On Laser-Induced High-Order Wave Mixing and Harmonic Generation in a Graphene Quantum Dot

JETP Letters - We present results of numerical investigations of high-order wave mixing/harmonic generation (HWM/HHG) with many-body interaction processes derived by a strong two-frequency circular...     

Broadening and Shift of the D1 and D2 Lines of Rb Atoms by Neon: Resolving Hyperfine Components in a Half-Wave Cell Using Double Differentiation with Respect to Frequency

Optics and Spectroscopy - A cell with a submicron thickness was used to measure the broadening and shift of the D1 and D2 lines of Rb atoms by neon. The resolution of hypefine components...     

From Dinuclear Systems to Close Binary Stars and Galaxies

The evolution of close binary cosmic objects in the mass-asymmetry coordinate is considered. Conditions for the formation of stable symmetric binary stars and galaxies are analyzed. The role of symmetrization of an asymmetric binary system in the transformation of the potential energy into the internal energy and in the release of a large amount of energy is explained.     

Tannin-Mordant Coloration with Matcha (camelia sinensis) and Iron(II)-Lactate on Human Hair Tresses

The aim of this work was to optimize our natural hair dyeing system which we described in our previous work and to compare with other dyeing systems. Therefore, we investigated concentration limits of matcha and mordant and compared this new dyeing method with commercial permanent systems on the market. Completely unpigmented hair tresses were dyed with matcha powder (camelia sinensis) and iron(II)-lactate. To investigate the wash fastness and concentration limits, the differently dyed hair tresses were spectrophotometrically measured. The comparison of the damage potential for which cysteic acid is an indicator was measured by NIR. The concentration of matcha and mordant are responsible for the intensity of the color results. The higher the matcha or the mordant concentration, the darker the color results of the dyed hair tresses. Hair damage of matcha mordant dyeing is comparable with results of commercial permanent hair coloration systems. Moreover, the results of wash fastness of matcha mordant dyed hair tresses is comparable and even better by tendency to permanent colored hair tresses.     

On the Statistical Calibration of Physical Models

We introduce a novel statistical calibration framework for physical models, relying on probabilistic embedding of model discrepancy error within the model. For clarity of illustration, we take the measurement errors out of consideration, calibrating a chemical model of interest with respect to a more detailed model, considered as “truth” for the present purpose. We employ Bayesian statistical methods for such model‐to‐model calibration and demonstrate their capabilities on simple synthetic models, leading to a well‐defined parameter estimation problem that employs approximate Bayesian computation. The method is then demonstrated on two case studies for calibration of kinetic rate parameters for methane air chemistry, where ignition time information from a detailed elementary‐step kinetic model is used to estimate rate coefficients of a simple chemical mechanism. We show that the calibrated model predictions fit the data and that uncertainty in these predictions is consistent in a mean‐square sense with the discrepancy from the detailed model data.     

Synthesis and Some Transformations of 5-(1,4-Benzodioxan-2-yl)-4-phenyl-4H-1,2,4-triazole-3-thiol

Russian Journal of Organic Chemistry - The title compound was synthesized by reaction of 1,4-benzodioxane-2-carbohydrazide with phenyl isothiocyanate, followed by cyclization of the...     

Polymer chelates of fe,co, and ni based on 5-ethynyl-2H-tetrazole

Electrochemical preparation of chelates based on 5-ethynyl-2H-tetrazole on the surface of iron, cobalt, and nickel results in colored polymer film at low current density. At higher current density the polymer chelate is transferred into the solution. The composition and structure of the polymer chelates has been studied by infrared spectroscopy, elemental analysis, and thermogravimetric analysis. The mechanism of the chelates formation in various solvents has been suggested.