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排序方式: 共有97条查询结果,搜索用时 31 毫秒
1.
红外光谱对碱土金属二元羧酸盐结构的研究 总被引:16,自引:2,他引:14
研究了三十种二元羧酸金属盐的红外光谱,讨论了金属离子和二元酸的种类对二元酸盐配位结构的影响。发现Mg盐、Ba盐,Sr盐为螯合配位,Ca盐,Zn盐中同时存在螯合配位和桥式配位,二元酸的种类对羧酸盐配位结构没有影响。对羧酸盐在常温和熔融后的栩位方式和结构上的差异的研究结果表明,Mg盐,Ca盐与Sr盐,Ba盐在熔融后的结构变化不同。 相似文献
2.
Two coordination polymers, namely, two-dimensional complex 1 {[Cu(μ- L)1.5(ClO4)2(H2O)].(H2O)0.5}n (L = pyrazine-1,4-dioxide) and one-dimensional complex 2 [Co(μ-L)Br2(H2O)2]n, have been synthesized with pyrazine-1,4-dioxide as bridging ligands, and their crystal structures were determined by X-ray crystallography. Crystal data for complex 1: monoclinic system, space group C2/c, with a = 23.310(3), b = 12.2338(17), c = 10.6075(15) , β = 110.487(2)°, V = 2833.6(7) 3, Z = 8, C6H9Cl2CuN3O12.5, Mr = 457.60, Dc = 2.145 g/cm3, F(000) = 1832 and μ = 1.998 mm-1; and those for 2: monoclinic system, space group C2/c, with a = 11.012(3), b = 7.483(2), c = 11.451(3) , β = 101.654(4)°, V = 924.2(4) 3, Z = 4, C4H8Br2CoN2O4, Mr = 366.87, Dc = 2.637 g/cm3, F(000) = 700 and μ = 10.487 mm-1. 1 shows a two-dimensional sheet structure on the ac plane through the coordination of μ-L bridging ligands with Cu(II) ions, while 2 displays a zigzag one-dimensional chain along the c axis via the coordination of μ-L bridging ligand with Co(II) ions. Hydrogen bonds in 1 and 2 make the sheets (or chains) connect each other to form a three-dimensional structure. 相似文献
3.
《中国化学快报》2020,31(5):1305-1308
This study presents a facile strategy for the formation of highly substituted butterfly 1,4-adducts/9,10-adducts via the Diels–Alder reaction of benzyne intermediates. The method achieves very good to excellent yields of the respective anthracene derivatives under mild conditions. This practical protocol is compatible with a variety of sensitive functional groups and provides access to difunctionalized bridge 1,4-adducts/9,10-adducts. 相似文献
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超导故障限流器的研究现状及其应用 总被引:1,自引:0,他引:1
超导故障限流器(Superconducting Fault Current Limiter,SFCL)是利用超导体的基本特性,有效限制电力系统故障短路电流,提高电网安全性和稳定性的一种新型电力设备。文中在综合大量文献的基础上,对超导故障限流器进行了一种较为系统的分类。基于该种分类,结合目前国内外的研究现状,就电阻型、磁屏蔽型、饱和铁芯电抗器型、桥路型SFCL的工作原理作了详细的分析介绍,还给出了它们在电力系统中的安装位置。最后,对超导故障限流器的研究中存在的问题及其发展趋势做了说明。 相似文献
6.
This paper describes a perspective for information versatile disk for removable usage (iVDR) business. iVDR is the best bridge media for high-resolution image because of high capacity and high reliability. The first iVDR product was delivered with PMR technology hard disk drives and a copyright protection function for high-definition TV programs. The business opportunity and the new business model are discussed. 相似文献
7.
斜拉桥塔锚固区光弹性应力分析与等倾线图像处理 总被引:1,自引:2,他引:1
本文采用光弹性冻结应力法,对独塔斜拉桥塔锚固区进行了应力分析,给出了有关截面的边界应力分布及主应力迹线,从而为优化工程设计提供了重要的参考依据。本文还提出了一种新的提取等倾线的方法──图像对数增强相减法,实现了等倾线与等差线条纹的分离,同时使条纹得到了细化,提高了处理等倾线的速度与准确度。编制了自动绘制主应力迹线的程序,利用它绘制了桥塔截面的次主应力迹线。 相似文献
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In this paper, we develop a method to estimate the bridge deflection using fiber optic Bragg-grating (FBG) strain sensors.
For most structural evaluation of bridge integrity, it is very important to measure the geometric profile, which is a major
factor representing the global behavior of civil structures, especially bridges. In the past, because of the lack of appropriate
methods to measure the deflection curve of bridges on site, the measurement of deflection has been restricted to just a few
discrete points along the bridge, and the measuring points have been limited to the locations installed with displacement
transducers. However, by applying classical beam theory, a formula is rearranged to estimate the continuously deflected profile
by using strains measured directly from several points. In addition, FBG strain sensors, which are electromagnetic, noise-free
and multipoint measurable, are employed to obtain flexural strains more accurately and stably. The regression analysis is
performed to obtain a strain function from the measured strain data. Finally, the deflection curve can be estimated by applying
the strain function to the formula. An experimental test has also been carried out to verify the developed method. 相似文献