全文获取类型
收费全文 | 429篇 |
免费 | 24篇 |
国内免费 | 1篇 |
专业分类
化学 | 270篇 |
晶体学 | 4篇 |
力学 | 2篇 |
数学 | 9篇 |
物理学 | 169篇 |
出版年
2023年 | 7篇 |
2022年 | 3篇 |
2021年 | 12篇 |
2020年 | 8篇 |
2019年 | 17篇 |
2018年 | 9篇 |
2017年 | 6篇 |
2016年 | 9篇 |
2015年 | 13篇 |
2014年 | 24篇 |
2013年 | 25篇 |
2012年 | 36篇 |
2011年 | 37篇 |
2010年 | 25篇 |
2009年 | 12篇 |
2008年 | 38篇 |
2007年 | 37篇 |
2006年 | 29篇 |
2005年 | 24篇 |
2004年 | 18篇 |
2003年 | 10篇 |
2002年 | 7篇 |
2001年 | 4篇 |
2000年 | 5篇 |
1999年 | 2篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1996年 | 5篇 |
1995年 | 4篇 |
1994年 | 1篇 |
1993年 | 7篇 |
1992年 | 4篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1989年 | 5篇 |
1985年 | 1篇 |
1981年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有454条查询结果,搜索用时 15 毫秒
1.
Seong-Wook Kim Hyeonjung Jung Dr. Mahmut Sait Okyay Dr. Hyuk-Jun Noh Sein Chung Young Hyun Kim Jong-Pil Jeon Prof. Dr. Bryan M. Wong Prof. Dr. Kilwon Cho Dr. Jeong-Min Seo Prof. Dr. Jung-Woo Yoo Prof. Dr. Jong-Beom Baek 《Angewandte Chemie (International ed. in English)》2023,62(42):e202310560
The development of covalent organic frameworks (COFs) with efficient charge transport is of immense interest for applications in optoelectronic devices. To enhance COF charge transport properties, electroactive building blocks and dopants can be used to induce extended conduction channels. However, understanding their intricate interplay remains challenging. We designed and synthesized a tailor-made COF structure with electroactive hexaazatriphenylene (HAT) core units and planar dioxin (D) linkages, denoted as HD-COF. With the support of theoretical calculations, we found that the HAT units in the HD-COF induce strong, eclipsed π–π stacking. The unique stacking of HAT units and the weak in-plane conjugation of dioxin linkages leads to efficient anisotropic charge transport. We fabricated HD-COF films to minimize the grain boundary effect of bulk COFs, which resulted in enhanced conductivity. As a result, the HD-COF films showed an electrical conductivity as high as 1.25 S cm−1 after doping with tris(4-bromophenyl)ammoniumyl hexachloroantimonate. 相似文献
2.
Optical Review - We present analytical solutions for the subsidiary maxima in multiple slit interference up to eleven slits. For the number of slits N, there exist $$N-2$$ subsidiary maxima between... 相似文献
3.
Design of highly active and stable electrocatalyst is a major objective in a fuel cell. The special situation imposed to the electrocatalyst such as one of the most sluggish catalysis of oxygen reduction reaction, inherent structural instability of dispersed nanoparticle, harsh electrochemical conditions of electric potential and nonzero pH aqueous solution requires unique attention in the design. Considering that various attempts have been made for the purpose, high-speed but rigorous formalisms to evaluate the performance of candidates are crucial.This review article briefly introduces recently developed first-principles computational methodologies mainly applied to catalytic activity and electrochemical stability of electrocatalysts in proton exchange membrane fuel cells. Innovative design principles deduced from the outcomes are clearly discussed. 相似文献
4.
The decaying vacuum model (DV), treating dark energy as a varying vacuum, has been studied well recently. The vacuum energy
decays linearly with the Hubble parameter in the late-times, ρ
Λ
(t)∝H(t), and produces the additional matter component. We constrain the parameters of the DV model using the recent data-sets from
supernovae, gamma-ray bursts, baryon acoustic oscillations, CMB, the Hubble rate and X-rays in galaxy clusters. It is found
that the best fit of the matter density contrast Ω
m
in the DV model is much lager than that in ΛCDM model. We give the confidence contours in the Ω
m
–h plane up to 3σ confidence level. Besides, the normalized likelihoods of Ω
m
and h are presented, respectively. 相似文献
5.
So Young An Seung Man Noh Joon Hyun Nam Jung Kwon Oh 《Macromolecular rapid communications》2015,36(13):1255-1260
Polymer‐based crosslinked networks with intrinsic self‐repairing ability have emerged due to their built‐in ability to repair physical damages. Here, novel dual sulfide–disulfide crosslinked networks (s‐ssPxNs) are reported exhibiting rapid and room temperature self‐healability within seconds to minutes, with no extra healing agents and no change under any environmental conditions. The method to synthesize these self‐healable networks utilizes a combination of well‐known crosslinking chemistry: photoinduced thiol‐ene click‐type radical addition, generating lightly sulfide‐crosslinked polysulfide‐based networks with excess thiols, and their oxidation, creating dynamic disulfide crosslinkages to yield the dual s‐ssPxNs. The resulting s‐ssPxN networks show rapid self‐healing within 30 s to 30 min at room temperature, as well as self‐healing elasticity with reversible viscoelastic properties. These results, combined with tunable self‐healing kinetics, demonstrate the versatility of the method as a new means to synthesize smart multifunctional polymeric materials.
