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排序方式: 共有160条查询结果,搜索用时 15 毫秒
1.
Minoru Koyama Dr. Takafumi Kawakami Dr. Takashi Okazoe Prof. Dr. Kyoko Nozaki 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(46):10913-10917
Methacrylic esters, represented by methyl methacrylate (MMA), are widely used as commodity chemicals. Here, the one-pot synthesis of methacrylic esters from acetone, a haloform and alcohols in the presence of an organic base is described. Using DBU as the organic base for the reaction of acetone, chloroform and methanol in acetonitrile afforded MMA in 66 % yield. When the solvent was replaced by benzonitrile, the product MMA was successfully purified by distillation. Applicability of this process to various alcohols was also investigated to show ethyl, phenyl, CF3CH2, and n-C6F13CH2CH2 esters were obtained in moderate yields. The use of bromoform instead of chloroform resulted in the improvement of the yield, for example, methyl and n-C6F13CH2CH2 esters up to 81 and 70 %, respectively. The reaction with deuterated starting materials acetone-d6 and MeOH-d4, with DBU in acetonitrile afforded deuterated MMA (MMA-d8) in 70 % yield. 相似文献
2.
The content of residual monomers is one of the most important characteristics of polymer dispersions. As a result of the similar physicochemical parameters of ethyl acrylate and methyl methacrylate, it is very difficult to determine the residual monomers in acrylate dispersions obtained by emulsion polymerization of both monomers. Gas chromatography with capillary columns, however, permits separation of these monomers and their quantitative determination in acrylate dispersions. 相似文献
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聚(C60 甲基丙烯酸甲酯)与聚(C60 苯乙烯)的THF溶液的透射光谱随浓度的增大而不断红移.这种异常的光谱位移可能与富勒烯的纳级(10-9)簇的形成有关.用简单的办法来“调改”一物质的性质是科学家们长期梦寐以求的,而含C60的聚合物正代表了这一群新奇的物质,它们的光学性质可以预期地和可逆地调变,只要简单改变一下浓度. 相似文献
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Copolymerisation of methyl methacrylate with nine novel monomer compounds, triazinyl benzanthrone dyes, triazinyl benzotriazole stabilisers and their combined structures, was investigated. Chemical bonding of the compounds in the polymers obtained was confirmed spectrophotometrically. The quantity of the chemically bonded monomer compounds was determined to be over 50%, providing a colour and a fluorescence stable to solvents. Their influence on the rate of the copolymerisation was studied. It was found that the compounds under study did not significantly affect the rate of copolymerisation. A stabilizing effect towards photo-degradation of PMMA was achieved at 0.1 wt.% initial concentration of the compounds, which made them suitable for “one-step” colouration and stabilisation of PMMA. 相似文献
8.
AIBN/SmCl3/乳酸体系催化甲基丙烯酸甲酯的反向原子转移自由基聚合 总被引:5,自引:0,他引:5
利用稀土金属化合物三氯化钐(SmCl3)和二氯化钐(SmCl2)之间的单电子转移反应,以AIBN/SmCl3/乳酸作为反向原子转移自由基聚合(ReverseATRP)的催化体系,成功地实现了甲基丙烯酸甲酯(MMA)的反向ATRP,并考察了温度、溶剂和组分比对聚合反应的影响.MMA在该体系中的聚合反应是一级反应,所得PMMA的分子量与单体转化率成正比,聚合物的分子量分布较窄(Mw/Mn<1.5),具有活性聚合的特征. 相似文献
9.
Yalan Ning Megan J. Cooney Eugene Y.-X. Chen 《Journal of organometallic chemistry》2005,690(26):6263-6270
Characteristics of methyl methacrylate (MMA) polymerization using oscillating zirconocene catalysts, (2-Ph-Ind)2ZrX2 (X = Cl, 1; X = Me, 2), mixtures of rac- and meso-zirconocene diastereomers, (SBI)ZrMe2 [3, SBI = Me2Si(Ind)2] and (EBI)ZrMe2 [4, EBI = C2H4(Ind)2], as well as diastereospecific metallocene pairs, rac-4/Cp2ZrMe2 (5) and rac-4/CGCTiMe2 [6, CGC = Me2Si(Me4C5)(t-BuN)], are reported. MMA polymerization using the chloride catalyst precursor 1 activated with a large excess of the modified methyl aluminoxane is sluggish, uncontrolled, and produces atactic PMMA. On the other hand, the polymerization by a 2/1 ratio of 2/B(C6F5)3 or 2/Ph3CB(C6F5)4 is controlled and produces syndiotactic PMMA. Mixtures of diastereomeric ansa-zirconocenes 3 or 4 containing various rac/meso ratios, when activated with B(C6F5)3, yield bimodal PMMA; this behavior is attributed to the meso-diastereomer that, in its pure form, affords bimodal, syndio-rich atactic PMMA. For MMA polymerization using diastereospecific metallocene pairs, rac-4/5 and rac-4/6, the isospecific catalyst site dominates the polymerization events under the conditions employed in this study, and the aspecific and syndiospecific sites are largely nonproductive, thereby forming only highly isotactic PMMA. 相似文献
10.
Sm(II)-modified periodic mesoporous silica (PMS), Sm[N(SiHMe2)2]2(THF)x@MCM-41, was used for the synthesis of Sm(II) alkyl, alkoxide, and indenyl surface species via secondary ligand exchange. The performance of the novel Sm(II)-based organometallic–inorganic hybrid materials as initiators for the graft polymerization of methyl methacrylate (MMA) is reported. All of the Sm(II) hybrid materials including the new PMMA–PMS composites were characterized via N2 physisorption, elemental analysis, FTIR spectroscopy, and scanning electron microscopy (SEM). The organic–inorganic composites revealed complete pore blockage as well as enrichment and strong adhesion of the polymer at the exterior of the porous silica material. 相似文献