全文获取类型
收费全文 | 625篇 |
免费 | 27篇 |
国内免费 | 23篇 |
专业分类
化学 | 479篇 |
晶体学 | 6篇 |
力学 | 5篇 |
数学 | 44篇 |
物理学 | 141篇 |
出版年
2023年 | 4篇 |
2022年 | 6篇 |
2021年 | 6篇 |
2020年 | 4篇 |
2019年 | 3篇 |
2018年 | 5篇 |
2017年 | 7篇 |
2016年 | 12篇 |
2015年 | 17篇 |
2014年 | 12篇 |
2013年 | 46篇 |
2012年 | 32篇 |
2011年 | 40篇 |
2010年 | 19篇 |
2009年 | 14篇 |
2008年 | 49篇 |
2007年 | 43篇 |
2006年 | 53篇 |
2005年 | 40篇 |
2004年 | 38篇 |
2003年 | 28篇 |
2002年 | 20篇 |
2001年 | 9篇 |
2000年 | 9篇 |
1999年 | 9篇 |
1998年 | 5篇 |
1997年 | 7篇 |
1996年 | 7篇 |
1995年 | 6篇 |
1992年 | 7篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1985年 | 11篇 |
1984年 | 13篇 |
1983年 | 7篇 |
1982年 | 6篇 |
1981年 | 8篇 |
1980年 | 5篇 |
1979年 | 7篇 |
1978年 | 4篇 |
1977年 | 5篇 |
1976年 | 3篇 |
1973年 | 3篇 |
1968年 | 2篇 |
1955年 | 2篇 |
1954年 | 2篇 |
排序方式: 共有675条查询结果,搜索用时 15 毫秒
1.
本文研究表明通过膜厚控制和表面等离激元增强方法可有效区分隐藏界面和空气表面的和频振动光谱信号. 以氟化钙基底支撑的PMMA薄膜为模型,观察到隐藏界面和空气表面对和频信号贡献的变化. 通过监控羰基和甲基伸缩振动基团,发现薄PMMA膜的和频信号来自PMMA/空气表面的化学基团-CH2、-CH3、-OCH3和C=O,而厚PMMA膜的和频信号则来自基底/PMMA埋层界面的-OCH3和C=O基团. 随制膜浓度增大,埋层界面C=O基团的取向角从65°下降到43°,且浓度大于或等于0.5 wt%时,取向角等于45°±2°. 相比之下,空气表面C=O的取向角落在21°∽38°之间. 在金纳米棒存在条件下,表面等离激元可以极大地增强和频信号,尤其是来自埋层界面信号. 相似文献
2.
Dr. Chuanzhao Li Renlong Zhu Zhe Yang Jing Lai Dr. Junjun Tan Prof. Yi Luo Prof. Shuji Ye 《Angewandte Chemie (International ed. in English)》2023,62(7):e202214208
We demonstrate that an ordered 2D perovskite can significantly boost the photoelectric performance of 2D/3D perovskite heterostructures. Using selective fluorination of phenyl-ethyl ammonium (PEA) lead iodide to passivate 3D FA0.8Cs0.2PbI3, we find that the 2D/3D perovskite heterostructures passivated by a higher ordered 2D perovskite have lower Urbach energy, yielding a remarkable increase in photoluminescence (PL) intensity, PL lifetime, charge-carrier mobilities (ϕμ), and carrier diffusion length (LD) for a certain 2D perovskite content. High performance with an ultralong PL lifetime of ≈1.3 μs, high ϕμ of ≈18.56 cm2 V−1 s−1, and long LD of ≈7.85 μm is achieved in the 2D/3D films when passivated by 16.67 % para-fluoro-PEA2PbI4. This carrier diffusion length is comparable to that of some perovskite single crystals (>5 μm). These findings provide key missing information on how the organic cations of 2D perovskites influence the performance of 2D/3D perovskite heterostructures. 相似文献
3.
4.
Tomoko Kemmei Shuji Kodama Atsushi Yamamoto Yoshinori Inoue Kazuichi Hayakawa 《Analytica chimica acta》2015
We describe a simple and sensitive liquid chromatographic method for the analysis of organic acids using on-line complexation with copper(II) ion. Organic acids complexed with copper(II) ion were separated on a reversed-phase C18 column and detected by UV absorption at 240 nm. The copper(II) ion concentration in the mobile phase had a great influence on separation and sensitivity. A mobile phase consisting of 10 mM copper(II) sulfate in 5 mM sulfuric acid (pH 2.3) was used to separate nine organic acids (tartaric, malic, malonic, lactic, acetic, citric, maleic, succinic and fumaric acids). The detection limits of the examined organic acids calculated at S/N = 3 ranged from 0.6 to 100 μM. The detector signal was linear over three orders of magnitude of organic acid concentration. The method successfully measured organic acids in juice and vinegar samples. 相似文献
5.
Tae Seok Kwon Sadanori Kumazawa Shuji Kondo† Koji Takagi Hideo Kunisada Yasuo Yuki 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(12):1895-1913
Abstract 1,4-Bis(p-tert-butylphenylselenomethyl) benzene was synthesized, and used as a bifunctional photoiniferter for the polymerization of styrene. Both the polymer yields and the number average of molecular weights (n) of polymers increased with the polymerization. The polymerization of styrene by this iniferter permitted telechelic polystyrene containing arylseleno groups at both chain ends, and the degree of functionality was 1.9. The seleno groups of both chain ends of polystyrene were reduced quantitatively by tri-n-butyltin hydride. These seleno groups in polystyrene were also eliminated by treatment with hydrogen peroxide to give telechelic polystyrene with carbon-carbon double bond at both chain ends. Further, polystyrene with double bonds was converted to telechelic polystyrene carrying terminal functional groups as epoxy, hydroxy, and iodide group, respectively. 相似文献
6.
The photoinitiating ability of some sulfur ylides was studied. Diphenylsulfonium bis (methoxycarbony1)methylide (DPSY) could photoinitiate methyl methacrylate and styrene. A free radical mechanism was confirmed by a kinetic study, the inhibiting effect of benzoquinone, and the copolymer composition. From an analysis of the photodecomposition products it is suggested that the phenyl radical generated from the bond fission between the sulfur atom and the phenyl group participates in the initiation of this free radical polymerization. Methylphenylsulfonium bis (methoxycarbonyl) methylide, as well as DPSY, served as a photoinitiator, but dimethylsulfonium bis (methoxycarbony1)methylide did not. The differences are explained based on UV spectra. 相似文献
7.
Optical Review - In this study, the effects of selectively yellow-cut lenses on contrast sensitivity were investigated in healthy young and middle-aged individuals and elderly patients with... 相似文献
8.
Shuji Saito 《应用光谱学评论》2013,48(3-4):261-296
Abstract Modern radio astronomy has revealed that various kinds of molecules exist in ther very cold region between stars: interstellar space. An electromagnetic wave with a wavelength of a few centimeters to 1 mm corresponds in energy to a few to ten degrees of Kelvin. A molecule having its spectrum in this energy region provides us with valuable information about the low-energy environment where the molecule exists. New information provided by radio astronomy has rarely been 相似文献
9.
10.
Miyauchi Suguru Yamada Shuji Takeuchi Shintaro Tazaki Asahi Kajishima Takeo 《Transport in Porous Media》2022,141(1):185-199
Transport in Porous Media - A concise and accurate prediction method is required for membrane permeability in chemical engineering and biological fields. As a preliminary study on this topic, we... 相似文献