Large-area hydrated vanadium oxide/carbon nanotube composite films for high-performance aqueous zinc-ion batteries

Science China Chemistry - Synchronously reducing/self-assembling strategy on Zn substrate was designed to fabricate large-area cation-doped hydrated V2O5/multi-walled carbon nanotube (D-HVO/MWCNT)...     

一种饱和Keggin硅钨酸盐过渡金属衍生物[Cu(biim)_2]_4[α-SiW_(12)O_(40)]_2·4H_2O（英文）

在水热环境下,将Na10[α-SiW9O34]爛18H2O和CuCl2爛2H2O在2,2′-联咪唑和4,4′-联吡啶存在下反应合成一种饱和Keggin硅钨酸盐杂化物[Cu(biim)2]4[α-SiW12O40]2爛4H2O(1),并通过红外光谱,X射线光电子能谱和X射线单晶衍射进行了结构表征.化合物1分子包含2个中性的Keggin[Cu(biim)2]2[α-SiW12O40]单元和4个结晶水分子.值得注意的是在[α-SiW12O40]4-单元中,与硅原子相连的每个氧原子无序排列在两个位置,这导致了硅原子呈现立方体的几何构型.中性Keggin型[Cu(biim)2]2[α-SiW12O40]单元具有中心对称性,两个[Cu(biim)2]2+配离子对称连接在[α-SiW12O40]4-的两端.邻近的[Cu(biim)2]2[α-SiW12O40]单元之间通过氢键作用形成三维的超分子结构.     

Synthesis and characterization of novel poly（aryl ether）s containing naphthyl moieties

Two poly(aryl ether)s containing naphthyl moieties were prepared from bis(3,5-dimethyl-4-hydroxyphenyl)naphthyl methane (monomer 1) via nucleophilic aromatic substitution polycondensation with bis(4-fluorophenyl) ketone and bis(4-fluorophenyl) sulfone.The structures of these polymers were confirmed by ~1H NMR.The M_n values of the two polymers were 96,200 and 88,600, respectively.The polymers exhibited good thermal stabilities with 5%mass loss at T>400℃and high glass-transition temperature(T_g) of T>250℃...     

Editorial for Special Issue on Frontiers in Optical Bioimaging

<正>Optical bioimaging has become a very important tool in life science because it is noninvasive, of high specificity, capable of performing multi-parameter measurement,     

光纤受激调制不稳定性的谱理论

利用多重尺度微扰法,直接从包含非线性极化项的麦克斯韦方程组出发,得到了在频域描述光纤中的受激调制不稳定性的谐波耦合方程组,在此基础上,得出了受激调制不稳定性的谱分布的一些数字结果。     

远红外契伦柯夫FEL的动力学理论

契伦柯夫自由电子激光可以产生远红外相干受激辐射。本文建立了契伦柯夫自由电子激光的动力学理论并详细研究了初始信号频率,电子束电压和束—介质膜间隙对器件性能的影响。与自由电子激光,回旋自谐振脉塞比较,指出了短波契伦柯夫自由电子激光的几个显著特点。     

Ce~(3+)∶LiCaAlF_6紫外激光器的研究

报道了利用Nd∶YAG四倍频266nm脉冲激光端面泵浦Ce∶LiCAF晶体,采用平凹谐振腔,输出296nm波长紫外激光.当输出镜透过率为20%,入射泵浦能量为13.5mJ时,获得最大输出激光脉冲能量为270μJ,脉冲宽度为3.4ns,输出激光峰值功率为79.4kW,光-光转换效率为2%,斜效率为1.6%.     

两段级联掺铒光纤放大器的优化研究

基于Giles模型,研究了980 nm和1480 nm泵浦的两段级联掺铒光纤放大器(EDFA)的设计,得出了掺铒光纤(EDF)的最佳长度和光隔离器的最佳位置随泵浦功率和信号功率的变化关系.比较980 nm和1480 nm泵浦的两段级联EDFA,可以发现,前者的最佳EDF长度短,而光隔离器最佳位置距EDFA输入端远.     

一种测量微量有机材料磁化率各向异性的光学方法

提出了一种测量有机材料的磁化率各向异性的方法。原理是利用掺杂对丝状液晶磁场扭曲费雷德里克兹转变影响的现象,将待测有机材料作为掺杂物,采用光学相位延迟法测量掺杂丝状液晶磁场扭曲费雷德里克兹转变阈值和过程,从而获得待测有机材料的磁化率各向异性。通过实验测量,从原理和方法上验证了测量方法的可行性。测得有机材料磁化率各向异性的同时也为有机材料的表征提供了一种方法。测量方法适用于无固有磁矩的有机材料。     

Uptake of transferrin-conjugated quantum dots in single living cells

We study the uptake and distribution of transferrin （Tf）-conjugated CdSe/CdS/ZnS quantum dots （QDs） in single living HeLa cells with both fluorescence confocal microscopy and three-dimensional （3D） reconstruction technique. By increasing the co-incubation time or the dosage of QDs-Tf, we find that the uptake of QDs-Tf bioconjugates in the cells increases correspondingly, but with different uptake rates. Additionally, the distribution of QDs-Tf, in single live HeLa cells is time dependent. To our knowledge, this is the first study on quantitatively analyzing the uptake and distribution of bioconjugated QDs in single living cells. Such QDs nanoplatform can be further modified for developing biomedical evaluation tool in cancer diagnosis and targeted drug delivery.