中药配方颗粒红外光谱法的快速鉴别

采用红外光谱法对中药配方颗粒及其辅料进行了鉴别研究。结果表明：不同生产厂商的配方颗粒中所添加的辅料类型及用量有较大差别；不同种的配方颗粒在辅料含量较低的情况下有较明显的指纹性，而辅料含量较高时，采用差谱技术可以提高谱图的指纹性，达到中药配方颗粒--鉴别的目的。该法简便、快速、可靠，是中药配方颗粒宏观质控的一个强有力的手段。     

高效液相亲水作用色谱-串联质谱法同时测定婴幼儿配方乳粉中胆碱和左旋肉碱的含量

称取乳粉样品1.000g,加入1.0mol·L~(-1)的盐酸溶液25mL,涡旋混匀5min,于70℃水浴中水解3h(每隔30min振摇混匀一次),冷却后加入20mL乙醚,涡旋振荡30s,然后于4℃下以6 000r·min~(-1)冷冻离心10min。取上清液0.10mL,加入1mol·L~(-1)的乙酸铵溶液50μL,用水定容至10.0 mL,涡旋混匀,吸取1～2 mL上清液,经0.22μm水系针式滤膜过滤后,采用Hypersil GOLDTMAQ色谱柱(2.1mm×100mm,1.9μm)分离,以乙腈-乙酸铵溶液为流动相进行梯度洗脱。质谱选择电喷雾正离子源和多反应监测模式。胆碱和左旋肉碱的质量浓度分别在0.05～1.0mg·L~(-1),0.01～0.20mg·L~(-1)内与其定量离子峰面积呈线性关系,检出限(3S/N)分别为0.003,0.005mg·kg~(-1)。方法用于测定质控样品中的胆碱和左旋肉碱,测定值与认定值的相对误差在10%以内。采用本方法测定婴幼儿配方乳粉样品中的胆碱和左旋肉碱,测定结果和国家标准方法的测定结果相符,测定值的相对标准偏差(n=6)小于9.0%     

简讯

二恶英检测技术已较成熟人们熟悉的生活垃圾焚烧发电,公众有所担忧的主要理由便是垃圾焚烧会产生二恶英,这种被称为"世纪之毒"的物质的毒性比砒霜还要毒大约900倍。不久前,被视为国内二恶英研究权威的中科院研究员郑明辉表示,全国每年排放到大气环境中的二恶英大约5 kg左右,其中来自生活垃圾     

沃特世化工领域解决方案

随着化工市场对于新型技术需求的增加和化工企业对于可持续发展的重视,传统的分析技术已经满足不了企业的需求,越来越复杂的产品配方让分析工作者面临极大的挑战。为了保证收益和增长,公司必须寻找最新的实验室技术来提升研发速度和研发实力,增加产品收益,探明不合格产品原因,并对客户投诉做出迅速反应。沃特世针对化工领域细分市场解决方案沃特世化工领域市场经理蔡麒将化工行业面临的挑战概括为三个简单的词:创新、效率及服务。从分析检测角度而言,化工行业需要分离性能更高、分离效率更高及多样性的分析设备。而沃特世专门面向化学材料行业的综合解决方案可以帮助生产商有效降低成本并加速新产品研发,改善生产流程效率,保障成品质量。能有效应对以上挑战。     

应用正交试验法筛选高阻燃级别MPPO配方

MPPO即改性聚苯醚,是世界五大通用工程塑料品种之一,应用范围极广.我院生产的MPPO产品具有优秀的机械性能、热性能及加工性能,阻燃级别达到UL94V-1级.目前,国际市场对MPPO阻燃性能的要求较高,我国电器行业规定出口产品所用MPPO材料的阻燃性能要达到美国UL94V-0级标准.为尽快提高我院MPPO产品的阻燃性,早日获得美国公司UL的黄卡认证,为我国电器产品出口创汇提供有利条件,我们选择了正交试验法进行高阻燃级别MPPO配方筛选.     

