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Sanchez-sanz M; Blyth MG 《The Quarterly Journal of Mechanics and Applied Mathematics》2007,60(2):125-138
Unsteady, axisymmetric stagnation flow about a circular cylinderis examined when the far-field flow is a periodic function oftime with a fixed time average and an oscillatory part of prescribedamplitude and frequency. Solutions are computed for arbitraryvalues of the Reynolds number, quantifying the effects of surfacecurvature, and a frequency parameter based on the period ofthe far-field flow. It is found that solutions remain regularand periodic provided that the far-field amplitude lies belowa critical value. Above this value, solutions terminate in afinite-time singularity. The blow-up time is delayed by increasingthe curvature of the surface. These results are corroboratedby asymptotic predictions valid in the limits of small and largeamplitude and frequency. For large Reynolds number, the problemreduces to the two-dimensional stagnation-point flow againsta plane wall studied by previous authors. 相似文献
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S -nitrosothiols have many biological activities and may act as nitric oxide (NO) carriers and donors, prolonging NO half-life in vivo. In spite of their great potential as therapeutic agents, most S -nitrosothiols are too unstable to isolate. We have shown that the S -nitroso adduct of N -acetylcysteine (SNAC) can be synthesized directly in aqueous and polyethylene glycol (PEG) 400 matrix by using a reactive gaseous (NO/O2 ) mixture. Spectral monitoring of the S–N bond cleavage showed that SNAC, synthesized by this method, is relatively stable in nonbuf-fered aqueous solution at 25°C in the dark and that its stability is greatly increased in PEG matrix, resulting in a 28-fold decrease in its initial rate of thermal decomposition. Irradiation with UV light (λ= 333 nm) accelerated the rate of decomposition of SNAC to NO in both matrices, indicating that SNAC may find use for the photogeneration of NO. The quantum yield for SNAC decomposition decreased from 0.65 ± 0.15 in aqueous solution to 0.047 ± 0.005 in PEG 400 matrix. This increased stability in PEG matrix was assigned to a cage effect promoted by the PEG microenvironment that increases the rate of geminated radical pair recombination in the homolytic S–N bond cleavage process. This effect allowed for the storage of SNAC in PEG at −20°C in the dark for more than 10 weeks with negligible decomposition. Such stabilization may represent a viable option for the synthesis, storage and handling of S -nitrosothiol solutions for biomedical applications. 相似文献
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Haas P Hempstead M Jensen T Kagan H Kass R Behrends S Gentile T Guida JM Guida JA Morrow F Poling R Rosenfeld C Thorndike EH Tipton P Besson D Green J Namjoshi R Sannes F Skubic P Stone R Bortoletto D Chen A Goldberg M Horwitz N Jawahery A Lubrano P Moneti GC Trahern CG van Hecke H Csorna SE Garren L Mestayer MD Panvini RS Word GB Yi X Alam MS Bean A Ferguson T Avery P Bebek C Berkelman K Blucher E Cassel DG Copie T DeSalvo R DeWire JW Ehrlich R Galik RS Gilchriese MG Gittelman B Gray SW 《Physical review letters》1985,55(12):1248-1251
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马丽娜 《纯粹数学与应用数学》2007,23(4):549-555
通过构造两个非负鞅证明了一个强极限定理,然后把它应用到本文所定义的广义Bethe树上的奇偶马尔可夫链场上,从而获得了此马氏链场上的一类强极限定理. 相似文献
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Bean A Bobbink GJ Brock IC Engler A Ferguson T Kraemer RW Rippich C Vogel H Bebek C Berkelman K Blucher E Cassel DG Copie T DeSalvo R DeWire JW Ehrlich R Galik RS Gilchriese MG Gittelman B Gray SW Halling AM Hartill DL Heltsley BK Holzner S Ito M Kandaswamy J Kowalewski R Kreinick DL Kubota Y Mistry NB Mueller J Namjoshi R Nordberg E Ogg M Perticone D Peterson D Pisharody M Read K Riley D Silverman A Stone S Yi X Sadoff AJ Avery P Besson D Bowcock T Giles RT Hassard J Kinoshita K Pipkin FM 《Physical review letters》1987,58(3):183-186
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Csorna SE Garren L Mestayer MD Panvini RS Yi X Alam MS Avery P Bebek C Berkelman K Cassel DG Copie T DeSalvo R DeWire JW Ehrlich R Ferguson T Galik R Gilchriese MG Gittelman B Halling M Hartill DL Holzner S Ito M Kadaswamy J Kreinick DL Kubota Y Mistry NB Nordberg E Ogg M Peterson D Perticone D Read K Silverman A Stein PC Stone S Kezun X Sadoff AJ Giles RT Hassard J Hempstead M Kinoshita K McKay WW Pipkin FM Wilson R Haas P Jensen T Kagan H Kass R Behrends S Gentile T Guida JM Guida JA Morrow F 《Physical review letters》1985,54(17):1894-1897
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Csorna SE Mestayer MD Panvini RS Word GB Yi X Bean A Bobbink GJ Brock I Engler A Ferguson T Kraemer R Rippich C Sutton R Vogel H Bebek C Berkelman K Blucher E Cassel DG Copie T DeSalvo R DeWire JW Ehrlich R Galik RS Gilchriese MG Gittelman B Gray SW Halling AM Hartill DL Heltsley BK Holzner S Ito M Kandaswamy J Kowalewski R Kreinick DL Kubota Y Mistry NB Mueller J Nordberg E Ogg M Peterson D Perticone D Pisharody M Read K Riley D Silverman A Stein PC Stone S Sadoff AJ Avery P Besson D Bowcock T 《Physical review letters》1986,56(12):1222-1225
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Bebek C Berkelman K Blucher E Cassel DG Copie T DeSalvo R DeWire JW Ehrlich R Galik RS Gilchriese MG Gittelman B Gray SW Halling AM Hartill DL Heltsley BK Holzner S Ito M Kandaswamy J Kowalewski R Kreinick DL Kubota Y Mistry NB Mueller J Nordberg E Ogg M Peterson D Perticone D Pisharody M Read K Riley D Silverman A Stein PC Stone S Sadoff AJ Avery P Besson D Bowcock T Giles RT Hassard J Kinoshita K Pipkin FM Wilson R Haas P Hempstead M Jensen T Kagan H Kass R Behrends S Gentile T Guida JM 《Physical review letters》1986,56(18):1893-1896
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Conway GD Borba DN Alper B Bartlett DV Gormezano C von Hellermann MG Maas AC Parail VV Smeulders P Zastrow KD 《Physical review letters》2000,84(7):1463-1466
Correlation of density turbulence suppression and reduced plasma transport is observed in the internal transport barrier (ITB) region of JET tokamak discharges with optimized magnetic shear. The suppression occurs in two stages. First, low frequency turbulence and ion transport are reduced across the plasma core by a toroidal velocity shear generated by intense auxiliary heating. Then with the ITB formation, high frequency turbulence and electron transport are reduced locally within the steep pressure gradient region of the ITB. 相似文献