全文获取类型
收费全文 | 2248篇 |
免费 | 30篇 |
国内免费 | 161篇 |
专业分类
化学 | 2116篇 |
晶体学 | 11篇 |
力学 | 8篇 |
综合类 | 4篇 |
数学 | 58篇 |
物理学 | 242篇 |
出版年
2024年 | 2篇 |
2023年 | 19篇 |
2022年 | 13篇 |
2021年 | 21篇 |
2020年 | 15篇 |
2019年 | 34篇 |
2018年 | 26篇 |
2017年 | 27篇 |
2016年 | 25篇 |
2015年 | 30篇 |
2014年 | 120篇 |
2013年 | 136篇 |
2012年 | 101篇 |
2011年 | 193篇 |
2010年 | 154篇 |
2009年 | 165篇 |
2008年 | 139篇 |
2007年 | 178篇 |
2006年 | 186篇 |
2005年 | 183篇 |
2004年 | 169篇 |
2003年 | 147篇 |
2002年 | 61篇 |
2001年 | 32篇 |
2000年 | 26篇 |
1999年 | 29篇 |
1998年 | 23篇 |
1997年 | 27篇 |
1996年 | 25篇 |
1995年 | 22篇 |
1994年 | 13篇 |
1993年 | 20篇 |
1992年 | 19篇 |
1991年 | 14篇 |
1990年 | 7篇 |
1989年 | 5篇 |
1988年 | 8篇 |
1987年 | 1篇 |
1986年 | 6篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1976年 | 1篇 |
1974年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有2439条查询结果,搜索用时 15 毫秒
1.
Haixing Guan Qianwen Zhang Prof. Dr. Patrick J. Walsh Prof. Dr. Jianyou Mao 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(13):5210-5215
A unique nickel/organic photoredox co-catalyzed asymmetric reductive cross-coupling between α-chloro esters and aryl iodides is developed. This cross-electrophile coupling reaction employs an organic reductant (Hantzsch ester), whereas most reductive cross-coupling reactions use stoichiometric metals. A diverse array of valuable α-aryl esters is formed under these conditions with high enantioselectivities (up to 94 %) and good yields (up to 88 %). α-Aryl esters represent an important family of nonsteroidal anti-inflammatory drugs. This novel synergistic strategy expands the scope of Ni-catalyzed reductive asymmetric cross-coupling reactions. 相似文献
2.
Copper bromide was used as a catalyst for the addition of pyrroles to enones. When both the reactants were used in equimolar amounts, mono and dialkylated products were obtained. However, the use of excess enone furnished only dialkylated products. Thus, copper bromide was shown to be an efficient catalyst for the dialkylation of pyrroles. 相似文献
3.
5-Perfluorophenyl 4,5-dihydro-1H-pyrazoles were synthesized from 1,3-dipolar cycloaddition reaction of perfluorobenyl 2,4,6-triisopropylbenzenesulfonylhydrazone and α,β-unsaturated carbonyl compounds or acrylonitrile in THF or water. It was worthy to note that better results were obtained when water was employed as the solvent, which was considered as an effective, economic and environmentally friendly method to synthesize these pyrazole derivatives. 相似文献
4.
Aldehydes undergo smooth conjugate addition to α,β-unsaturated ketones in the presence of 5-(2-hydroxyethyl)-1,3-thiazolium halides and DBU adsorbed onto the surface of basic alumina under microwave irradiation and solvent-free conditions to afford 1,4-diketones in enhanced yields and reduced reaction times compared to conventional methods. 相似文献
5.
IntroductionOver the past few years, dimethyl carbonate(DMC) has been proven to be an efficientmethylating,methoxylating, and methoxycarbonylating agent inorganic syntheses, in which DMC is used to replace thetoxic methyl halides, dimethyl sulfate or carb 相似文献
6.
The interactive two-state model of cell membrane ion channels in an electric field is formulated on the Bethe lattice by means
of the exact recursion relations. The probability of channel opening or maximum fractions of open potassium and sodium channels
are obtained by solving a non-linear algebraic equation. Using known parameters for the conventional mean-field theory the
model gives a good agreement with the experiment both at low and high trans-membrane potential values. For intermediate voltages,
the numerical results imply that collective effects are introduced by trans-membrane voltage. 相似文献
7.
Peptidic aminopeptidase inhibitors, bestatin, phebestin and probestin have been prepared by stereo- and regiocontrolled reactions from a common α,β-epoxy ester precursor. 相似文献
8.
Maryam Mirza-Aghayan Rabah Boukherroub Mahshid Rahimifard 《Journal of organometallic chemistry》2007,692(23):5113-5116
The palladium(II) chloride/triethylsilane system has been successfully applied for the selective hydrogenation of the carbon-carbon double bond of α,β-unsaturated ketones to yield the corresponding saturated carbonyl compounds. The reaction takes place under mild conditions and affords high yields. 相似文献
9.
Eiko Yasui 《Tetrahedron letters》2006,47(5):743-746
A novel method for synthesizing arylhydrazones, the precursor for Fischer indole synthesis, using aryllithium reagents and α-diazo esters that are easily obtained from α-amino acid esters, is described. 相似文献
10.
催化动力学光度法测定痕量钴(Ⅱ) 总被引:8,自引:0,他引:8
本法基于钴 (Ⅱ )对高碘酸钾氧化孔雀绿的催化作用 ,提出一种灵敏地测定痕量钴 (Ⅱ )的新方法。该方法线性范围在 0~ 0 8μg·2 5mL- 1 ,检测限为 2 1× 10 - 1 0 g·mL- 1 。测定出反应表现活化能Ea=37 94kJ·mol- 1 。此法用于茶叶、维生素B1 2 中钴的测定 ,结果满意 相似文献