6.
Chi Won Kim Jungmin Ahn Sung Min Kim Tae Hwan Noh Ok-Sang Jung 《Transition Metal Chemistry》2011,36(5):545-551
Type studies on competitive polyatomic anion versus acetonitrile coordination in the self-assembly of a series of [Ag2(X)
m
(bip)(NCCH3)
n
](X)2−m
(X− = NO3
−, CF3SO3
−, ClO4
−, BF4
−, and PF6
−; m = 0, 2; n = 0, 2, 4; bip = 1,4-bis(2-isonicotinoyloxyethyl)piperazine) were carried out. Each bip spacer acts as an N4 tetradentate ligand and is linked to four silver(I) centers through two pyridine and two piperazine moieties, producing a
double strand consisting of two 20-membered ring units. The coordinating environment around the silver(I) center is subtly
determined by the competition of the polyatomic anions with acetonitrile, that is, by the Ag···NCCH3 versus Ag···X interactions. The coordinating ability of acetonitrile is inversely proportional to the order of the coordination
ability of the Hoffmeister series of polyatomic anions, NO3
− ≫ CF3SO3
− > ClO4
− > BF4
− ≫ PF6
−. 相似文献
7.
Tae Young Jang Ku Bong Chung Hye Ri Eom Dong Kyun Noh In Kyu Song Jongheop Yi Sung-Hyeon Baeck 《Research on Chemical Intermediates》2011,37(9):1275-1282
Catalytic hydrogenation of lactic acid to propylene glycol was performed over various metals (Ag, Co, Cu, Ni, Pt, and Ru) supported on silica prepared by an incipient wetness impregnation method. The loading amount of each metal was 5 wt%. Crystallinity of the synthesized catalysts was investigated by X-ray diffraction (XRD), and the BET method was utilized to examine the surface area. Pore volume and pore size of catalysts were determined using BJH analysis of the N2 adsorption isotherm. Particle sizes of various metals were determined from transmission electron microscopy (TEM) images. The catalytic activity was found to be strongly dependent on the supported metal. Among catalysts tested, Ru/SiO2 showed the highest propylene glycol yield. The yield of propylene glycol increased with pressure, and the highest yield was achieved at 130 °C. 相似文献
8.
Electrochemical properties of composite cathodes consisting of La0.8Sr0.2Mn1?x Cu x O3 (LSMCu, 0?≤?x?≤?0.2) and Ce0.8Gd0.2O2?x (GDC) were determined by impedance spectroscopy, and conduction mechanism for the composite cathodes was investigated by a near-edge X-ray absorption fine-structure analysis (NEXAFS). LSMCu–GDC cathodes showed lower polarization resistance (R p) than LSM–GDC up to 750 °C, whereas they exhibited better performance at higher temperature (≥800 °C). The best performance was achieved with the LSMCu10–GDC cathode: 0.27 and 0.08?Ω cm2 at 800 °C and 850 °C, respectively. NEXAFS and refinement results confirmed that Cu doping caused the oxidation of Mn3+ to Mn4+ and lattice contraction. This additional Mn4+ can lead to the formation of oxygen vacancies when Mn4+ is converted to Mn3+ at relatively high temperatures (above 600 °C). This in turn contributes to improved oxygen ion transport in LSM. The LSMCu–GDC composite cathode can thus be considered a suitable potential cathode for SOFC applications. 相似文献
9.
Jun Myung Kim So Hyeong Sohn Noh Soo Han Prof. Seung Min Park Prof. Joohoon Kim Prof. Jae Kyu Song 《Chemphyschem》2014,15(14):2917-2921
Direct evidence for the blue luminescence of gold nanoclusters encapsulated inside hydroxyl‐terminated polyamidoamine (PAMAM) dendrimers was provided by spectroscopic studies as well as by theoretical calculations. Steady‐state and time‐resolved spectroscopic studies showed that the luminescence of the gold nanoclusters consisted largely of two electronic transitions. Theoretical calculations indicate that the two transitions are attributed to the different sizes of the gold nanoclusters (Au8 and Au13). The luminescence of the gold nanoclusters was clearly distinguished from that of the dendrimers. 相似文献
10.
Mohammad Noh Daud 《化学物理学报》2011,24(6):679-685
采用时间依赖的量子波包法研究14N14N16O、14N15N16O、15N14N16O、15N15N16O、14N14N17O和14N14相似文献