椭球粒子声辐射力计算及分析

针对水下椭球粒子,以声散射理论为基础,采用分波序列的方法,建立了椭球粒子声辐射力的理论计算模型。进而根据声辐射力计算公式,以刚性椭球粒子和液体椭球粒子为例,计算并分析不同Bessel波束作用下椭球粒子的轴向声辐射力函数特征。数值仿真计算结果表明,对于刚性椭球粒子,扁平椭球粒子相对于细长椭球粒子更有助于激发负声辐射力；对于液体椭球粒子,细长椭球粒子相对于扁平椭球粒子更加容易产生负声辐射力；对于不同介质的椭球粒子,不同的入射波束激发的负声辐射力的效果也存在明显的差异。该结果为复杂的尺寸和介质粒子声操控技术提供了理论的可行性。     

基于粒子滤波和人工势场法的放射源搜寻方法

针对放射源搜寻过程中难度大、定位精度低等问题，提出了一种适用于移动机器人的自主寻源方法。该方法利用移动机器人搭载辐射探测器采集的剂量计数值，根据γ射线的衰减规律建立辐射衰减模型；在机器人前进的过程中利用粒子滤波算法对放射源的参数进行实时估计；采用高斯分布函数对重采样后的粒子进行自适应更新，保证重采样后的粒子具有多样性；根据辐射环境创建机器人路径规划模型，采用人工势场法规划机器人的自主寻源路径。实验在Matlab下进行了仿真验证，结果表明，该方法在有遮挡环境下能够搜寻到未知的单点源，同时自适应更新能够提高算法的稳定性，缩小寻源误差。     

Acidic Media Impedes Tandem Catalysis Reaction Pathways in Electrochemical CO2 Reduction

Electrochemical CO₂ reduction (CO₂R) in acidic media with Cu-based catalysts tends to suffer from lowered selectivity towards multicarbon products. This could in principle be mitigated using tandem catalysis, whereby the *CO coverage on Cu is increased by introducing a CO generating catalyst (e.g. Ag) in close proximity. Although this has seen significant success in neutral/alkaline media, here we report that such a strategy becomes impeded in acidic electrolyte. This was investigated through the co-reduction of ¹³CO₂/¹²CO mixtures using a series of Cu and CuAg catalysts. These experiments provide strong evidence for the occurrence of tandem catalysis in neutral media and its curtailment under acidic conditions. Density functional theory simulations suggest that the presence of H₃O⁺ weakens the *CO binding energy of Cu, preventing effective utilization of tandem-supplied CO. Our findings also provide other unanticipated insights into the tandem catalysis reaction pathway and important design considerations for effective CO₂R in acidic media.     

One-pot synthesis of CoO–ZnO/rGO supported on Ni foam for high-performance hybrid supercapacitor with greatly enhanced cycling stability

The high specific capacitance along with good cycling stability are crucial for practical applications of supercapacitors,which always demands high-performance and stable electrode materials.In this work,we report a series of ternary composites of CoO-ZnO with different fractions of reduced graphene oxide(rGO) synthesized by in-situ growth on nickel foam,named as CZG-1,2 and 3,respectively.This sort of binder-free electrodes presents excellent electrochemical properties as well as large capacitance due to their low electrical resistance and high oxygen vacancies.Particularly,the sample of CZG-2(CoO-ZnO/rGO 20 mg) in a nanoreticular structure shows the best electrochemical performance with a maximum specific capacitance of 1951.8 F/g(216.9 mAh/g) at a current intensity of 1 A/g.The CZG-2-based hybrid supercapacitor delivers a high energy density up to 45.9 Wh/kg at a high power density of 800 W/kg,and kept the capacitance retention of 90.1% over 5000 charge-discharge cycles.     

Gravitational-wave detection with matter-wave interferometers based on standing light waves

We study the possibility of detecting gravitational-waves with matter-wave interferometers, where atom beams are split, deflected and recombined totally by standing light waves. Our calculation shows that the phase shift is dominated by terms proportional to the time derivative of the gravitational wave amplitude. Taking into account future improvements on current technologies, it is promising to build a matter-wave interferometer detector with desired sensitivity.     

