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排序方式: 共有1347条查询结果,搜索用时 15 毫秒
1.
Journal of Structural Chemistry - Atomic and electronic structures of cyclic organosilicon compound 9,9,10,10-tetraethynyl-9,10-dihydrodisilaanthracene are studied by the density functional theory.... 相似文献
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E. S. Zhukova A. S. Prokhorov I. E. Spektor V. A. Karavanskiĭ N. N. Mel’nik T. N. Zavaritskaya B. P. Gorshunov 《Physics of the Solid State》2007,49(12):2242-2250
The dielectric response (conductivity and permittivity) spectra of a series of nanoporous silicon samples prepared by anodization of low-resistivity single-crystal silicon are measured, for the first time, using terahertz and IR spectroscopy in the frequency range 7–4000 cm?1 at room temperature. The spectra obtained are analyzed in terms of the effective medium theory with a size-dependent dielectric response function of nanoinclusions and averaged dielectric characteristics of the surrounding medium. The geometric and dielectric characteristics of silicon nanoinclusions are determined. The dielectric properties of inclusions are found to be affected by nanosize effects, namely, carrier scattering at crystallite boundaries and a broadening of the band gap due to quantum confinement. The spectra of the samples prepared by adding iodine to the electrolyte exhibit a resonance at frequencies of 150–300 cm?1. The nature of the resonance can be associated with the presence of chemisorbed iodine on the surface of porous silicon. Possible mechanisms responsible for the changes in broadband conductivity and permittivity spectra of single-crystal silicon upon transformation into a nanoporous structure are discussed. 相似文献
4.
Multi-dimensional asymptotically quasi-Toeplitz Markov chains with discrete and continuous time are introduced. Ergodicity
and non-ergodicity conditions are proven. Numerically stable algorithm to calculate the stationary distribution is presented.
An application of such chains in retrial queueing models with Batch Markovian Arrival Process is briefly illustrated.
AMS Subject Classifications Primary 60K25 · 60K20 相似文献
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Michelina Soccio Lara Finelli Nadia Lotti Valentina Siracusa Tiberio A. Ezquerra Andrea Munari 《Journal of Polymer Science.Polymer Physics》2007,45(13):1694-1703
Poly(butylene naphthalate) (PBN), poly(diethylene naphthalate) (PDEN), and poly(thiodiethylene naphthalate) (PTDEN) were synthesized and characterized in terms of chemical structure and molecular weight. The polyesters were examined by TGA, DSC, and DMTA. All the polymers showed a good thermal stability, even though depending on chemical structure. At room temperature they appeared as semicrystalline materials; the effect of the introduction along the PBN polymer chain of ether oxygen atoms or sulfur ones was a lowering in the Tg value, a decrement of Tm, and a decrease of the crystallization rate. Changing in chemical structure also affects the main α absorption associated with the glass transition which moves to lower temperature and whose energetic requirements decrease. The results were explained as due to the presence of highly flexible C? S? C or C? O? C bonds in the polymeric chain. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1694–1703, 2007 相似文献
7.
Carlo Carlini Valentina De Luise Anna Maria Raspolli Galletti Glauco Sbrana 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):200-206
Novel catalytic systems, prepared in situ by the oxidative addition of 8‐hydroxyquinoline ligands to bis(1,5‐cyclooctadiene)nickel(0) and activated by methylaluminoxane, were studied in ethylene polymerization. When 8‐hydroxyquinoline was employed, only oligomeric products were obtained. On the contrary, 5,7‐dinitro‐8‐hydroxyquinoline gave linear polyethylene (PE), but with a modest activity. For the catalyst based on 5‐nitro‐8‐hydroxyquinoline, the productivity was largely dependent on the content of free trimethylaluminum (TMA) present in the commercial aluminoxane. The progressive optimization of the TMA/oligomeric methylaluminoxane ratio increased the productivity, which reached 700 kg of PE/(mol of Ni × h), by an order of magnitude. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 200–206, 2006 相似文献
8.
Rastislav Varga Arcady Zhukov Michail Ipatov Juan Maria Blanco Julian Gonzalez Valentina Zhukova Pavol Vojtanik 《Journal of magnetism and magnetic materials》2006
The effect of the glass coating on the single domain wall potential in amorphous glass-coated Fe-based microwire has been studied by the switching field distribution technique. The thermoactivated mechanism model is used to describe the thermally activated switching through the complex energy barrier in amorphous FeSiB microwires. Glass removal leads to the increase of the probability of the thermally activated switching pointing to the decrease of the energy barrier. 相似文献
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G. Z. Zhukova 《Ukrainian Mathematical Journal》1990,42(10):1262-1266
Solutions with asymptotics in integral and fractional powers of the parameter ? are constructed for the vector differential equation $$\varepsilon ^h \dot X = A(t,\varepsilon ) X + \varepsilon ^{\alpha _1 } p(t,\varepsilon ) \exp \left( {\varepsilon ^{ - h} \int\limits_0^t {\lambda (\tau )d\tau } } \right)$$ in the case of resonance and multiple spectrum of the limit matrix. $$\varepsilon ^h \dot X = A(t,\varepsilon ) X + \varepsilon ^{\alpha _1 } p(t,\varepsilon ) \exp \left( {\varepsilon ^{ - h} \int\limits_0^t {\lambda (\tau )d\tau } } \right)$$ 相似文献
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