Observation of complete- and incomplete-fusion components in <Superscript>159</Superscript>Tb , <Superscript>169</Superscript>Tm ( <Superscript>16</Superscript>O,x) reactions: Measurement and analysis of forward recoil ranges at E/A ≈ 5-6 MeV

With a view to study complete- and incomplete-fusion components in ¹⁵⁹Tb , ¹⁶⁹Tm ( ¹⁶O , x reactions, experiments have been carried out at the Inter-University Accelerator Center, New Delhi, India using the 15UD Pelletron accelerator facilities. The forward mean recoil ranges for some radio-nuclides; ^168m Lu , ¹⁶⁷Lu , ¹⁶⁷Yb , ¹⁶⁶Tm produced in the ¹⁶O$ + $¹⁵⁹Tb system at ≈ 90 MeV, and ¹⁷⁹Re , ¹⁷⁷Re , ¹⁷⁷W , ¹⁷⁸Ta and ¹⁷⁷Hf produced in the ¹⁶O$ + $¹⁶⁹Tm system at ≈ 87 MeV have been measured. The recoil-catcher activation technique followed by off-line γ -spectrometry has been employed in the present work. The analysis of forward mean ranges for different radio-nuclides has been done in the framework of the degree of linear momentum transfer from projectile to target nucleus by adopting break-up fusion model considerations. Different complete- and incomplete-fusion components, which may be attributed to the fusion of ¹⁶O and/or ¹²C and ⁸Be transfer from the ¹⁶O projectile to the target nucleus have been observed. An attempt has also been made to separate out the relative percentage contributions of complete- and incomplete-fusion components using experimentally measured forward recoil ranges. The complete-fusion contributions deduced from recoil range distribution are found to be consistent with the prediction of the theoretical model code PACE. The analysis of data indicates the complete- and incomplete-fusion competition for both the systems at the given energies.     

Highly efficient and green synthesis of spiro[indoline-3,9′-xanthene]trione and spiro[chromene-4,3′-indoline]-3-carbonitrile derivatives in water catalyzed by graphene oxide-supported dicationic ionic liquid

Research on Chemical Intermediates - In this article, a mild and highly efficacious synthetic route has been developed for the synthesis of spiro[indoline-3,9′-xanthene]trione and...     

New palladium(II)-catalyzed asymmetric 1,2-dibromo synthesis

[reaction: see text] The oxidation of olefins by chiral monometallic and bimetallic Pd(II)-Cu(II) catalysts in bromide-containing aqueous-THF reaction mixtures produced chiral 1,2-dibromides. With alpha-olefins, the ee's were about 95% while most of the internal alkenes gave somewhat lower enantioselectivities ( approximately 80%).     

A study of pre-equilibrium emission of neutrons in <Superscript>93</Superscript>Nb(α, xn) reactions

With a view to study the pre-equilibrium emission mechanism in α-induced reactions the excitation functions for ⁹³Nb(α, n)^96m Tc, ⁹³Nb(α, n)⁹⁶Tc, ⁹³Nb(α, 2n)^95m Tc, ⁹³Nb(α, 2n)^95g Tc and ⁹³Nb(α, 3n)⁹⁴Tc reactions have been measured in the energy range threshold to ≈ 10MeV/nucleon using the activation technique. The measured excitation functions have also been compared with theoretical predictions based on the semi-classical code, which takes into account compound nucleus as well as pre-equilibrium emission. The analysis of the data indicates significant contribution from pre-equilibrium emission at these energies particularly in the high-energy tail portion of EFs. The effect of the variation of the parameters used in the code has been studied. The isomeric cross-section ratios have also been measured. It has been observed that the pre-equilibrium fraction increases rapidly with the increase in α-particle bombarding energy.