Base-mediated reaction of vinyl bromides with aryl azides: one-pot synthesis of 1,5-disubstituted 1,2,3-triazoles

A one-pot base-mediated reaction of azides and β- or α-vinyl bromides has been reported. The effects of bases and solvents have been investigated in the process. A variety of 1,5-disubstituted triazoles were prepared in low to good yields. Further studies reveal that the corresponding alkynes were produced as intermediates via elimination reaction. Under the same reaction conditions, the reactions of alkyl alkynes with phenyl azide would give 1,5-disubstituted 1,2,3-triazoles.     

CaAl12O19基质中Eu2+-Cr3+的能量传递与发光性质

在还原气氛下高温固相法合成了CaAl12O19:Eu2+,Cr3+荧光粉.样品光谱显示:Eu2+发射带与Cr3+吸收带有重叠,具备Eu2+-Cr3+之间发生能量传递必要条件.在290 nm近紫外光激发下,单掺杂Eu2+和Cr3+时样品均无691 nm发射,仅在Eu2+,Cr3+共掺时才出现691 nm发射,这证明Eu2+和Cr3+之间发生了能量传递,且监测691 nm时样品的激发光谱也证实了这一点.CaAl12O19:1%Eu2+,x%Cr3+样品组的发射光谱研究表明:增大x能提高Cr3+红光与Eu2+蓝紫光发射强度之比及Eu2+-Cr3+之间能量传递效率.CaAl12O19:2%Cr3+,x%Eu2+样品组的激发光谱分析表明:x>2时,Cr3+在415 nm处的吸收效率相对于565 nm有显著提高.还对样品CaAl12O19:1%Eu2+,1%Cr3+荧光寿命和能量传递速率进行了简单分析.     

高阶辛算法的稳定性与数值色散性分析

利用Maxwell方程的哈密尔顿函数,导出对应的欧拉-哈密尔顿方程.利用辛积分技术与高阶交错差分技术,建立求解三维时域Maxwell方程的高阶辛算法;结合电磁场中的物理概念,借助矩阵分析和张量分析理论,获得高阶时域方法及高阶辛算法的稳定性和数值色散性的统一处理新方法.用数值结果证实方法的正确性,与FDTD算法和其它时域高阶方法相比,高阶辛算法具有较大的计算优势,为电磁计算提供了新的途径.     

基于电光补偿测量的光相位延迟拓展测量法

在激光电光调制补偿测量光相位延迟量过程中,加入交流调制电压形成倍频接收信号,获得消光的精确定位,能提高测量精确度。通过调制信号形状变化与相关参量之依赖关系,可拓展测量范围,解决在某些点附近无法测量波片相位的"盲区"问题。根据接收到的调制光信号形状变化趋势与待测波片样品方位、延迟量、旋转方向等条件的联系,在待测波片快轴选定后,通过波片旋转影响信号形状变化规律的观测,可敏锐地甄别在半波点或全波长点附近波片的正负偏差特性,从而解决了一般偏振干涉补偿测量相位无法解决的测量盲区问题。不改变测量系统结构也不需添加任何器件,适应于最小延迟偏差≥λ/360的情况。     

多点云雾爆炸波相互作用的数值模拟

为研究多点云雾爆炸超压场的分布特性,利用LS-DYNA程序,对4个非圆柱体云雾的爆炸超压的相互作用过程进行了数值模拟,并与实验结果进行了对比。得到了中心区域冲击波相互作用演化过程与中心竖直方向0~20 m处的超压变化规律,以及0°、90°、135°和180°等4个方向的地面峰值超压随水平距离变化的规律。结果表明:中心区域地面依次出现3重冲击波;地面整体超压场强度向中心区域倾斜。在45°方向竖直截面上冲击波波系由入射波、反射波与马赫波构成。