Mode conversion and anomalous transport in Kelvin-Helmholtz vortices and kinetic Alfvén waves at the Earth's magnetopause

Observations at the Earth's magnetopause identify mode conversion from surface to kinetic Alfvén waves at the Alfvén resonance. Kinetic Alfvén waves radiate into the magnetosphere from the resonance with parallel scales up to the order of the geomagnetic field-line length and spectral energy densities obeying a k(perpendicular)(-2.4) power law. Amplitudes at the Alfvén resonance are sufficient to both demagnetize ions across the magnetopause and provide field-aligned electron bursts. These waves provide diffusive transport across the magnetopause sufficient for boundary layer formation.     

Concentration of sodium ion as the determining factor for the association of dansyl amino acids with the teicoplanin molecule in reversed-phase liquid chromatography

The mechanism of the binding of D,L dansyl amino acids to teicoplanin was investigated. Na+ was used as an indicator of the interactions between the solutes and teicoplanin. The number (n) of sodium ions, Na+, excluded from the solute-teicoplanin interface when analyte transfer occurred was determined. A thermodynamic study and enthalpy-entropy compensation were performed to further explore the interaction mechanism. From these results, it was shown that teicoplanin was balanced between 2 conformational states characterized by distinct enantioselective properties. This approach indicates that liquid chromatography (LC) is a useful tool to extract physicochemical and molecular information from retention data. Thus, LC can be used as a complementary technique with the conventional techniques of molecular interaction analysis.     

Solitary electromagnetic pulses detected with super-Alfvénic flows in Earth's geomagnetic tail

Solitary nonlinear (deltaB/B>1) electromagnetic pulses have been detected in Earth's geomagnetic tail accompanying plasmas flowing at super-Alfvénic speeds. The pulses in the current sheet had durations of approximately 5 s, were left-hand circularly polarized, and had phase speeds of approximately the Alfvén speed in the plasma frame. These pulses were associated with a field-aligned current J(parallel) and observed in low density (approximately 0.3 cm(-3)), high temperature (T(e) approximately T(i) approximately 3x10(7) K), and beta approximately 10 plasma that included electron and ion beams streaming along B. The wave activity was enhanced from below the ion cyclotron frequency to electron cyclotron and upper hybrid frequencies. The detailed properties suggest the pulses are nonlinearly steepened ion cyclotron or Alfvén waves.     

The origin of open circuit voltage of porphyrin-sensitised TiO(2) solar cells

Electron lifetime and diffusion coefficient measurements in highly efficient porphyrin-sensitised TiO(2) solar cells showed reduced electron lifetime, and consequently, lower photo-induced electron density under illumination compared to commonly used ruthenium dye (N719)-sensitised solar cells, which is proposed to be the origin of the generally lower open circuit voltage.     

Drift-kinetic Alfvén waves observed near a reconnection X line in the earth's magnetopause

We identify drift-kinetic Alfvén waves in the vicinity of a reconnection X line on the Earth's magnetopause. The dispersive properties of these waves have been determined using wavelet interferometric techniques applied to multipoint observations from the Cluster spacecraft. Comparison of the observed wave dispersion with that expected for drift-kinetic Alfvén waves shows close agreement. The waves propagate outwards from the X line suggesting that reconnection is a kinetic Alfvén wave source. Energetic O+ ions observed in these waves indicate that reconnection is a driver of auroral ion outflow.     

Principle and Experimental Validation of a new Apparatus Allowing Large Deformation in Pure Bending: Application to thin Wire

Experimental pure bending conditions are difficult to obtain when large deformations and displacements are required. In this work, a new principle using two universal joints is proposed and developed to enable such pure bending conditions. This principle has been applied to design an apparatus suitable to test small size samples (such as wires of diameter < 1 mm) at small curvature radii (? 5 mm) and to specifically provide small size samples moment-curvature relationship. This article underlines and validates the abilities of this new apparatus by performing and analysing tests on samples made of well-known material.     

Preparation and analytical characterization of a chelating resin coated with 1-(2-pyridylazo)-2-naphthol

A chelating sorbent was obtained by deposition of 1-(2-pyridylazo)-2-naphthol on Amberlite XAD-4. The analytical characteristics of the sorbent were established and optimum sorption conditions for Cu, Zn, Fe, Cd, Ni, and Pb under static and dynamic conditions were determined. The sorbent was applied to analysis of river water. After group separation of traces of metals on the sorbent and subsequent elution with hydrochloric add, the metals were determined in the effluent by atomic-absorption spectrophotometry.     

Influence of the lower-hybrid drift instability on magnetic reconnection in asymmetric configurations

Using fully kinetic 3D simulations of magnetic reconnection in asymmetric antiparallel configurations, we demonstrate that an electromagnetic lower-hybrid drift instability (LHDI) localized near the X line can substantially modify the reconnection mechanism in the regimes with large asymmetry, a moderate ratio of electron to ion temperature, and low plasma β. However, the mode saturates at a small amplitude in the regimes typical of Earth's magnetopause. In these cases, LHDI-driven turbulence is predominantly localized along the separatrices on the low-β side of the current sheet, in agreement with spacecraft observations.     

Direct evidence for a three-dimensional magnetic flux rope flanked by two active magnetic reconnection X lines at Earth's magnetopause

We report the direct detection by three THEMIS spacecraft of a magnetic flux rope flanked by two active X lines producing colliding plasma jets near the center of the flux rope. The observed density depletion and open magnetic field topology inside the flux rope reveal important three-dimensional effects. There was also evidence for nonthermal electron energization within the flux rope core where the fluxes of 1-4 keV superthermal electrons were higher than those in the converging reconnection jets. The observed ion and electron energizations differ from current theoretical predictions.