Pd0‐Catalyzed Intramolecular α‐Arylation of Sulfones: Domino Reactions in the Synthesis of Functionalized Tetrahydroisoquinolines

A new strategy for the synthesis of tetrahydroisoquinolines based on the Pd⁰‐catalyzed intramolecular α‐arylation of sulfones is reported. The combination of this Pd‐catalyzed reaction with intermolecular Michael and aza‐Michael reactions allows the development of two‐ and three‐step domino processes to synthesize diversely functionalized scaffolds from readily available starting materials.     

Modeling of semiconductor optical amplifier RIN and phase noise for optical PSK systems

Phase modulation schemes are attracting much interest for use in ultra-fast optical communication systems because they are much less sensitive to fibre nonlinearities compared to conventional intensity modulation formats. Semiconductor optical amplifiers (SOAs) can be used to amplify and process phase modulated signals, but with a consequent addition of nonlinear phase noise (NLPN). Existing SOA NLPN models are simplistic. In this paper we show that a more accurate model can be used, which results in simple expressions for SOA nonlinear noise, in particular when used to amplify differential phase shift keyed modulated data. The model is used to calculate the optical signal to noise ratio introduced by a power booster SOA and the first inline amplifier of a 40 Gb/s NRZ-DQPSK single channel link.

     

Spatial imaging of two-dimensional electronic states in semiconductor quantum wells

We measure the spatial distribution of the local density of states (LDOS) at cleaved surfaces of InAs/GaSb isolated quantum wells and double quantum wells (DQWs) by low-temperature scanning tunneling spectroscopy. Distinct standing wave patterns of LDOS corresponding to subbands are observed. These LDOS patterns and subband energies agree remarkably well with simple calculations with tip-induced band bending. Furthermore, for the DQWs, coupling of electronic states between the quantum wells is also clearly observed.