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1.
《Electroanalysis》2006,18(6):595-604
The following two numerical models have been applied to zinc cations electroreduction in 1 M NaClO4 water solution: a classical EE model describing the concentration of involved species in solution (semi infinitive diffusion region), an extended EE model describing both: the concentration of involved species in solution and the concentration of metallic zinc inside mercury drop (in limited area of diffusion). In the latter model the inner part of mercury drop and surrounding solution were treated as dynamic interrelated system. Both models were applied to experimental cyclic voltammetric CV data in 1 M NaClO4, the results compared and discussed. The concentration profiles of all species including metallic zinc inside mercury drop were performed. The presented integrated model is essential for theoretical and analytical aspects of the electrochemistry of mercury soluble metal cations and amalgams.  相似文献   
2.
根据GaN氢化物气相外延生长(HVPE)的原理,设计制作了双温区卧式HVPE系统.根据实际生长中出现的问题和CaN样品的测试情况,对系统进行了逐步的调试和改进.  相似文献   
3.
This study focuses on the constructions in terms of area and perimeter in equivalent triangles developed by students aged 12–15 years-old, using the tools provided by Cabri-Geometry II [Labore (1990). Cabri-Geometry (software), Université de Grenoble]. Twenty-five students participated in a learning experiment where they were asked to construct: (a) pairs of equivalent triangles “in as many ways as possible” and to study their area and their perimeter using any of the tools provided and (b) “any possible sequence of modifications of an original triangle into other equivalent ones”. As regards the concept of area and in contrast to a paper and pencil environment, Cabri provided students with different and potential opportunities in terms of: (a) means of construction, (b) control, (c) variety of representations and (d) linking representations, by exploiting its capability for continuous modifications. By exploiting these opportunities in the context of the given open tasks, students were helped by the tools provided to develop a broader view of the concept of area than the typical view they would construct in a typical paper and pencil environment.  相似文献   
4.
ABSTRACT. The excessive and unsustainable exploitation of our marine resources has led to the promotion of marine reserves as a fisheries management tool. Marine reserves, areas in which fishing is restricted or prohibited, can offer opportunities for the recovery of exploited stock and fishery enhancement. In this paper we examine the contribution of fully protected tropical marine reserves to fishery enhancement by modeling marine reserve‐fishery linkages. The consequences of reserve establishment on the long‐run equilibrium fish biomass and fishery catch levels are evaluated. In contrast to earlier models this study highlights the roles of both adult (and juvenile) fish migration and larval dispersal between the reserve and fishing grounds by employing a spawner‐recruit model. Uniform larval dispersal, uniform larval retention and complete larval retention combined with zero, moderate and high fish migration scenarios are analyzed in turn. The numerical simulations are based on Mombasa Marine National Park, Kenya, a fully protected coral reef marine reserve comprising approximately 30% of former fishing grounds. Simulation results suggest that the establishment of a fully protected marine reserve will always lead to an increase in total fish biomass. If the fishery is moderately to heavily exploited, total fishery catch will be greater with the reserve in all scenarios of fish and larval movement. If the fishery faces low levels of exploitation, catches can be optimized without a reserve but with controlled fishing effort. With high fish migration from the reserve, catches are optimized with the reserve. The optimal area of the marine reserve depends on the exploitation rate in the neighboring fishing grounds. For example, if exploitation is maintained at 40%, the ‘optimal’ reserve size would be 10%. If the rate increases to 50%, then the reserve needs to be 30% of the management area in order to maximize catches. However, even in lower exploitation fisheries (below 40%), a small reserve (up to 20%) provides significantly higher gains in fish biomass than losses in catch. Marine reserves are a valuable fisheries management tool. To achieve maximum fishery benefits they should be complemented by fishing effort controls.  相似文献   
5.
The theory and experiment of spatially and temporally partially coherent speckle shearing interferometry is reported in this rapid communication for the first time. The general requirements for the surface roughness and coherence area of a diffuse object surface in spatially and temporally partially coherent speckle shearing interferometry are discussed. An experimental verification is presented and the results of theory and experiment are in good agreement.  相似文献   
6.
产生特殊聚焦图形的二元光学元件   总被引:2,自引:0,他引:2  
通过面积编码将伽博(Gabor)波带片的透过率函数的余弦分布等效为二元分布,研制了能产生各种特殊聚焦图形的二元光学元件。根据透镜聚焦的物理原理制作的二元振幅型波带片可以方便地产生多种聚焦线,给出了相应的实验结果,并讨论了改善聚焦效果的优化条件。  相似文献   
7.
There is a high correlation between molecular surface area (TSA) of triorganotin and triorganolead compounds and their toxicity towards a bacterium (Escherichia coli) and an alga (Selenastrum capricornutum). Parallel attempts to correlate other Group IVA organometals incorporating silicon or germanium were unsuccessful. It was further demonstrated, however, that a high correlation was obtainable between certain series of compounds with the same organic substituent but different metal centers involving all Group IVA elements. In both instances, the inability to obtain a quantitative structure-activity relationship (QSAR) for all systems studied appears to be a function of the solubility of the compounds. While organotin TSA values have been found to correlate well with their toxicities toward various organisms, this study clearly suggests that this type of QSAR can be readily extended to include other organometal systems, provided that there is no solubility problem and the toxicity is a function of the hydrophobicity of the organometal compounds.  相似文献   
8.
以山区高空间分辨率的DEM数据为主要数据源,在提取纬度、坡度、坡向等相应的地形要素栅格数据的基础上,利用GIS技术对山区可照时间的空间分布进行了模拟,实现了山区可照时间空间分布规律的可视化表达,分析了山区可照时间的空间分布特征,对于山区的农业、林业和生态环境等方面的研究具有重要意义.  相似文献   
9.
超声波声孔效应中气泡动力学的研究   总被引:8,自引:0,他引:8       下载免费PDF全文
陈谦  邹欣晔  程建春 《物理学报》2006,55(12):6476-6481
在超声快速制取组织细胞病理切片的过程中,发现激励信号对切片制取效果有明显的影响.为了掌握超声激励信号对组织细胞的影响规律,达到快速制取病理切片的最佳状态,从气泡空化模型入手,通过改变激励信号频率、声压、气泡初始半径和液体黏滞系数等参量,研究了声孔效应中气泡动力学激励机制.数值计算表明:空化泡振动随激励声压增强而升高,随液体黏滞系数增强而减弱;一定频率范围内空化泡振动能保持在膨胀、收缩和振荡的稳定空化状态,存在空化泡稳态振动的最佳激励频率;一定初始半径能保证空化泡产生稳定的振动,存在空化泡稳态振动幅度最大的初始半径.实际操作中,在频率、声压、初始半径和黏滞系数综合作用的若干空化阈内,声孔效应使超声快速法制取细胞组织切片获得最佳效果. 关键词: 声孔效应 超声空化 气泡振动 稳态空化域  相似文献   
10.
基于Prony算法的Delsuc谱预测是目前NMR LPSVD(Linear Prediction SingularValue Decomposition)法中比较实用的方法。但在高噪声的条件下,时有失峰和假峰出现且要事先知道谱的峰数。本文通过跟踪迭代过程发现Delsuc法的判别因子r_(mis) 很难选定。如果它太小会失峰,而过大又会出现假峰。同时,由于噪声的影响,弱信号的采样点之间的相关性比强信号小,从而在迭代过程中会增加数值不稳定性。文中引入峰面积判据来改善Delsuc法,经模拟与实验均证明结果有效。  相似文献   
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