Application of a Laplace Transform Method to the Study of Binary Mixtures of Spherical and Rod-Like Particles for Low Intensity Levels.

A Laplace Transform (LT) method is used to improve the results obtained in a quasi-elastic scattering (QELS) experiment. This is designed to determine the characteristic parameters of a bimodal solution of spherical and rod-like macromolecules. The theoretical study and the experimental simulation are carried out for low light levels and the results show that the LT technique provides a real alternative to the second order correlation function, g⁽²⁾(τ), in QELS measurements for these particularly difficult experimental conditions.     

SPR-based Markov chain method for degree distributions of evolving networks

In this paper, we develop a stochastic process rules (SPR) based Markov chain method to calculate the degree distributions of evolving networks. This new approach overcomes two shortcomings of Shi, Chen and Liu’s use of the Markov chain method (Shi et al. 2005 [21]). In addition we show how an SPR-based Markov chain method can be effectively used to calculate degree distributions of random birth-and-death networks, which we believe to be novel. First SPR are introduced to replace traditional evolving rules (TR), making it possible to compute degree distributions in one sample space. Then the SPR-based Markov chain method is introduced and tested by using it to calculate two kinds of evolving network. Finally and most importantly, the SPR-based method is applied to the problem of calculating the degree distributions of random birth-and-death networks.     

Probability routing strategy for scale-free networks

This study proposes a probability routing strategy for improving traffic capability on scale-free networks. Compared with the shortest path routing strategy depending on central nodes largely and the efficient routing strategy avoiding hub routers as much as possible, the probability routing strategy makes use of hub routers more efficiently, transferring approximate average amount of packs of the whole network. Simulation results indicate that the probability routing strategy has the highest network capacity among the three routing strategies. This strategy provides network capacity that can be more than 30 times higher than that of the shortest path routing strategy and over 50% higher than that of the efficient routing strategy. In addition, the average routing path length of our proposed strategy is over 10% shorter than that of the efficient routing strategy and only about 10% longer than that of the shortest path routing strategy.     

A Capped Octahedral MHC6 Compound of a Platinum Group Metal

A MHC₆ complex of a platinum group metal with a capped octahedral arrangement of donor atoms around the metal center has been characterized. This osmium compound OsH{κ²‐C,C‐(PhBIm‐C₆H₄)}₃, which reacts with HBF₄ to afford the 14 e^? species [Os{κ²‐C,C‐(PhBIm‐C₆H₄)}(Ph₂BIm)₂]BF₄ stabilized by two agostic interactions, has been obtained by reaction of OsH₆(PiPr₃)₂ with N,N′‐diphenylbenzimidazolium chloride ([Ph₂BImH]Cl) in the presence of NEt₃. Its formation takes place through the C,C,C‐pincer compound OsH₂{κ³‐C,C,C‐(C₆H₄‐BIm‐C₆H₄)}(PiPr₃)₂, the dihydrogen derivative OsCl{κ²‐C,C‐(PhBIm‐C₆H₄)}(η²‐H₂)(PiPr₃)₂, and the five‐coordinate osmium(II) species OsCl{κ²‐C,C‐(PhBIm‐C₆H₄)}(PiPr₃)₂.     

Nanocrystals of CdSe Formed by the Pressure Cycle Method

CdSe nanocrystals were prepared by the pressure cycle method using the Paris-Edinburgh cell up to 7 GPa. The recovered samples are nanocrystals in the cubic phase (zinc-blende structure) and were characterized using transmission electron microscopy (TEM), electron diffraction and Raman scattering. Transmission electron micrographs shows that these nanocrystals are nearly spherical with diameters ranging from 20 to 50 nm. The Raman scattering measurement confirm the existence of CdSe nanocrystals in the cubic phase (ZB).