Coalescence process of monodispersed Co cluster assemblies

Cluster-cluster coalescence process of monodispersed Co clusters with mean diameter d = 8.5 and 13 nm deposited a plasma-gas-condensation-type cluster beam deposition system was investigated by in situ electrical conductivity measurements and ex situ scanning electron microscopy (SEM) and transmission electron microscopy (TEM), and analyzed by percolation concept. The electrical conductivity measurement and TEM observation indicated that, below temperature T≈ 100^°C, the Co clusters in the assemblies maintain their original structure as deposited at room temperature, while that the inter-cluster coalescence takes place at T > 100^°C, although the size distribution and the interface morphology of the clusters showed no marked change at substrate temperatures T _s≤200^°C. Received 29 November 2000     

Formation and characterization of high-density Fe cluster-assembled films with soft magnetic behaviors

High-density, magnetically soft Fe cluster-assembled films were obtained at room temperature by an energetic cluster deposition. Size-monodispersed Fe clusters with the mean cluster size d = 9, 13 and 16 nm were produced using a plasma-gas-condensation technique. Ionized clusters in cluster beam were accelerated electrically and deposited onto the substrate together with neutral clusters from the same cluster source. The morphology, microstructure and magnetic properties of the cluster-assembled films have been studied by an atomic force microscopy, scanning electron microscopy, transmission electron microscopy, and superconducting quantum interference device magnetometer. By increasing the impact energy of the ionized clusters up to 0.6 eV/atom, the Fe cluster-assembled film has a packing fraction of 0.86±0.03, and reveals a soft magnetic behavior. In addition, it is found that oxidization of the cluster-assembled films is remarkably suppressed with the increase in the density of the films.     

Fe–Si core/Si-shell clusters prepared by double glow discharge sources

Journal of Nanoparticle Research - Using an improved plasma gas condensation cluster deposition system, Fe and Si clusters are prepared by a single glow discharge source and Fe/Si hybrid clusters...     

The amorphous structure of immiscible Fe---Cu---Ag alloys

By means of facing target dc sputtering, an amorphous phase has been produced for immiscible Fe---Cu---Ag alloys at around the central concentration of the ternary phase diagram. The radial distribution function estimated from X-ray diffraction measurements indicates that a tetrahedron is the dominant structure unit and that the average coordination number is about 11. In the extended X-ray absorption fine structure radial structure function, a clear peak is detected at the nearest neighbor distance, but the peak intensity is weaker than those for binary crystalline Fe---Cu and Fe---Ag alloys and no clear peak is detectable at larger distances. A hard or soft sphere dense random packing model is appropriate for the amorphous structure in these immiscible alloys.     

FINITE RINGS WITH COMMUTING NILPOTENT ELEMENTS

As a generalization of Wedderburn's theorem, Herstein [5] proved that a finite ring R is commutative, if all nilpotent elements are contained in the center of R. However a finite ring with commuting nilpotent elements is not necessarily commutative. Recently, in [9] and [10], Simons described the structure of finite rings R with J(R)² = 0 in a variety with definable principal congruences. In this paper, we will consider the difference between the finite commutative rings and the finite rings in which any two nilpotent elements commute with each other. As a consequence, we describe the structure of finite rings R with [J(R), J(R)] = 0 in a variety with definable principal congruences.     

Preparation and characterization of the ZnO:Al/Fe65Co35/ZnO:Al multifunctional films

The ferromagnetic transparent conducting film is a multifunctional film which has high visible transmittance, low resistivity and room-temperature ferromagnetism, simultaneously. In this article, ferromagnetic transparent conducting ZnO:Al/Fe₆₅Co₃₅/ZnO:Al multilayer films were fabricated by inserting a middle magnetic Fe₆₅Co₃₅ layer into aluminum-doped zinc oxide (ZnO:Al) matrix using a magnetron sputtering apparatus at substrate temperature ranging from room temperature (RT) to 400^∘C. The total film thickness was about 400 nm and the middle Fe₆₅Co₃₅ alloy layer was 4 nm. The influences of substrate temperature (T _s ) on the structural, electrical, optical and magnetic properties of the multilayer films were systemically investigated. The results showed that the microstructure and performance of the composite multilayer films strongly depended on the substrate temperature. The present results also showed that the inserted middle Fe₆₅Co₃₅ alloy thin layer played an important role in providing the RT ferromagnetism and decreasing the resistivity of the multilayer films. Therefore, it is possible to obtain a multifunctional film material with the combination of good optical transparency, high electrical conductivity and RT ferromagnetism.     

Magnetic properties of a non-equilibrium Al(Fe–Ni) alloy powder by rod-milling and chemical leaching

In this paper, the magnetic properties of non-equilibrium nanocrystalline phase by chemical leaching of as-milled Al_0.6(Fe_0.5Ni_0.5)_0.4 powder is reported. X-ray diffractometry (XRD), transmission electron microscopy (TEM), differential scanning calorimetry (DSC), vibrating sample magnetometry (VSM), and superconducting quantum interference device magnetometry (SQUID) were used to characterize the as-milled powder and leached specimens. The saturation magnetization M_s decreased approximately 15 times than that of the powder before milling. Magnetization sharply increased to approximately 580 °C, when cooling of the specimen from 750 °C. The broad peaks of the magnetization shifted towards a lower-temperature side and the peak intensity increased, with increasing external field. The irreversibility between the field-cooling (FC) and zero-field cooling (ZFC) for the specimen begins greatly above the wide ZFC magnetization maximum and occurs at relatively high temperature. The magnetization is higher at lower temperatures, with increasing external field.     

Mössbauer study of high concentration Fe−Ag alloys produced by vapour quenching

Mössbauer spectra have been observed for Fe?Ag alloys sputter-deposited on liquid nitrogen cooled substrates and water cooled substrates under several Ar gas pressures, P_Ar. The magnetic hyperfine field does not depend on the substrate temperature. However, in paramagnetic spectra, a single line component corresponding to isolated Fe atoms in the Ag matrix is more pronounced for the alloys deposited on liquid nitrogen cooled substrates. The alloys deposited under high P_Ar reveal very weak intensity ratios of the second and fifth lines of the ferromagnetic sextet, indicating a tendency of perpendicular magnetic anisotropy.