全文获取类型
收费全文 | 8793篇 |
免费 | 1656篇 |
国内免费 | 979篇 |
专业分类
化学 | 5952篇 |
晶体学 | 89篇 |
力学 | 731篇 |
综合类 | 65篇 |
数学 | 1145篇 |
物理学 | 3446篇 |
出版年
2024年 | 8篇 |
2023年 | 180篇 |
2022年 | 207篇 |
2021年 | 294篇 |
2020年 | 343篇 |
2019年 | 321篇 |
2018年 | 288篇 |
2017年 | 283篇 |
2016年 | 426篇 |
2015年 | 414篇 |
2014年 | 455篇 |
2013年 | 641篇 |
2012年 | 755篇 |
2011年 | 839篇 |
2010年 | 560篇 |
2009年 | 537篇 |
2008年 | 616篇 |
2007年 | 487篇 |
2006年 | 525篇 |
2005年 | 388篇 |
2004年 | 323篇 |
2003年 | 260篇 |
2002年 | 247篇 |
2001年 | 208篇 |
2000年 | 195篇 |
1999年 | 194篇 |
1998年 | 195篇 |
1997年 | 183篇 |
1996年 | 173篇 |
1995年 | 141篇 |
1994年 | 119篇 |
1993年 | 113篇 |
1992年 | 93篇 |
1991年 | 71篇 |
1990年 | 75篇 |
1989年 | 64篇 |
1988年 | 49篇 |
1987年 | 36篇 |
1986年 | 36篇 |
1985年 | 22篇 |
1984年 | 19篇 |
1983年 | 15篇 |
1982年 | 15篇 |
1981年 | 3篇 |
1980年 | 7篇 |
1979年 | 2篇 |
1975年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 250 毫秒
1.
Tian Jie Yang Weifeng Chen Min Zheng Minfang Chen Ding Qiu Yusheng 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(2):1039-1049
Journal of Radioanalytical and Nuclear Chemistry - This study presents a time-efficient method of analysing 210Pb, 210Bi, and 210Po in natural waters. The optimum pH (1.00), temperature... 相似文献
2.
Donglei Wei Huili Li Chuanqing Yang Jianmin Fu Hou Chen Liangjiu Bai Wenxiang Wang Huawei Yang Lixia Yang Ying Liang 《Journal of polymer science. Part A, Polymer chemistry》2022,60(10):1588-1594
Acridone as a new kind of visible light photocatalyst has been developed to catalyze metal free atom transfer radical polymerization (ATRP). The photocatalyst possess low excited state potential as can undergo an oxidative quenching pathway to initiate ATRP of vinyl monomers. Kinetic study and light on/off reaction demonstrate the “living”/controlled nature of the polymerization by light. Block copolymers can be achieved by using PMMA as macroinitiator to reinitiate polymerization of other vinyl monomers, which shows highly preserved Br chain-end functionality in the synthesized polymers. Moreover, the polymerization can be conducted under air atmosphere as most photocatalysts need anaerobic condition, which may give inspiration of further application of this kind of photocatalyst. 相似文献
3.
4.
Peng-Yan Gui Xiao-Hui Yan Wen-Juan Yuan Yuan-Liang Ma Xiao Ding Shuai Liu 《Natural product research》2019,33(19):2830-2836
A new A, D-seco limonoid, named 12-acetyloxyperforatin (1), along with three known ones, were isolated from the leaves of Harrisonia perforata. Their structures were elucidated on the basis of spectroscopic analysis, including extensive NMR techniques and computational modelling. These compounds showed no inhibitory activity against the 11β-HSD1 enzyme. 相似文献
5.
Nonlinear Dynamics - Conventional tuned liquid column dampers (TLCDs) are deficient in multidirectionality. In contrast, toroidal TLCDs are designed to extend the application to multidirectional... 相似文献
6.
Science China Chemistry - 相似文献
7.
Ding Q. Yao M. Wu Sh. Zeng M. Xue N. Wu D. Xu J. 《Journal of Applied Spectroscopy》2022,89(4):712-718
Journal of Applied Spectroscopy - Based on partial least squares (PLS) analysis, the effects of different smoothing points and different preprocessing methods on the accuracy and precision of the... 相似文献
8.
9.
The discharge of diverse pollutants has led to a complex water environment and posed a huge health threat to humans and animals. Self-propelled micromotors have recently attracted considerable attention for efficient water remediation due to their strong localized mass transfer effect. However, a single functionalized component is difficult to tackle with multiple contaminants and requires to combine different decontamination effects together. Here, we introduced a multifunctional micromotor to implement the adsorption and degradation roles simultaneously by integrating the poly(aspartic acid) (PASP) adsorbent with a MnO2-based catalyst. The as-prepared micromotors are well propelled in contaminated waters by MnO2 catalyzing hydrogen peroxide. In addition, the catalytic ramsdellite MnO2(R-MnO2) inner layer is decorated with Fe2O3 nanoparticles to improve their catalytic performance, contributing to an excellent degradation ability with 90% tetracycline (TC) removal in 50 minutes by enhanced Fenton-like reactions. Combining the attractive adsorption capability of poly (aspartic acid) (PASP), the composite micromotors offer an efficient removal of heavy metal ions in short time. Moreover, the designed micromotors are able to simultaneously remove antibiotic and heavy metals in mixed contaminants circumstance just in single treatment. This multifunctional micromotor with distinctive decontamination ability exhibits a promising prospective in treating multiple pollutants in the future. 相似文献
10.
Dr. Feifan Wang Jie Tian Dr. Mengzhu Li Dr. Weizhen Li Dr. Lifang Chen Xiaozhi Liu Dr. Jian Li Aidaer Muhetaer Prof. Dr. Qi Li Prof. Dr. Yuan Wang Prof. Dr. Lin Gu Prof. Dr. Ding Ma Prof. Dr. Dongsheng Xu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(21):8280-8286
Fully utilizing solar energy for catalysis requires the integration of conversion mechanisms and therefore delicate design of catalyst structures and active species. Herein, a MOF crystal engineering method was developed to controllably synthesize a copper–ceria catalyst with well-dispersed photoactive Cu-[O]-Ce species. Using the preferential oxidation of CO as a model reaction, the catalyst showed remarkably efficient and stable photoactivated catalysis, which found practical application in feed gas treatment for fuel cell gas supply. The coexistence of photochemistry and thermochemistry effects contributes to the high efficiency. Our results demonstrate a catalyst design approach with atomic or molecular precision and a combinatorial photoactivation strategy for solar energy conversion. 相似文献