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Elahe Yazdani Farzane Pazoki Arefe Salamatmanesh Masoume Jadidi Nejad Maryam Kazemi Miraki Akbar Heydari 《应用有机金属化学》2020,34(10):e5855
Copper supported on magnetite nanoparticles modified with environmentally friendly ligand tricine was devised for synthesis of acetamides via C–C oxidative cleavage of ketones with amines. The catalyst was characterized using different techniques, including Fourier transform infrared, X-ray diffraction, scannin electron microscopy, vibrating sample magnetometry, thermogravimetric analysis, and energy dispersive x-ray spectroscopy. The protocol showed relatively high yields of acetamide products. Furthermore, the magnetic recovery of the catalyst rendered the overall process fast and efficient. It was used in the reaction for six consecutive cycles with negligible loss of catalytic activity. This research is the first report of application of magnetic nanocatalysts for synthesis of acetamides from ketones of low activity through a C–C bond cleavage strategy. 相似文献
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Podophyllotoxin extraction from Linum usitatissimum plant and its anticancer activity against HT‐29, A‐549 and MDA‐MB‐231 cell lines with and without the presence of gold nanoparticles 下载免费PDF全文
Mohammad Safarpoor Mehrorang Ghaedi Masoume Yousefinejad Hamedreza Javadian Arash Asfaram Zahra Ghasemi Hajar Jaberi Daruosh Rahimi 《应用有机金属化学》2018,32(2)
In recent years, gold nanoparticles (Au‐NPs) have been taken into consideration in nanomedicine due to their excellent biocompatibility, chemical stability and promising optical properties. In this research, podophyllotoxin conjugated with gold nanoparticles (Au‐NPs‐POT) was synthesized and the conjugation of POT with Au‐NPs was confirmed using scanning electron microscopy, mass spectrometry and Fourier transform infrared spectroscopy. The anticancer effects of the product on preclinical models of lung, colon and breast cancers were investigated using MTT test. The analyses showed a direct dose–response relationship. It was found that higher concentrations of POT have more positive effects on the inhibition of cancer cell growth. At POT concentrations of 1, 2.5, 5, 7.5, 10, 15 and 20 ng ml?1, approximately 50% of the growth of colorectal, lung and breast cancer cell lines was inhibited, while similar results were obtained in the presence of 1, 2, 3, 4 and 5 μg ml?1 Au‐NPs‐POT. Au‐NPs‐POT exhibited the lowest cytotoxicity due to the presence of POT. The anticancer feature of Au‐NPs‐POT proved the potential to develop better anticancer therapeutics and to open new avenues for treatment of cancers. 相似文献
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The main objective of this research is to use the photocatalytic properties of PES/TiO2 nanofibers membranes to remove the phenol as a toxic pollutant in various effluents. The uniform fibers in terms of minimum bead formation and fibers diameter were fabricated. Therefore, more TiO2 catalysts are on the surface of the fibers which increase the active surface area of nanoparticles and consequently improve the phenol degradation efficiency. The effects of TiO2 concentration on hydrophilicity, mechanical properties, porosity, mean pore size, and water flux of membranes were studied. The PES/TiO2 nanofibers were evaluated for phenol degradation under UVA irradiation through a transparent membrane module. The amount of removable phenol was analyzed with high‐performance liquid chromatography. Central composite design was used as a statistical experimental design. Finally, the effect of TiO2 content in nanofibers and initial phenol concentrations were investigated as well as pH values in synthetic wastewater, on phenol degradation. The results from analysis of variance (ANOVA) analysis indicated that TiO2 content in nanofibers was the most important and effective parameter on phenol degradation. It was also presented that there is no significant interaction between parameters so that the effect of each parameter was investigated separately. Maximum phenol degradation was 43.0 ± 0.3% and found under conditions of TiO2 content, initial phenol concentration, and pH value of 8%, 120 ppm, and 7, respectively. 相似文献
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Masoume Mansouri Mohsen Askarbioki Saeed Ghavami Sabouri Alireza Khorsandi 《中国物理 B》2015,24(2):24216-024216
To reduce the walk-off angle of the extraordinary third-harmonic ultraviolet wave at 355 nm generated by type ⅡKTiOPO_4 and type I β-BaB_2O_4 optical crystals,and the Gaussian output beam of a Q-switched Nd:YAG laser,a simple theoretical model was developed based on a rotatable BK7 plate of variable thickness.By rotating the plate up to 35°along the beam direction,we reduced the walk-off angle up to ~ 13%.The same phenomenon is predicted by the model,confirming the performance of the model.It is found that,due to the walk-off effect,the intensity profile of the thirdharmonic generation beam is slightly degraded.To compensate for the observed phenomena and further reduce the walkoff,we used a combination of a convex lens and an axicon to transform the beam profile of the interacting fundamental and second-harmonic generation waves to the zero-order Bessel-Gaussian form.As a result,the walk-off is decreased to~ 48.81 mrad,providing ~ 30%relative reduction.By using the same BK7 plate rotated up to 35° along the third-harmonic beam direction,the walk-off angle is further reduced to 38.9 mrad.Moreover,it is observed that the beam profile of the emerged Bessel-Gaussian third-harmonic generation beam remains unchanged with no degradation. 相似文献
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One of room acoustic goals, especially in small to medium rooms, is sound diffusion in low frequencies, which have been the
subject of lots of researches. Sound diffusion is a very important consideration in acoustics because it minimizes the coherent
reflections that cause problems. It also tends to make an enclosed space sound larger than it is. Diffusion is an excellent
alternative or complement to sound absorption in acoustic treatment because it doesn’t really remove much energy, which means
it can be used to effectively reduce reflections while still leaving an ambient or live sounding space. Distribution of diffusive
and nondiffusive surfaces on room walls affect sound diffusion in room, but the amount, combination, and location of these
surfaces are still the matter of question. This paper investigates effects of these issues on room acoustic frequency response
in different parts of the room with different source-receiver locations. Room acoustic model based on wave method is used
(implemented) which is very accurate and convenient for low frequencies in such rooms. Different distributions of acoustic
surfaces on room walls have been introduced to the model and room frequency response results are calculated. For the purpose
of comparison, some measurements results are presented. Finally for more smooth frequency response in small and medium rooms,
some suggestions are made. 相似文献
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Energy Gain Investigation in Fast Ignition ICF with Electron Ignition Beam by Changing Fuel Characteristics 下载免费PDF全文
Fast ignition is a method in inertial confinement fusion (ICF) in which an ignition spark in pre-compression fuel is formed by an ultra-intense laser beam. In applying this method, a hot spot is built by relative electrons which are produced by the ultra-intense laser beam. For a better understanding, a fuel energy gain curve based on density is drawn and it can be observed that the ignition by an electron beam has the maximum energy gain. The maximum energy gain has been observed in equimolar DT fuel with a density of 500g/cma and in fuel with tritium (10%) with a density of 1000g/cm^3. 相似文献
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