振动谱学研究中的光谱线型函数

本文讨论了在振动谱带计算拟合处理中的光谱线型函数问题,推导出适用于单道及多道拉曼光谱仪及色散型红外谱仪谱带线型公式。通过实验及拟合计算证实了它们的适用性并讨论了可能的误差源。理论计算和实验验证结果说明:在振动谱的谱带拟合计算中,应使用根据测谱条件计算求得的谱带线型函数,以保证拟合结果的可靠性。     

Short synthesis of novel 9,11-secosterols

Starting from ergosterol two novel 9,11-secosterols with modified side chains (1a) and (1c) were synthesized via eight main transformations.     

Parameter space map of an electron cyclotron resonance plasma in acompact chamber

Ion current density measurements were made in an electron cyclotron resonance (ECR) plasma reactor for both argon and oxygen discharges. Spatial changes in the ion current density were also recorded across the reactor diameter for changes in pressure and power. These measurements revealed a minimum in the ion current density on the reactor axis. This observation has been explained as a consequence of the shape of the ECR region, which, in turn, is dependent on the mode of coupling. Current density measurements were made as a function of reactor pressure and microwave power for two different axial locations in the system. A Langmuir probe was also used at these two locations to measure the electron temperature as a function of these process conditions. It was observed that the ion current density and/or plasma density measured downstream from the ECR zone, increased significantly in the low-pressure/high-microwave power region. Results from this region of the operating parameter space have not previously been reported. Further existing models do not predict this observed increase in plasma density or ion current density. It has been proposed that a rarefication of the gas in the ECR region, as a result of gas heating, has acted to increase the outward diffusion of electrons from the ECR zone and, thus, has increased the ambipolar diffusion of ions to the downstream location. This proposal has been partially validated by experimental results in which the ion energy was measured as a function of reactor pressure and gas flow rate. The shape of the oxygen parameter space map differs significantly from that for Ar. The principal reasons for these changes are a number of different inelastic electron scattering mechanisms which effect the transport electrons out of the ECR zone and through ambipolar diffusion also the transport of ions. The second factor is the production of negative ionic species which varies with reactor pressure and, thus, T_e     

Automated preparative HPLC of prostanoids

Summary The separation of prostaglandins (PG) PGE₁, PGE₂, PGF_1α , PGF_2α and PGF_2β on Silasorb 600 columns with a water-containing mobile phases is described. A flexible, automated, preparative liquid-chromatographic (PLC) system has been used involving column switching, column temperature control, solvent selection and automated fraction collection.     

Solvent selectivity in the resolution of some regioisomeric and diastereomeric prostaglandin intermediates on silica

The possibilities of predicting the selectivity in the resolution of regioisomeric and diastereomeric prostaglandin intermediates on silica gel was investigated. A satisfactory correlation between log alpha and the solvent localization parameters m and m0 was obtained, confirming the importance of solvent-solute localization in determining alpha values. The results will be useful in developing further the theory of the selectivity of resolution.     

Copper (II) Bromide Utilization in the Synthesis of 15-Keto-PGB1 and its 16, 16-Dimethyl Analog

Title compounds, monomeric intermediates of biologically active prostaglandin oligomers were synthesized using cupric bromide for introduction of a double bond into the prostanoid cyclopentane ring.     

Modeling,simulation and adaptive process control of biotechnological processes in decentralized anaerobic treatment of domestic wastewater

Control in anaerobic wastewater treatment plants is difficult to achieve but necessary due to a high sensitivity to disturbances and process complexity. With the help of different mathematical tools, control strategies can be developed. Particularly, a well-defined mathematical model can be highly effective for design, assessment and optimization of treatment plants. However, applications directly in the control system of a treatment plant are hard to achieve due to model complexity and usually require specialized software and the engagement of experts in the subject. The objective of the present study was the development of less empirical methods for assessment and control of a decentralized anaerobic plant for the treatment of domestic wastewater. A lab-scale plant, which consisted of a two-stage anaerobic digestion process followed by an anaerobic ammonium oxidation (ANAMMOX) reactor for nitrogen removal, was used as object of study. Ordinary differential equation models were implemented to simulate the processes that took place in the treatment plant. With the help of the implemented models, control tools were developed. These tools include a standalone application for monitoring of the two-stage anaerobic digestion process and an ammonium estimator for the ANAMMOX reactor by means of artificial neural networks (ANNs). The procedures followed aimed to reduce the amount of experimental work required so they can be easily transferred from laboratory to full-scale conditions. (© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Recurrence properties of sequences of integers

In order to study the recurrence of sequences of integers, we investigate their L2-exactness and Θ-Hartman property (Θ being a set of rational numbers). Two classes of sequences of integers are well studied, which are return times relative to a weakly mixing system and Bernoulli random sequences.