Synthesis and antimycobacterial activity of purine conjugates with (S)-lysine and (S)-ornithine

1. Download high-res image (115KB)
2. Download full-size image

     

Nanosized Vanadium Diboride: Synthesis,Structure, and Properties

Russian Journal of General Chemistry - X-ray diffraction, scanning electron microscopic, and X-ray photoelectron spectroscopic examinations, as well as energy dispersive X-ray and elemental...     

Transformations of peroxide ozonolysis products of terminal olefins treated with tosylhydrazide

Russian Journal of Organic Chemistry -     

Polymorphism of methyl 4‐amino‐3‐phenylisothiazole‐5‐carboxylate: an experimental and theoretical study

Being a close analogue of amflutizole, methyl 4‐amino‐3‐phenylisothiazole‐5‐carboxylate (C₁₁H₁₀N₂O₂S) was assumed to be capable of forming polymorphic structures. Noncentrosymmetric and centrosymmetric polymorphs have been obtained by crystallization from a series of more volatile solvents and from denser tetrachloromethane, respectively. Identical conformations of the molecule are found in both structures. The two polymorphs differ mainly in the intermolecular interactions formed by the amino group and in the type of stacking interactions between the π‐systems. The most effective method for revealing packing motifs in structures with intermolecular interactions of different types (hydrogen bonding, stacking, dispersion, etc.) is to study the pairwise interaction energies using quantum chemical calculations. Molecules form a column as the primary basic structural motif due to stacking interactions in both polymorphic structures under study. The character of a column (straight or zigzag) is determined by the orientations of the stacked molecules (in a `head‐to‐head' or `head‐to‐tail' manner). Columns bound by intermolecular N—H…O and N—H…N hydrogen bonds form a double column as the main structural motif in the noncentrosymmetric structure. Double columns in the noncentrosymmetric structure and columns in the centrosymmetric structure interact strongly within the ab crystallographic plane, forming a layer as a secondary basic structural motif. The noncentrosymmetric structure has a lower density and a lower (by 0.59 kJ mol^?1) lattice energy, calculated using periodic calculations, compared to the centrosymmetric structure.     

Two-Phase Filtration in a Transversally Isotropic Porous Medium: Experiment and Theory

The results of an experimental determination of the relative phase permeabilities during flow of two immiscible fluids in stratified sandstone with transversally isotropic characteristics are presented. The measurements were performed on samples oriented in three directions: along, perpendicular to and at an angle of 45° to the stratification plane. An approximate solution of the problem of steady two-phase flow toward a finite gallery in an anisotropic porous medium for arbitrary relative orientation of the gallery and the principal axes of the absolute permeability tensor is given. This solution was tested against the experimental results. The good agreement between the theoretical and experimental results makes it possible to recommend for engineering calculations both the relations between the absolute and phase permeabilities for transversally isotropic and orthotropic porous media and the approximate solution obtained.     

Noise-Immune Communication with Orthogonal Frequency Division Multiplexing Using Kravchenko Weight Function Processing

Doklady Mathematics - Signal structures based on OFDM signals and error-correcting codes resistant to the influence of spectrum-concentrated noise are described. An algorithm for receiving such...     

Elastic Properties of Lithium and Sodium Amides

Russian Physics Journal - This paper presents the optimization of the structural parameters of tetragonal and orthorhombic crystals α-LiNH2 and α-NaNH2 and computation of elastic...     

The Bergman kernel for the Vekua equation

The paper extends some well-known results for analytic functions onto solutions of the Vekua equation $\partial \overline{{}_z}W=aW+b\overline{W}$ regarding the existence and construction of the Bergman kernel and of the corresponding Bergman projection operator.     

Features of the Photovoltaic Properties of Photosemiconductive Film Composites Based on a Carbazolyl-Containing Oligomer with Azobenzene Dyes as Additives

Journal of Applied Spectroscopy - New photosensitive polymeric film composites based on oligo-N-glycidylcarbazole oligomer with azobenzene dyes as additives (azobenzene derivatives with a glycidyl...