全文获取类型
收费全文 | 3169篇 |
免费 | 269篇 |
国内免费 | 70篇 |
专业分类
化学 | 2321篇 |
晶体学 | 23篇 |
力学 | 81篇 |
综合类 | 3篇 |
数学 | 235篇 |
物理学 | 845篇 |
出版年
2023年 | 37篇 |
2022年 | 22篇 |
2021年 | 76篇 |
2020年 | 85篇 |
2019年 | 106篇 |
2018年 | 60篇 |
2017年 | 71篇 |
2016年 | 126篇 |
2015年 | 119篇 |
2014年 | 155篇 |
2013年 | 207篇 |
2012年 | 282篇 |
2011年 | 313篇 |
2010年 | 207篇 |
2009年 | 173篇 |
2008年 | 265篇 |
2007年 | 178篇 |
2006年 | 222篇 |
2005年 | 182篇 |
2004年 | 148篇 |
2003年 | 85篇 |
2002年 | 84篇 |
2001年 | 54篇 |
2000年 | 20篇 |
1999年 | 26篇 |
1998年 | 25篇 |
1997年 | 25篇 |
1996年 | 14篇 |
1995年 | 19篇 |
1994年 | 14篇 |
1993年 | 13篇 |
1992年 | 5篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 7篇 |
1987年 | 8篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 7篇 |
1983年 | 8篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1978年 | 3篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1973年 | 2篇 |
1969年 | 2篇 |
排序方式: 共有3508条查询结果,搜索用时 15 毫秒
1.
Luan Nguyen Ngoc Kim Do Sang Yen Nguyen Dong 《Journal of Optimization Theory and Applications》2022,193(1):574-597
Journal of Optimization Theory and Applications - We consider the conic linear program given by a closed convex cone in an Euclidean space and a matrix, where vector on the right-hand side of the... 相似文献
2.
Chen Yujie Sang Weixuan Chen Rong Liu Xue Li Xiaoyan Guan Fenfen Li Xun Xiao Hui 《Journal of Radioanalytical and Nuclear Chemistry》2020,324(1):367-373
Journal of Radioanalytical and Nuclear Chemistry - The nanoscale zero-valent nickel (nano-Ni0) was prepared by liquid-phase reduction method and characterized by BET, XPS, FT-IR and XRD and be used... 相似文献
3.
Kellie R. England Dr. Sang Ho Lim Lucy M. C. Luong Prof. Marilyn M. Olmstead Prof. Alan L. Balch 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(3):874-878
The mono- and di-chloroform solvates of [Au2(μ-1,2-bis(diphenylarsino)ethane)2](AsF6)2 undergo single-crystal-to-single-crystal transformations that result in gain (over 12 hours) or slow loss (over five years) of only one chloroform molecule. The change in solvation results in changes in the structure and luminescence of the digold cation. The cation consists of a pair of slightly bent As-Au-As units that are connected through the two bridging dpae ligands and by aurophilic interactions with Au⋅⋅⋅Au contacts of 3.05152(15) Å in the disolvate or 2.9570(5) Å in the monosolvate. 相似文献
4.
Nonlinear Dynamics - The large-scale use of the Internet brings the problem of the rapid spread of computer malware over the network. Aiming at the relationship between malware, propagation paths... 相似文献
5.
6.
7.
Cellulose - In this study, cellulose microparticle were prepared by sulfuric acid hydrolysis, glyoxal crosslinking and acetylation followed by air classifying mill, and their properties including... 相似文献
8.
Kenkera Rayappa Naveen Dr. Keshavananda Prabhu CP Dr. Ramanaskanda Braveenth Prof. Jang Hyuk Kwon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(12):e202103532
Pure organic molecules based thermally activated delayed fluorescence (TADF) emitters have been successfully developed in recent years for their propitious application in highly efficient organic light emitting diodes (OLEDs). In the case of orange red emitters, the non-radiative process is known to be a serious issue due to its lower lying singlet energy level. However, recent studies indicate that there are tremendous efforts put to develop efficient orange red TADF emitters. In addition, the external quantum efficiency (EQE) of heteroaromatic based orange red TADF OLEDs surpassed 30 %. Such heteroaromatic type emitters showed wide emission spectra; therefore, more attention is being paid to develop highly efficient orange red TADF emitters along with good color purity. Herein, the recent progress of orange red TADF emitters based on molecular structures, such as cyanobenzene, heteroaromatic, naphthalimide, and boron-based acceptors, are reviewed. Further, our insight on these acceptors has been provided by their photophysical studies and device performances. Future perspectives of orange red TADF emitters for real practical applications are discussed. 相似文献
9.
Hong-Li Xuan Yu-Feng Sang Prof. Liang-Jin Xu Da-Sheng Zheng Cui-Mi Shi Prof. Zhong-Ning Chen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(48):e202201299
Circular polarized luminescence (CPL)-active materials attract great attentions owing to their widely applications in 3D optical displays and encrypted transmission. Inspired by the strategies adopted in perovskite based CPL materials, herein, CPL-active hybrids (D)- and (L)-(tert-butyl prolinate)MnCl3 were successfully prepared by assembling chiral D/L tert-butyl prolinate with manganese (II) chloride. Single crystal structures show the as-formed hybrids possess one-dimensional (1D) structure containing linear chains of face-sharing MnCl6 octahedral surrounded by prolinate cations. The 1D Mn(II) hybrids display strong red emission peaked at 646 nm with PLQY of 67.1 % and 57.2 % for d -type and l -type, respectively, representing the highest PLQY for 1D MnII hybrids. Interestingly, the 1D Mn(II) hybrids exhibit prominent circular dichroism (CD) signals and remarkable CPL activity with the dissymmetry factor g of 6.1*10−3 and −6.3*10−3 from 550 to 800 nm for (D)- and (L)-(tert-butyl prolinate)MnCl3, respectively, owing to the existence of chiral cations. It is worthy noted the obtained g represents the highest value for non-lead organic–inorganic hybrids. 相似文献
10.
In this paper,we consider a possible modification of the de Sitter and anti-de Sitter space for the extended uncertainty principle.For the modified anti-de Sitter model we discuss the representation and wave functions of the momentum operator for a one-dimensional box problem.Also,we consider modified Snyder and anti-Snyder models for the generalized uncertainty principle.Then,we assume the Hamiltonian with different potential and solve the Heisenberg algebra for the modified(anti)-de Sitter and(anti)-Snyder models in both position and in the momentum space. 相似文献