A new ternary Cu (II) complex with 4,7-dimethyl-1,10-phenanthroline and NOO-type tridentate Schiff base ligand: Synthesis,crystal structure,biomacromolecular interactions,and radical scavenging activities

NOO-type tridentate Schiff base, N-salicylidene-2-aminobenzoic acid, (H₂L), and its ternary Cu (II) complex containing H₂L Schiff base and 4,7-dimethyl-1,10-phenanthroline (4,7-dmphen), [Cu(4,7-dmphen)(H₂L)]₂7H₂O, have been synthesized and characterized by CHN analysis, ESI-MS, FTIR, and single-crystal X-ray diffraction techniques. The interaction of alone H₂L Schiff base ligand and ternary Cu (II) complex with biomacramolecules {calf thymus DNA (CT-DNA) and bovine serum albumin (BSA)} has been investigated by electronic absorption and fluorescence spectroscopy. The experimental results indicate that H₂L Schiff base ligand and ternary Cu (II) complex bind to CT-DNA by means of a moderate intercalation mode. Furthermore, the fluorescence quenching mechanism between H₂L Schiff base ligand and ternary Cu (II) complex with BSA possesses a static quenching process. Radical scavenging activity of H₂L Schiff base ligand and ternary Cu (II) complex was measured in terms of EC₅₀, using the DPPH and H₂O₂ methods. Biomacromolecule interactions and scavenging activity studies revealed that ternary Cu (II) complex yielded better results than H₂L Schiff base ligand alone.     

Excitation of linear and nonlinear cavity modes upon interaction of femtosecond pulses with arrays of metallic nanowires

We investigate linear and nonlinear effects induced by the scattering of femtosecond optical pulses by cavity-shaped two-dimensional distributions of metallic cylinders. In particular, by employing a numerical method based on the multiple scattering matrix algorithm, we demonstrate that, at both the fundamental frequency and the second harmonic, such arrays of metallic nanowires support localized (cavity) surface plasmon–polariton modes with characteristic lifetime ranging from a few tens of femtoseconds to more than a hundred of femtoseconds.     

Modulation instability in silicon photonic nanowires

We demonstrate that strong modulation instability (MI) of copropagating optical waves can be observed in Si photonic nanowires with a length of only a few millimeters. We consider two distinct cases, namely one in which one wave propagates in the normal group-velocity dispersion (GVD) region and the other one experiences anomalous GVD, and a second case in which both waves propagate in the anomalous GVD region. In both cases we show that, for comparable optical powers, the peak value of the MI gain spectrum is 2 to 3 orders of magnitude larger than that achieved in optical fibers.     

On-chip optical filters with designable characteristics based on an interferometer with embedded silicon photonic structures

We demonstrate chip-scale flat-top filters at near-IR wavelengths using negative index photonic crystal based Mach-Zehnder interferometers. Supported by full three-dimensional numerical simulations, we experimentally demonstrate a new approach for engineering high-pass, low-pass, bandpass, and band-reject filters, based on designing the photonic band diagram both within the bandgap frequency region and away from it. We further show that our approach can be used to design filters that have tunable multilevel response for different sections of the spectrum and for different polarizations. This configuration enables deterministic control of the bandwidth and the rejection ratio of filters for integrated photonic circuits.     

Semidiscrete composite solitons in arrays of quadratically nonlinear waveguides

We demonstrate that an array of discrete waveguides on a slab substrate, both featuring chi2 nonlinearity, supports stable solitons composed of discrete and continuous components. Two classes of fundamental composite soliton are identified: ones consisting of a discrete fundamental-frequency (FF) component in the waveguide array, coupled to a continuous second-harmonic (SH) component in the slab waveguide, and solitons with an inverted FF/SH structure. Twisted bound states of the fundamental solitons are found, too. In contrast with the usual systems, the intersite-centered fundamental solitons and bound states with the twisted continuous components are stable over almost the entire domain of their existence.     

Simulation of mode-locked surface-emitting lasers through a finite-difference time-domain algorithm

An approach based on the finite-difference time-domain method is developed for simulating the dynamics of passive mode locking in vertical-cavity surface-emitting lasers (VCSELs). The material response is modeled by the effective semiconductor Bloch equations through a resonant polarization term in the Maxwell's equations. Nonlinear gain saturation is incorporated through a gain compression factor in the equation governing the dynamics of the resonant polarization. An extended-cavity VCSEL with a quantum-well saturable absorber is simulated, and stable mode-locking pulses are obtained. Fine features of the spatial profile of the mode-locked pulses are also studied within this approach.     

Non-envelope formulation for femtosecond optical pulses in semiconductors

We analyze the response of an ensemble of 1s-excitons driven by a femtosecond optical pulse, beyond traditional “slowly varying amplitudes” approach. For optical pulses of a given duration it is shown that the off-resonance optical field can evolve into a stable soliton with nonzero asymptotic behavior. Pis’ma Zh. éksp. Teor. Fiz. 65, No. 5, 380–384 (10 March 1997) Published in English in the original Russian journal. Edited by Steve Torstveit.