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排序方式: 共有537条查询结果,搜索用时 31 毫秒
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Timothy R. Totsch Victoria L. Stanford Oleksander Klep Mary K. Burdette Benjamin Grant Stephen H. Foulger Gary M. Gray 《Journal of polymer science. Part A, Polymer chemistry》2020,58(13):1825-1842
Linear polyphosphonates with the generic formula –[P(Ph)(X)OR′O]n– (X = S or Se) have been synthesized by polycondensations of P(Ph)(NEt2)2 and a diol (HOR′OH = 1,4-cyclohexanedimethanol, 1,4-benzenedimethanol, tetraethylene glycol, or 1,12-dodecanediol) followed by reaction with a chalcogen. Random copolymers have been synthesized by polycondensations of P(Ph)(NEt2)2 and mixture of two of the diols in a 2:1:1 mol ratio followed by reaction with a chalcogen. Block copolymers with the generic formula –[P(Ph)(X)OR′O](x + 2) –[P(Ph)(X)OR′O](x + 3)– (X = S or Se) have been synthesized by the polycondensations of Et2N[P(Ph)(X)OR′O](x + 2)P(Ph)NEt2 oligomers with HOR′O[P(Ph)(X)OR′O](x + 3)H oligomers followed by reaction with a chalcogen. The Et2N[P(Ph)(X)OR′O](x + 2)P(Ph)NEt2 oligomers are prepared by the reaction of an excess of P(Ph)(NEt2)2 with a diol while the HOR′O[P(Ph)(X)OR′O](x + 3)H oligomers are prepared by the reaction of P(Ph)(NEt2)2 with an excess of the diol. In each case the excess, x is the same and determines the average block sizes. All of the polymers were characterized using 1H, 13C{1H}, and 31P{1H} NMR spectroscopy, TGA, DSC, and SEC. 31P{1H} NMR spectroscopy demonstrates that the random and block copolymers have the expected arrangements of monomers and, in the case of block copolymers, verifies the block sizes. All polymers are thermally stable up to ~300°C, and the arrangements of monomers in the copolymers (block vs. random) affect their degradation temperatures and Tg profiles. The polymers have weight average MWs of up to 3.8 × 104 Da. 相似文献
3.
Rotem Shemesh Maksym Krepker Diana Goldman Yael Danin‐Poleg Yechezkel Kashi Nadav Nitzan Anita Vaxman Ester Segal 《先进技术聚合物》2015,26(1):110-116
Active antimicrobial packaging is a promising form of active packaging that can kill or inhibit microorganism growth in order to maintain product quality and safety. One of the most common approaches is based on the release of volatile antimicrobial agents from the packaging material such as essential oils. Due to their highly volatile nature, the challenge is to preserve the essential oils during the high‐temperature melt processing of the polymer, while maintaining high antimicrobial activity for a desired shelf life. This study suggests a new approach in order to achieve this goal. Antimicrobial active films are developed based on low‐density polyethylene (LDPE), organo‐modified montmorillonite clays (MMT) and carvacrol (used as an essential oil model). In order to minimize carvacrol loss throughout the polymer compounding, a pre‐compounding step is developed in which clay/carvacrol hybrids are produced. The hybrids exhibit a significant increase in the d‐spacing of clay and enhanced thermal stability. The resulting LDPE/(clay/carvacrol) films exhibit superior and prolonged antibacterial activity against Escherichia coli and Listeria innocua, while polymer compounded with pure carvacrol loses the antibacterial properties within days. The films also present an excellent antifungal activity against Alternaria alternata, used as a model plant pathogenic fungus. Furthermore, infrared spectroscopy analysis of the LDPE/(clay/carvacrol) system displayed significantly higher carvacrol content in the film as well as a slower out‐diffusion of the carvacrol molecules in comparison to LDPE/carvacrol films. Thus, these new films have a high potential for antimicrobial food packaging applications due to their long‐lasting and broad‐spectrum antimicrobial efficacy. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
4.
