全文获取类型
收费全文 | 1249篇 |
免费 | 135篇 |
国内免费 | 215篇 |
专业分类
化学 | 1585篇 |
晶体学 | 1篇 |
物理学 | 13篇 |
出版年
2023年 | 15篇 |
2022年 | 15篇 |
2021年 | 29篇 |
2020年 | 57篇 |
2019年 | 36篇 |
2018年 | 47篇 |
2017年 | 34篇 |
2016年 | 46篇 |
2015年 | 53篇 |
2014年 | 74篇 |
2013年 | 130篇 |
2012年 | 63篇 |
2011年 | 76篇 |
2010年 | 80篇 |
2009年 | 83篇 |
2008年 | 65篇 |
2007年 | 83篇 |
2006年 | 79篇 |
2005年 | 71篇 |
2004年 | 92篇 |
2003年 | 96篇 |
2002年 | 47篇 |
2001年 | 36篇 |
2000年 | 40篇 |
1999年 | 22篇 |
1998年 | 24篇 |
1997年 | 15篇 |
1996年 | 12篇 |
1995年 | 15篇 |
1994年 | 11篇 |
1993年 | 11篇 |
1992年 | 10篇 |
1991年 | 3篇 |
1990年 | 7篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有1599条查询结果,搜索用时 15 毫秒
1.
Yonghui Liu Huaying Gao Xiaoli Sheng Yuming Zhou Beibei Wang Xiao Sha Maolu Jin Jie Zhao Wenqi Liu 《应用有机金属化学》2019,33(11)
In this work, a series of novel acidic polymerized ionic liquids were used as heterogeneous catalyst for alkylation of o‐Xylene with styrene. And the effect of the amount of initiator and the type of acid used for ion exchange on catalyst structure and the catalytic performance of catalysts for alkylation were studied thoroughly. The experiment results show: when the percentage of the amount of initiator in the total material is 3%, the polymerized ionic liquid catalyst MPM‐SO3H‐[C3V][SO3CF3] has the most uniform with a specific surface area of 97.30 m2/g and a pore volume of 0.35 cm3/g. Benefiting from the unique structure features, MPM‐SO3H‐[C3V][SO3CF3] manifested an excellent catalytic performance for alkylation of o‐Xylene with styrene, along with the conversion of styrene was 96.8% and the yield of 1‐Phenyl‐1‐ortho‐xylene ethane was 94.7%. Therefore, this work provides a novel reference to the synthesis of polymerized ionic liquids and clearly explains the advantage of novel acidic polymerized ionic liquids on alkylation. 相似文献
2.
Jia-Bin Han Ao Guo Prof. Xiang-Ying Tang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(12):2989-2994
A challenging deoxygenation of alkoxyl radicals from readily accessible alcohol derivatives was developed, affording facile synthesis of functionalized alkenes with good functional group tolerance under mild reaction conditions. Because alkoxyl radicals can easily undergo β-fragmentations or hydrogen abstractions, this new strategy for deoxygenation of alkoxyl radicals is highly valuable. Moreover, mechanistic studies revealed that the electron-neutral phosphine acts as the deoxygenation reagent. 相似文献
3.
Dr. Ming-Hui Sun Prof. Dr. Li-Hua Chen Shen Yu Prof. Dr. Yu Li Xian-Gang Zhou Dr. Zhi-Yi Hu Prof. Dr. Yu-Han Sun Prof. Dr. Yan Xu Prof. Dr. Bao-Lian Su 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(44):19750-19759
Zeolite Beta single crystals with intracrystalline hierarchical porosity at macro-, meso-, and micro-length scales can effectively overcome the diffusion limitations in the conversion of bulky molecules. However, the construction of large zeolite Beta single crystals with such porosity is a challenge. We report herein the synthesis of hierarchically ordered macro-mesoporous single-crystalline zeolite Beta (OMMS-Beta) with a rare micron-scale crystal size by an in situ bottom-up confined zeolite crystallization strategy. The fully interconnected intracrystalline macro-meso-microporous hierarchy and the micron-sized single-crystalline nature of OMMS-Beta lead to improved accessibility to active sites and outstanding (hydro)thermal stability. Higher catalytic performances in gas-phase and liquid-phase acid-catalyzed reactions involving bulky molecules are obtained compared to commercial Beta and nanosized Beta zeolites. The strategy has been extended to the synthesis of other zeolitic materials, including ZSM-5, TS-1, and SAPO-34. 相似文献
4.
Hui Hu Xiaoping Hu Prof. Yuanhong Liu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(43):19137-19141
An efficient copper-catalyzed regioselective C−H alkenylation and borylative alkylation of quinoline N-oxides with vinyl arenes in the presence of pinacol diborane has been developed. The reaction proceeds through the borylcupration of the vinyl arenes followed by nucleophilic attack of the resulting alkyl copper species to the quinoline N-oxides. Benzoquinone and KOtBu were identified as the necessary additives at the second step of the reaction that are crucial for the success of the reaction. A wide range of C2-functionalizaed quinolines were obtained with good functional group tolerance, which may find utilities in pharmaceuticals and synthetic chemistry. 相似文献
5.
A new environment-friendly bentonite intercalation composite was successfully obtained from alumina sol intercalation. This process used industrial grade pseudo boehmite as the aluminum source and provided with the advantage of zero emission of acidic wastewater. The bentonite intercalation composite was investigated by XRF, ICP, XRD, FT-IR, BET, and pyridine-FTIR. Results indicated that the basal spacing was enlarged from 14.72 to 15.60 Å; the specific surface area increased by 128%; and the total acid content increased from 65.32 to 245.76 μmol/g. The catalytic activity of this composite was tested by alkylation of aromatics with olefins. The results show that the weak Lewis acid generated by extra-framework aluminum and specific surface area play a decisive role, while weak Brønsted acid site is not the active site for this alkylation reaction. 相似文献
6.
7.
《Mendeleev Communications》2022,32(3):357-359
Mild and ‘green’ ultrasound-assisted reaction of chitin with 3-(chloromethyl)[1,2,4]selenadiazolo[4,5-a]pyridin-4-ium bromide in water affords novel selenium-containing cationic chitin derivatives. The thus obtained chitin derivatives are water soluble and are characterized by high in vitro antifungal activity comparable with conventional antifungal drug Amphotericin B. 相似文献
8.
《Mendeleev Communications》2022,32(6):792-794
Alkyl-H-phosphinic acid alkyl esters are synthesized in 65–71% yield via chemoselective reaction of alkyl bromides with available alkyl-H-phosphinic acids (60–65 °C, Et3N). The latter are prepared, in turn, by direct phosphorylation of alkyl bromides with red phosphorus under phase-transfer conditions. 相似文献
9.
10.
Shuaibo Zhang Dong Li Bangzhong Wang Wuding Sun Haojun Ma Kai Di Luyang Sun Jinfeng Zhao Jingping Qu Yuhan Zhou 《European journal of organic chemistry》2023,26(36):e202300593
An efficient strategy for asymmetric trifluoromethylated allylic alkylation of easily available N-substituted glycine ethyl esters with α-(trifluoromethyl)alkenyl acetates has been developed. Catalyzed by a [Pd(C3H5)Cl]2/(R)-BINAP, various trifluoromethyl-containing N-substituted glycine ethyl ester derivatives are afforded with good yields and excellent enantioselectivities. The product can be readily converted into diverse fluoro-substituted species, which shows the practicability of this method. 相似文献