控制管理影响因素和访问控制需求的分析，结合NIST基于角色的访问控制统一模型标准，构造了一种基于角色的访问控制元模型．并在这一元模型的基础上，提出了一种紧凑的基于角色的访问控制XML策略描述语言框架．结果表明该访问控制策略描述语言框架适合表述动态环境下对图书馆资源的访问策略，提高了基于Web的图书馆管理系统资源访问的安全性．     

PARTICIPATION IN INTERNATIONAL ENVIRONMENTAL AGREEMENTS: THE ROLE OF TIMING AND REGULATION

ABSTRACT. We analyze the formation of self‐enforcing international environmental agreements under the assumption that countries announce their participation either simultaneously or sequentially. It is shown that a sequential formation process opens up possibilities for strategic behavior of countries that may lead to inferior outcomes in terms of global abatement and welfare. We then analyze whether and under which conditions a regulator like an international organization, even without enforcement power, can improve upon globally suboptimal outcomes through coordination and moderation, given that recommendations must be Pareto‐improving to all parties.     

Application of nanodiamonds in human body fluid analysis by matrix-assisted laser desorption/ionization mass spectrometry

Direct mass spectrometric analysis of complex biological samples is very important and challenging. In this paper, nanodiamonds have been successfully used in matrix-assisted laser desorption/ionization mass spectrometric analysis of human serum and urine. As a practical tool and platform, it can be widely used in the field of humoral proteomics, and it plays a very promising role in clinical diagnosis, including identification of novel disease-associated biomarkers.