Flow structures and heat transfer characteristics in arrays of submerged laminar impinging jets

This study summarizes the scaling behavior of single laminar submerged jets with circular and planar cross sections. Unified correlations for the stagnation zone heat transfer of both configurations, based on the dominant dimensionless numbers, are presented. In technical applications, impinging jets are often applied in jet array configurations. Compared to single jet impingement, jet-to-jet interaction can have a substantial influence on local heat transfer. A distinct pattern of the heat transfer coefficient was observed experimentally. Numerical simulations revealed two counter-rotating vortices in the interaction zone between two jets to be the causing mechanism of this pattern. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Arithmetisch definierte Gruppen mit Galoisoperation

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Die maximalen arithmetisch definierten Untergruppen zerfallender einfacher Gruppen

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Two-phase electrohydrodynamic simulations using a volume-of-fluid approach: A comment

This comment refers to the article of Tomar et al. [1], which presents a numerical methodology of a continuum surface force formulation for simulating two-phase electrohydrodynamic flows. The present work shows, that due to the diffusive character of the Laplacian equation (? · (??₀E) = 0) with discontinuous physical properties (?(x, y, z)), different averaging methods (arithmetic and harmonic) for the fluid property in the transition region have to be applied. The correct choice of the averaging method depends on the orientation of the flux to the interface.An additional improvement is made by calculating the electric displacement D at the cell faces. This leads to a numerical solution independent of the spatial resolution as well as of the interfacial smearing. Simulation results of two different test cases show that the error of the numerical solution is in the order of machine precision.     

Über maximale arithmetisch definierte Gruppen

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O<Subscript>2</Subscript> photodesorption from AuO<Stack><Subscript>2</Subscript><Superscript>−</Superscript></Stack> and Au<Subscript>2</Subscript>O<Stack><Subscript>2</Subscript><Superscript>−</Superscript></Stack>

Using time-resolved photoelectron spectroscopy, the decay channels of AuO₂⁻ and Au₂O₂⁻ following photoexcitation with 3.1-eV photons have been studied. For AuO₂⁻, a state with a rather long lifetime of 30 ps has been identified. Its decay path could not be determined but photodesorption can be excluded. For Au₂O₂⁻, the spectra indicate O₂ desorption after 3.1-eV photoexcitation on a time scale of 1 ps. While comparing these results on Au _n O₂⁻ with analogous data on Ag _n O₂⁻ clusters, a discernible pattern emerges: for dissociatively bound O₂(AuO₂⁻, Ag₃O₂⁻), there are long-living excited states which do not decay by oxygen desorption, while for molecular chemisorption (Au₂O₂⁻, Ag₂O₂⁻, Ag₄O₂⁻, Ag₈O₂⁻), the 3.1-eV photoexcitation triggers fast O₂ desorption with a high quantum yield.     

Enantiomerically Pure Tribenzotriquinacenes through Stereoselective Synthesis

Inherently chiral acetophenones and benzaldehydes bearing the large, bowl‐shaped framework of tribenzotriquinacene (TBTQ) were synthesized in enantiomerically pure form employing enzyme catalysis. Five‐step sequences involving lipase CAL‐B lead to the (M)‐enantiomers, (+)‐2‐acetyl‐TBTQ (M)‐ 5 and (+)‐2‐formyl‐TBTQ (M)‐ 6 , whereas use of lipase PS leads to the (P)‐enantiomers, (?)‐2‐acetyl‐TBTQ (P)‐ 5 and (?)‐2‐formyl‐TBTQ (P)‐ 6 , with at least 99 % ee in each case. The absolute configuration of these rigid 3D building blocks was determined by X‐ray diffraction analysis of the ketones 5 and by comparison of their chiroptical properties with those of the aldehydes 6 .