Numerical study on K/S/Cl release during devolatilization of pulverized biomass at high temperature

In this paper, the interaction between different organic and inorganic K/S/Cl compounds in the solid structure of biomass is studied and a model is presented to predict the temporal release of K_g, HCl, CH₃Cl, KCl, KOH, K₂SO₄ and SO₂ from biomass devolatilization. Four types of pulverized biomass are chosen from literature, two of which have no chlorine content and two with chlorine content in lower stoichiometry to potassium. The results of the model are compared with the experimental measurements. In the presence of chlorine, KCl, HCl and K_g were found to be the dominant chlorine and potassium species. In the absence of chlorine, K_g dominates the release of potassium. KOH and K₂SO₄ release into the gas phase towards the end of devolatilization due to the overlapping with char combustion. SO₂ is the main sulfur species released into the gas phase. The model is coupled with a CFD solver where the gas phase chemistry of the K/S/Cl system can be studied using available chemical mechanisms for these species.     

LES study of diesel flame/wall interaction and mixing mechanisms at different wall distances

In this paper, the flame-wall interaction of reacting diesel spray under engine like conditions is investigated using large eddy simulations. The aim of this study is to understand the influence of the distance between the wall and the spray nozzle on the air entrainment rate, which is a key variable in formation/oxidation process of soot. Three experimental cases are investigated, a free jet case and two wall impingement cases with a distance from nozzle to wall of 30 mm and 50 mm, which are considered as characteristic wall impingement distances for light- and heavy-duty bores in diesel engines, respectively. The optical soot measurements imply a positive influence of wall on the rate of soot oxidation. Numerical simulations are employed to elucidate importance of different mechanisms for the air entrainment, i.e., air entrainment prior to flame lift-off position, enhanced mixing due to the wall impingement and enhanced mixing by the entrainment wave. The results show that oxidation process after the end of injection is driven by a different mixing mechanism depending on the distance to the wall. The 30 mm case resulted in a “mixing boost”, where the dominant mixing mechanism is the wall impingement vortex mixing, which gives rise to the fastest soot decay among the cases. The mixing in the 50 mm case is governed by a late wall impingement vortex mixing, giving rise to a low, but a constant air entrainment rate, i.e., a “mixing plateau”. The free jet case resulted in mixing governed by the entrainment wave mechanism. Both wall impingement cases have faster soot oxidation rate compared with the free jet case, but due to a different underlying mixing process. LES is shown to be able to replicate the line-of-sight measurements of natural OH* chemiluminescence and distribution of soot region from the optical soot diagnostics.     

Evaluation of aerodynamic performance enhancement of Risø_B1 airfoil with an optimized cavity by PIV measurement

Journal of Visualization - Airfoils are mostly inefficient in their off-design conditions. In order to improve the aerodynamic performance of airfoils in these conditions, using an optimized cavity...     

Kinked crack analysis by a hybridized boundary element/boundary collocation method

In this research a two dimensional displacement discontinuity method (which is a kind of indirect boundary element method) using higher order elements (i.e. a source element with a cubic variation of displacement discontinuities having four sub-elements) is used to obtain the displacement discontinuities along each boundary element. In this paper, three kinds of the higher order boundary elements are used: the ordinary elements, the kink elements and the special crack tip elements.The boundary collocation technique is used for the calculation of the displacement discontinuities at the center of each sub-elements. Again a special boundary collocation technique is used to treat the kinked source elements occur in the crack analysis. Considering the two source elements (each having four sub-elements) joined at a corner (kink point). The collocation points in the cubic element model which are outside of the kink point are moved to the crack kink then the displacement discontinuities on the left and right sides of the kink are calculated. The displacement discontinuities of the kink point are obtained by averaging the corresponding values of its left and right sides. The special crack tip elements are also treated by the boundary displacement collocation technique considering the singularity variation of the displacements and stresses near the crack tip. Some simple example problems are solved numerically by the proposed method. The numerical results are compared with the corresponding results obtained by the previous methods cited in the literature. This comparison shows a very good agreement between the results and verify the accuracy and validity of the proposed method.     

Quantitative analysis of cationic poly(vinyl alcohol) diffusion into the hairy structure of cellulose fiber pores: charge density effect

The diffusion of charged polymers into the pores of cellulose fibers has not yet been fully understood due to the complexity of the interaction between polymers and fibers. In this paper, the diffusion of cationic-modified poly(vinyl alcohol) (CPVA) with tailored charge densities and a relatively high molecular weight into the pores of bleached aspen high-yield pulp (via a chemi-thermomechanical pulping process) was quantitatively investigated via an adsorption analysis, charge density analysis, and solute exclusion technique (SET). The results showed that the adsorption of the low-charged CPVA was substantially higher than that of the high-charged CPVA on fibers. The surface charge density analysis confirmed that approximately 17 mg/g of the high-charged CPVA adsorbed on the outer surface and on the macropores of fibers and the remaining (23 mg/g) diffused into the pores. The SET analysis confirmed that the pore size of fibers was more significantly reduced by applying the low-charged CPVA than the high-charged one. The influencing factors for the diffusion of CPVA into the large and small pores were related to the repulsion force developed between the adsorbed polymers and approaching polymers, entropy increase, and the polymer flexibility. The Brunauer-Emmett-Teller surface area analysis showed an increase in the surface area of fibers upon CPVA adsorption. It was proposed that the diffused CPVA prevented complete fiber pore collapse during drying, which eventually increased the surface area of fibers.     

Essential normality for certain finite linear combinations of linear-fractional composition operators on the Hardy space H 2

In 1999 Nina Zorboska and in 2003 P. S.Bourdon, D. Levi, S.K.Narayan and J.H. Shapiro investigated the essentially normal composition operator ${C_\varphi }$ , when φ is a linear-fractional self-map of D. In this paper first, we investigate the essential normality problem for the operator T _w ${C_\varphi }$ on the Hardy space H ², where w is a bounded measurable function on ?D which is continuous at each point of F(φ), φ ∈ S(2), and T _w is the Toeplitz operator with symbol w. Then we use these results and characterize the essentially normal finite linear combinations of certain linear-fractional composition operators on H ².     

Fracture analyses of different pre-holed concrete specimens under compression

Crack propagation processes in specially prepared concrete discs and rectangular specimens containing a single cylindrical hole or multiple holes of varying diameters have been studied both experimentally and numerically.In this research, the cracks coalescence paths in Brazilian disc and rectangular specimens made from rock-like material containing multi-holes are investigated. These concrete specimens are specially prepared from an appropriate mixture of Portland Pozzolana Cement(PPC), fine sands, and water.The pre-holed Brazilian discs and rectangular specimens are experimentally tested under compression. The breakage load in the ring type disc specimens containing an axial hole with varying diameters is measured and the distribution of the induced lateral stress is obtained. The mechanism of cracks propagation in the wall of the ring type specimens is also studied. In the case of multi-hole Brazilian disc and rectangular specimens, the cracks propagation and cracks coalescence are also investigated. These experiments are numerically modeled by a modified higher order displacement discontinuity method. It has been shown that the corresponding experimental and numerical results are in good agreement with each other. The results presented in this research validate the accuracy and applicability of these crack analyses procedures.