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1.
A new sample business survey for agriculture, the REA survey, and a project of integration with the FADN network (RICA in
Italy) have significantly changed the production of statistical information nowadays available with reference to the agricultural
sector. On the basis of this relevant information, new economic analyses are being developed on farms’ performance, agricultural
households’ income and the Common Agricultural Policy (CAP). In this paper the authors estimate the relationship between the
levels of variables of interest and their sampling errors using models in order to improve the accessibility of the information
on estimates accuracy to the final users (agricultural analysts, policy makers).
The paper is the result of a joint research of the three authors. Sections 1–3 and 6 by Pizzoli, Sects. 4 and 5 by Rondinelli,
Sect. 7 by Filiberti, conclusions joint to the three authors. 相似文献
2.
3.
A di-molybdenum carbonyl compound containing thiolate and dithiocarbamate li- gands, [Bu4N][(CO)4Mo(μ-SC6H5)2Mo(C5H10dtc)(CO)2] 1 (C5H10dtc = S2CNC5H10), has been pre- pared by reaction of [Mo2(SC6H5)2(CO)8] with C5H10dtcNa and [NBu4]Br in acetone. It crystallizes in monoclinic, space group P21/n with a = 13.162(3), b = 17.466(2), c = 20.453(4)(A),β = 100.77(1)°, Z = 4, V = 4619(2)(A)3, C40H56Mo2N2O6S4, Mr = 980.95, Dc = 1.389 g/cm3, μ= 7.66 cm-1, F(000) = 1988 and R = 0.0746 for 5161 observed reflections with I > 2σ(I). The complex contains a [Mo2S2]2- planar core in which one Mo atom is chelated by a C5H10dtc ligand, leading to different coordination environments of the two Mo atoms. 95Mo NMR measurement indicates that the two Mo atoms are in different oxidation states. 相似文献
4.
Synthesis, Crystal Structure and Spectroscopic Properties of the Cluster Anions [(Mo6Br )X ]2? with Xa = F, Cl, Br, I The tetrabutylammonium (TBA), tetraphenylphosphonium (TPP) and tetraphenylarsonium (TPAs) salts of the octa-μ3-bromo-hexahalogeno-octahedro-hexamolybdate(2?) anions [(Mo6Br)X]2? (Xa = F, Cl, Br, I) are synthesized from solutions of the free acids H2[(Mo6Br9560313-0aaf-4855-973c-e96df6f1d488/tex2gif-stack-11.gif">)X] · 8 H2O with Xa = Cl, Br, I. The crystal structures show systematic stretchings in the Mo? Mo bond length and a slight compression of the Bri8 cube in the Fa to Ia series. The cations do not change much. The i.r. and Raman spectra show at 10 K almost constant frequencies of the (Mo6Bri8) cluster vibrations, whereas all modes with Xa ligand contribution are characteristically shifted. The most important bands are assigned by polarization measurements and the force constants are derived from normal coordinate analysis. The 95Mo nmr signals are shifted to lower field with increasing electronegativity of the Xa ligands. The fluorine compound shows a sharp 19F nmr singlet at ?184.5 ppm. 相似文献
5.
Mouna Smida Jérome Lhôste Mohamed Dammak Santiago Garcia-Granda 《Arabian Journal of Chemistry》2019,12(8):2519-2523
Crystal structure of Fe2F5(H2O)(Htaz)(taz)(Hdma) which crystallizes in the triclinic system space group with unit cell parameters a = 8.8392(5) Å, b = 9.1948(5) Å, c = 9.5877(5) Å, α = 82.070(3)°, β = 63.699(3)°, γ = 89.202(3)°, Z = 2, and V = 690.91(7) Å3, was synthesized under hydrothermal conditions at 393 K for 72 h, by a mixture of FeF2/FeF3, 1,2,4-triazole molecule (Htaz), and hydrofluoric acid solution (HF 4%) in dimethylformamide solvent (DMF). The main feature of this material is the coexistence of two oxidation states for iron atoms (Fe2+, Fe3+) in the unit cell, which associate by opposite fluorine corners of FeF5N and FeF2N4 octahedra, and/or triazole molecule which originates the 2D produces material. The structure determination, performed from single crystal X-ray diffraction data, lead to the R1/WR2 reliability factors 0.031/0.087. Thermal stability studies (TG/DTG/DTA) show that the decomposition provides in the temperature range 473–773 K and no mass loss was detected before 473 K. Mass spectrometry (MS) has been used. The optical absorption of the solid was measured at the corresponding λmax using UV–vis diffuse-reflectance spectrum. 相似文献
6.
Using chemical separations and radiometric measurements medium-half-life irradiation products of molybdenum with 12.5 MeV deuterons were determined (90Nb, 92Nb, 95mNb, 95Nb, 96Nb, 99Mo, 95mTc, 96Tc, 99mTc) as well as thick target yields for some of them: 92Nb (0.22 μCi/μAh), 95Nb(0.05 μCi/μAh), 99Mo (64 μCi/μAh), 95mTc(0.76 μCi/μAh), 96Tc((62.5 μCi/μAh). Moreover isolation possibiities of radioactive preparations from removed worn-cut molybdenum parts of the U-120 cycletron are discussed. 相似文献
7.
Let (X,B) be a complex projective klt pair, and let f:X→Z be a surjective morphism onto a normal projective variety with maximal albanese dimension such that KX+B is relatively big over Z. We show that such pairs have good log minimal models. 相似文献
8.
We study the statistical properties of wave transport in a disordered waveguide. We first derive the properties of a “building block” (BB) of length δL starting from a potential model consisting of thin potential slices. We then find a diffusion equation—in the space of transfer matrices that describe our system—which governs the evolution with the length L of the disordered waveguide of the transport properties of interest. The latter depend only on the mean free paths and on no other property of the slice distribution. The universality that arises demonstrates the existence of a generalized central-limit theorem. We have developed a numerical simulation in which the universal statistical properties of the BB found analytically are first implemented numerically, and then the various BBs are combined to construct the full waveguide. The reported results thus obtained are in good agreement with microscopic calculations, for both bulk and surface disorder. 相似文献
9.
" 在Pt/Ti/SiO2/Si基片上用溶胶-凝胶法与快速退火工艺制备了300 nm厚的锆钛酸铅Pb(Zr0:95Ti0:05)O3 (PZT95/5)反铁电薄膜.结果显示600~700 ℃晶化处理的钙钛矿PZT95/5薄膜具有高度(111)取向生长特性.薄膜的电性能测量采用金属-铁电-金属电容器结构.在20 V电压作用下,600~700 ℃晶化处理的PZT95/5薄膜显示出饱和电滞回线.在1 kHz下,600、650和700 ℃晶化的薄膜介电常数与损耗分别为519与0.028、677与0.029、987 相似文献
10.
在研究 Ada95 分布计算语义的基础上,提出了一个支持 Ada95 的分布计算的实现模型 并讨论了在该环境下实现 Ada95 分布计算所存在的问题和解决方法,以及如何实现非 Ada95 分布计算语义的 Ada 程序的分布并行计算的问题对于后者,着重讨论了远程会合的实现问题 相似文献