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1.
Differential Equations - Conditions for the separation of variables in autonomous systems of general differential equations are discussed. The approach is based on Liouville’s idea of... 相似文献
2.
Zabelinsky I. E. Bikova N. G. Kozlov P. V. Levashov V. Yu. Gerasimov G. Ya. 《Journal of Applied Spectroscopy》2022,89(1):56-59
Journal of Applied Spectroscopy - The emission spectra of oxygen behind the front of a strong shock wave were studied in the range of shock wave speeds of 5.7–7.4 and 8.1–10.0 km/s at... 相似文献
3.
Impact of the Oxygen Defects and the Hydrogen Concentration on the Surface of Tetragonal and Monoclinic ZrO2 on the Reduction Rates of Stearic Acid on Ni/ZrO2 下载免费PDF全文
Sebastian Foraita Dr. John L. Fulton Zizwe A. Chase Aleksei Vjunov Pinghong Xu Dr. Eszter Baráth Dr. Donald M. Camaioni Dr. Chen Zhao Prof. Dr. Johannes A. Lercher 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(6):2423-2434
The role of the specific physicochemical properties of ZrO2 phases on Ni/ZrO2 has been explored with respect to the reduction of stearic acid. Conversion on pure m‐ZrO2 is 1.3 times more active than on t‐ZrO2, whereas Ni/m‐ZrO2 is three times more active than Ni/t‐ZrO2. Although the hydrodeoxygenation of stearic acid can be catalyzed solely by Ni, the synergistic interaction between Ni and the ZrO2 support causes the variations in the reaction rates. Adsorption of the carboxylic acid group on an oxygen vacancy of ZrO2 and the abstraction of the α‐hydrogen atom with the elimination of the oxygen atom to produce a ketene is the key to enhance the overall rate. The hydrogenated intermediate 1‐octadecanol is in turn decarbonylated to heptadecane with identical rates on all catalysts. Decarbonylation of 1‐octadecanol is concluded to be limited by the competitive adsorption of reactants and intermediate. The substantially higher adsorption of propionic acid demonstrated by IR spectroscopy and the higher reactivity to O2 exchange reactions with the more active catalyst indicate that the higher concentration of active oxygen defects on m‐ZrO2 compared to t‐ZrO2 causes the higher activity of Ni/m‐ZrO2. 相似文献
4.
Alexander V. Semakov Valery G. Kulichikhin Aleksei K. Tereshin Sergei V. Antonov Alexander Ya. Malkin 《Journal of Polymer Science.Polymer Physics》2015,53(8):559-565
Experiments with stretching moderately concentrated polymer solutions have been carried out. Model experiments were carried out for poly(acrylonitrile) solutions in dimethyl siloxane. Just the choice of concentrated solutions allowed for a clear demonstration of a demixing effect with the formation of two separate phases—an oriented polymer fiber and solvent drops sitting on its surface. An original experimental device for following all subsequent stages in the demixing process was built. It combined two light beams, one transverse to the fiber and a second directed along (inside) the fiber, the latter played the role of an optical line. This gives a unique opportunity to observe processes occurring inside a fiber. The process of demixing starts from the volume phase separation across the whole cross section of a fiber at some critical deformation and the propagation of the front of demixing along the fiber. Then a solvent cylindrical skin appears which transforms into a system of separate droplets. New experimental data are discussed based on a comparison of the current different points of view on the phenomenon of deformation‐induced phase separation: thermodynamic shift of the equilibrium phase transition temperature, growth of stress‐induced concentration fluctuations in two‐component fluids, and mechanically pressing a solvent out from a polymer network. The general belief is that a rather specific (so‐called “beads‐on‐a‐string”) structure of a filament is realized in stretching dilute solutions: beads of a polymer solution connected by oriented polymer bridges forming a single object. The situation in stretching moderately concentrated solutions appears quite different: real phase separation was observed. So, the alternative phenomenon to the formation of the “beads‐on‐a‐string” structure has been experimentally proven. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 559–565 相似文献
5.
6.
V. V. Sagaradze N. V. Kataeva V. A. Zavalishin K. A. Kozlov V. V. Makarov A. R. Kuznetsov 《哲学杂志》2020,100(14):1868-1879
ABSTRACT The authors present the results of an investigation in Fe–Ni-Cr austenitic alloys of the low-temperature deformation-induced segregations of nickel that form in the micro regions being (i) located close to grain- and subgrain boundaries and (ii) characteristic of the concentration and magnetic inhomogeneities indicated by the appearance of a dark diffraction contrast at the electron diffraction patterns taken from these regions typical (at the same time) of an enhanced value of Curie temperature. The observed effects were connected with the micro distortions caused by the local change of lattice parameter because of an increase in nickel concentration, as well as in the result of a magnetostriction dilatation. Using methods of the X-ray energy dispersive spectroscopy (XEDS) and atomic-probe body-section radiography (tomography – APT) has made it possible to determine the borders of those regions of austenite that were characteristic of an enhanced concentration of nickel in the fields of the localisation of a deformation-induced segregation of nickel in the vicinity of grain (subgrain) boundaries of austenitic alloys of the types Fe–13Cr–30Ni and Fe–37Ni–3Ti. 相似文献
7.
Dement’eva O. V. Naumova K. A. Shishmakova E. M. Senchikhin I. N. Zhigletsova S. K. Klykova M. V. Dunaitsev I. A. Kozlov D. A. Rudoy V. M. 《Colloid Journal》2021,83(6):651-661
Colloid Journal - The features of the synthesis of SiO2 mesoporous container particles (MCPs) using a hybrid template represented by miramistin micelles with curcumin solubilized in them have been... 相似文献
8.
Mazaletskaya L. I. Sheludchenko N. I. Kozlov M. V. Shishkina L. N. 《Russian Chemical Bulletin》2019,68(10):1919-1923
Russian Chemical Bulletin - An inhibition by the semisynthetic polyphenols bearing bicyclic isobornyl substituents and OH groups arranged variously relative to each other was investigated in the... 相似文献
9.
Doklady Physics - The results of experimental investigations of the effect of distributed suction through a perforated section of a symmetric wing profile on the spatial development of disturbances... 相似文献
10.
We study the universal enveloping associative conformal algebra for the central extension of a current Lie conformal algebra at the locality level N =?3. A standard basis of defining relations for this algebra is explicitly calculated. As a corollary, we find a linear basis of the free commutative conformal algebra relative to the locality N =?3 on the generators.
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