Many complex unsteady mechanisms are thought to facilitate the high efficiency and agility commonly observed in small biological flyers. One of these, the flexible clap and fling maneuver, has not been extensively studied; an experimental characterization is the focus of this work. The clap–fling mechanism is approximated with a single flexible membrane flapping wing, replacing the symmetry plane between two wings with a splitter plate simulating the pair wing. This produces a complex vibro-impact aeroelastic problem, the deformation resulting from which is measured with a high-speed visual image correlation system. A low-dimensional representation of the ensuing large data set is obtained with proper orthogonal decomposition. The POD modes, and the relative importance of each, can help elucidate crucial mechanisms and relationships within the flapping system, and are computed for various membrane wing structures and flapping frequencies, with or without the presence of the splitter plate. 相似文献
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In the theory of function spaces it is an important problem to describe the differential properties for the classical Bessel and Riesz potentials as well as for their generalizations. Bessel potentials are determined by the convolutions of functions with Bessel-MacDonald kernels G α. In this paper we characterize the integral properties of functions by their decreasing rearrangements. The differential properties of potentials are characterized by their modulus of continuity of order k in the uniform norm. Estimates of such type were obtained by A. Gogatishvili, J. Neves, and B. Opic in the case k > α. Here, we remove this restriction and obtain the results for all values k ∈ N. We find order-sharp estimates from above for moduli of continuity and construct the examples confirming the sharpness. On the base of these results we obtain the order-sharp estimates for continuity envelope function in the space of potentials, and give estimates for the approximation numbers of the embedding operator. 相似文献
7.
Michael C. Haibach Nicholas Lease Prof. Alan S. Goldman 《Angewandte Chemie (International ed. in English)》2014,53(38):10160-10163
The development of efficient catalytic methods to cleave the relatively unreactive C? O bonds of ethers remains an important challenge in catalysis. Building on our group’s recent work, we report the dehydroaryloxylation of aryl alkyl ethers using pincer iridium catalysts. This method represents a rare fully atom‐economical method for ether C? O bond cleavage. 相似文献
8.
Distinct Spatial Relationship of the Interleukin‐9 Receptor with Interleukin‐2 Receptor and Major Histocompatibility Complex Glycoproteins in Human T Lymphoma Cells 下载免费PDF全文
9.
William Stanford 《Mathematical Social Sciences》2011,62(2):91-94
We list and prove a family of binomial identities by calculating in two ways the probabilities of approximate saddlepoints occurring in random m×n matrices. The identities are easily seen to be equivalent to the evaluation of a family of Gauss 2F1 polynomials according to a formula of Vandermonde. We also consider some implications concerning the number of approximate pure strategy Nash equilibria we can expect in large matrix zero-sum and team games. 相似文献
10.
B. Löhden S. Kuznetsova K. Sengstock V. M. Baev A. Goldman S. Cheskis B. Pálsdóttir 《Applied physics. B, Lasers and optics》2011,102(2):331-344
Intracavity absorption spectroscopy with a broadband Er3+-doped fiber laser is applied for the measurements of several molecular species revealing quantitative information about the
gas concentration, temperature and chemical reactions in flames. The spectral range of measurements extends from 6200 cm−1 to 6550 cm−1 with the proper choice of the fiber length and by moving an intracavity lens. With a pulsed laser applied in this experiment,
the sensitivity to absorption corresponds to an effective absorption path length of 3 km assuming the cavity is completely
filled with the sample. For a cw laser, the effective absorption path length is estimated to be 50 km. Absorption spectra
of various molecules such as CO2, CO, H2O, H2S, C2H2 and OH were recorded separately in the cell and/or in low-pressure methane and propane flames. The presented measurements
demonstrate simultaneous in situ detection of three molecular products of chemical reactions at different flame locations.
Variation of the relative strengths of OH absorption lines with the temperature enables the estimation of the local flame
temperature. The sensitivity of this laser does not depend on the broadband cavity losses and it can be used for in situ measurements
of absorption spectra in hostile environments such as contaminated samples, flames or combustion engines. The presented technique
can be applied for various diagnostic purposes, such as in environmental, combustion and plasma research, in medicine and
in the determination of stable isotope ratios. 相似文献