MIXED INTERIOR PENALTY DISCONTINUOUS GALERKIN METHODS FOR ONE-DIMENSIONAL FULLY NONLINEAR SECOND ORDER ELLIPTIC AND PARABOLIC EQUATIONS

This paper is concerned with developing accurate and efficient numerical methods for one-dimensional fully nonlinear second order elliptic and parabolic partial differential equations （PDEs）. In the paper we present a general framework for constructing high order interior penalty discontinuous Galerkin （IP-DG） methods for approximating viscosity solutions of these fully nonlinear PDEs. In order to capture discontinuities of the second order derivative uxx of the solution u, three independent functions p1,p2 and p3 are introduced to represent numerical derivatives using various one-sided limits. The proposed DG frame- work, which is based on a nonstandard mixed formulation of the underlying PDE, embeds a nonlinear problem into a mostly linear system of equations where the nonlinearity has been modified to include multiple values of the second order derivative uxz. The proposed framework extends a companion finite difference framework developed by the authors in [9] and allows for the approximation of fully nonlinear PDEs using high order polynomials and non-uniform meshes. In addition to the nonstandard mixed formulation setting, another main idea is to replace the fully nonlinear differential operator by a numerical operator which is consistent with the differential operator and satisfies certain monotonicity （called g-monotonicity） properties. To ensure such a g-monotonicity, the crux of the construction is to introduce the numerical moment, which plays a critical role in the proposed DG frame- work. The g-monotonicity gives the DG methods the ability to select the mathematically ＂correct＂ solution （i.e., the viscosity solution） among all possible solutions. Moreover, the g-monotonicity allows for the possible development of more efficient nonlinear solvers as the special nonlinearity of the algebraic systems can be explored to decouple the equations. This paper also presents and analyzes numerical results for several numerical test problems which are used to guage the accuracy and efficiency of the proposed DG methods.     

ERROR ESTIMATION FOR NUMERICAL METHODS USING THE ULTRA WEAK VARIATIONAL FORMULATION IN MODEL OF NEAR FIELD SCATTERING PROBLEM

In this paper, we investigate the use of ultra weak variational formulation to solve a wave scattering problem in near field optics. In order to capture the sub-scale features of waves, we utilize evanescent wave functions together with plane wave functions to approximate the local properties of the field. We analyze the global convergence and give an error estimation of the method. Numerical examples are also presented to demonstrate the effectiveness of the strategy.     

新型均相液体炸药配方及性能

研制的3种硝基甲烷为基的液体炸药具有腐蚀性小、安全和安定性好、价格低廉，并且其爆速、爆压、传爆等性能均能满足使用要求。但是，研制的炸药配方中稀释剂的挥发性和毒性都较大，并且液体炸药在成型、运输、贮存上都存在不足。对NM/／CHCL3／DETA(50／50／5(外))液体炸药进行了改进和完善。     

出入境乳品检验新规出台 将检测重金属元素

<正>为进一步加强对进出口乳品检验检疫的监督管理,保障进出口乳品的质量安全,督促企业落实食品安全主体责任,不久前,质检总局发布关于调整《进出口乳品检验检疫监督管理办法》实施要求的公告,相较于之前的实施要求,新要求对进口乳品检验检疫作出了两处明显的调整。一是检疫审批范围有新增。新要求增加了需要办理检疫审批手续的进口乳品种类。除已需办理检疫审批手续的生乳、生乳制品、巴氏杀菌乳外,以巴氏杀菌工艺生产加工的     

液相色谱串联四极杆质谱法同时测定婴幼儿配方食品中甲基香兰素和乙基香兰素

建立了混合阴离子交换固相萃取柱净化,液相色谱串联四极杆质谱法测定婴幼儿配方食品中甲基香兰素和乙基香兰素的方法.样品经水和乙腈提取,CuSO4溶液沉淀蛋白,NaOH调节pH,增加样品溶解性,阴离子交换固相萃取柱净化.目标化合物在梯度洗脱条件下经C18柱分离后采用ESI源负离子多反应监测模式进行检测.分别选取了婴幼儿配方乳...