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Summary The kinetics of oxidation of aldoses, namely xylose, arabinose, galactose and glucose, by CeIV have been studied in HClO4 + H2SO4 medium and in the presence of PdII. The reactions exhibit a first order rate dependence with respect to oxidant. The rate is inversely dependent on the [HSO
inf4
sup–
][H+] ratio. The order of reaction with respect to aldose decreases at higher [aldose]. Due to the formation of a complex between CeIV and PdII, a retarding effect of [PdII] on the rate of disappearance of [CeIV] has been observed. A mechanism consistent with the observed kinetic data is proposed. 相似文献
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The increasing accumulation of poly(ethylene terephthalate) polymer and poor recycle/disposal practices have made them omnipresent and a major culprit for environmental pollution. Currently global research efforts are focused on primary and secondary recycling of PET waste or through landfills. Chemical recycling of PET through hydrolytic or aminolytic route has been attempted by many researchers however with limited end applications. In our investigations we have used PET waste as a synthon and chemically converted it through a new non-catalytic route into several benzamide derivatives. We have successfully tested them for antistripping performance in bitumen. Our results as elaborated in the paper indicate a comparable performance of the new chemistry products based on PET, to commercially used antistripping chemicals. Our research work thus opens a new route for the recycling of used PET in bituminous concrete roads which may help in alleviating a major environmental problem and disposal of waste PET polymer in large scale. 相似文献
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Monika Sinha Manjari Bagchi Jishnu Dey Mira Dey Subharthi Ray Siddhartha Bhowmick 《Physics letters. [Part B]》2004,590(3-4):120-125
Strange stars (ReSS) calculated from a realistic equation of state (EOS), that incorporate chiral symmetry restoration as well as deconfinement at high density [Phys. Lett. B 438 (1998) 123; Phys. Lett. B 447 (1999) 352, Addendum; Phys. Lett. B 467 (1999) 303, Erratum; Indian J. Phys. B 73 (1999) 377] show compact objects in the mass radius curve. We compare our calculations of incompressibility for this EOS with that of nuclear matter. One of the nuclear matter EOS has a continuous transition to ud-matter at about five times normal density. Another nuclear matter EOS incorporates density dependent coupling constants. From a look at the consequent velocity of sound, it is found that the transition to ud-matter seems necessary. 相似文献
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M. S. Negi Yogesh Prasad Ganesh Prasad G. S. Gusain Manjari Badoni R. C. Ramola 《Indian Journal of Physics》2009,83(8):1209-1214
The natural pollution level due to gamma radiation was measured in about 22 residential houses around the Tehri Dam Project
in Uttarakhand state by using Environmental Radiation Dosimeter. Both urban and rural houses were selected for the measurements.
The recorded gamma dose rate in indoor atmosphere was found to vary from 25.1 μR/h to 67 μR/h with a mean value 38.6 μR/h
whereas in traditional rural houses the obtained values varied from 42.6 μR/h to 83.5 μR/h with mean value 60.3 μR/h. In outdoor
atmosphere, it was found to vary from 25.1 μR/h to 60 μR/h with an average value 35.8 μR/h. It is observed that the dose rates
are higher in rural houses than that in modern houses. Efforts have also been made to observe deviation of dose rate in the
underground (Power House) atmosphere of Tehri Dam Project in vertical and horizontal mode. It was observed that dose rate
remain almost same in horizontal mode, but a significant variation has been found in the vertical mode. In addition, the variation
of dose rate with type of building material, trend and mode of construction of houses and the age of houses are also discussed
in detail. 相似文献
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Ganesh Prasad Yogesh Prasad G. S. Gusain Manjari Badoni J. M. S. Rana R. C. Ramola 《Indian Journal of Physics》2009,83(6):887-892
Radon was measured in soil-gas and groundwater in the Budhakedar area of Tehri Garhwal, India in summer and winter to obtain
the seasonal variation and its correlation with radon exhalation rate. The environmental surface gamma dose rate was also
measured in the same area. The radon exhalation rate in the soil sample collected from different geological unit of Budhakedar
area was measured using plastic track detector (LR-115 type II) technique. The variation in the radon concentration in soil-gas
was found to vary from 1098 to 31,776 Bq.m−3 with an average of 7456 Bq.m−3 in summer season and 3501 to 42883 Bq.m−3 with an average of 17148 Bq.m−3 in winter season. In groundwater, it was found to vary from 8 to 3047 Bq.l−1 with an average value 510 Bq.l−1 in summer and 26 to 2311 Bq.l−1 with an average value 433 Bq.L−1 in winter. Surface gamma dose rate in the study area varied from 32.4 to 83.6 μR.h−1 with an overall mean of 58.7 μ-R.h−1 in summer and 34.6 to 79.3 μR.h−1 with an average value 58.2 μR.h−1 in winter. Radon exhalation rate from collected soil samples was found to vary from 0.1 × 10−5 to 5.7 × 10−5 Bq.kg−1.h−1 with an average of 1.5 × 10−5 Bq.kg−1.h−1 in summer season and 1.7 × 10−5 to 9.6 × 10−5 Bq.kg−1.h−1 with an average of 5.5 × 10−5 Bq.kg−1.h−1. A weak negative correlation was observed between radon exhalation rate from soil and radon concentration in the soil. Radon
exhalation rate from the soil was also not found to be correlated with the gamma dose rate, while it shows a positive correlation
with radon concentration in water in summer season. Inter-correlations among various parameters are discussed in detail.
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Deepak Kumar Semwal Ruchi Badoni Semwal Gurjaspreet Singh 《Helvetica chimica acta》2013,96(3):520-524
The novel androstane‐type steroidal glycoside 1 was isolated from the roots of Asparagus curillus Buch .‐Ham . ex Roxb . Its structure was elucidated as (2α,3β,5α,17β)‐17‐(1‐methoxyethoxy)‐17‐methylandrostane‐2,3‐diol 3‐(β‐D ‐digitoxopyranoside) by means of chemical and advanced spectral analysis. 相似文献
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