Soil–water retention curve (SRWC), also called soil moisture characteristic, is used for simulation models of soil water storage or soil aggregate stability. The present study addresses the modeling of SRWC with particular attention paid to hysteresis effects of water filling and draining the pores attributed to ink-bottle effects. For that purpose, an idealized pore size distribution previously developed for predicting water sorption isotherms on cementitious materials, and which can consider the double porosity structure of soils, is used. The input data of the model are assessed only from mercury intrusion porosimetry tests (MIP) and from grain size distribution (GSD). The hysteretic behavior of SRWC is reproduced in a satisfactory way. The model can also predict the specific surface area.
In the last decade, catalytic chemical vapor deposition (CVD) has been intensively explored for the growth of single-layer graphene (SLG). Despite the scattering of guidelines and procedures, variables such as the surface texture/chemistry of catalyst metal foils, carbon feedstock, and growth process parameters have been well-scrutinized. Still, questions remain on how best to standardize the growth procedure. The possible correlation of procedures between different CVD setups is an example. Here, two thermal CVD reactors were explored to grow graphene on Cu foil. The design of these setups was entirely distinct, one being a “showerhead” cold-wall type, whereas the other represented the popular “tubular” hot-wall type. Upon standardizing the Cu foil surface, it was possible to develop a procedure for cm2-scale SLG growth that differed only by the carrier gas flow rate used in the two reactors. 相似文献
This study investigated thermodynamic properties of uranium–titanium alloy to determine its suitability for storage of hydrogen isotopes. The enthalpy increments of U2Ti were measured using a high temperature inverse drop calorimeter in the temperature range of 299–1,169 K. Temperature dependence of the molar enthalpy increment and molar heat capacity is expressed in the form $ H^\circ_{\text{m}} (T) - H^\circ_{\text{m}} (298.15\,{\text{K}})({\text{J }}\,{\text{mol}}^{ - 1} ) = 23.236(T/{\text{K}}) + 53.292 \times 10^{ - 3} (T/{\text{K}})^{2} - 21.294 \times 10^{5} ({\text{K}}/T) - 4523 $ and $ C^\circ_{\text{p,m}} ({\text{J}}\,{\text{K}}^{ - 1} \,{\text{g}}^{ - 1} ) = 23.236 + 10.6584 \times 10^{ - 2} (T/{\text{K}}) + 21.294 \times 10^{5} ({\text{K}}/T)^{2} (300 \le T/{\text{K}} \le 900) $, respectively. A set of self consistent thermodynamic functions such as entropy, Gibbs energy function, heat capacity, and Gibbs energy and enthalpy values for U2Ti have been computed using data obtained in this study and required data from the literature. 相似文献
Structural Chemistry - The hydrogen-bonded complexes formed between proline and amides have been investigated completely by the use of computational methods such as Atoms In Molecules (AIM),... 相似文献
An unprecedented conversion of thioalkyl/aryl glycoside to the corresponding 1‐O‐acetates has been described using acetic anhydride and HClO4‐SiO2 at rt. Although this transformation does not play an important role in the oligosaccharide synthesis in comparison to its reverse transformation, this gives useful information in selecting the reaction condition for the synthesis of oligosaccharides. The yields were excellent in all cases. 相似文献
Condition monitoring is implementation of the advanced diagnostic
techniques to reduce downtime and to increase the efficiency and reliability.
The research is for determining the usage of advanced techniques like Vibration
analysis, Oil analysis and Thermography to diagnose ensuing problems of the
Plant and Machinery at an early stage and plan to take corrective and preventive
actions to eliminate the forthcoming breakdown and enhancing the reliability of
the system. Nowadays, the most of the industries have adopted the condition
monitoring techniques as a part of support system to the basic maintenance strategies.
Major condition monitoring technique they follow is Vibration Spectrum
Analysis, which can detect faults at a very early stage. However implementation
of other techniques like Oil analysis or Ferrography, Thermography etc. can
further enhance the data interpretation as they would detect the source of abnormality
at much early stage thus providing us with a longer lead time to plan and take
the corrective actions. In Large Captive Power Plants and Aluminium Smelters,
Integrated Condition Monitoring techniques play an important role as stoppage
of primary system and its auxiliaries (boiler, steam turbine, generator, coal and
ash handling plants etc.) results into the stoppage of the entire plant, which in turn
leads to loss of productivity. From economical and operational point of view, it is
desirable to ensure optimum level of system availability. 相似文献
The effects of CuO loading, reaction temperature, and surface gas velocity (Ug) on the photocatalytic reduction of NO have been determined in an annular flow type and a modified two-dimensional fluidized bed photoreactor. The optimum CuO loading was found to be 3.3 wt.% and NO degradation conversion in the modified two-dimensional fluidized bed photoreactor is more than 70% at 2.5 Umf. 相似文献
The concepts of differentiability, convexity, generalized convexity and minimization of a fuzzy mapping are known in the literature. The purpose of this present paper is to extend and generalize these concepts to fuzzy mappings of several variables using Buckley–Feuring approach for fuzzy differentiation and derive Karush–Kuhn–Tucker condition for the constrained fuzzy minimization problem. 相似文献
The Mobil Composition of Matter No. 41 (MCM-41) containing Cu and Al with Si/Al ratios varying from 100 to 10 and 1 to 6 wt.% of Cu was synthesized under hydrothermal and impregnation conditions, respectively. The samples were characterized by nitrogen adsorption–desorption measurements, X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), UV–Vis diffuse reflectance spectroscopy (UV–Vis DRS), temperature-programmed reduction (TPR), temperature-programmed desorption (TPD), and 29Si and 27Al magic-angle spinning–nuclear magnetic resonance (MAS–NMR) spectra. X-ray diffraction patterns indicate that the modified materials retain the standard MCM-41 structure. TPR patterns show the two-step reduction of Cu species. TPD study shows that Cu-impregnated Al-MCM-41 samples are more acidic than Al-MCM-41. From the MAS–NMR it was confirmed that most of the Al atoms are present tetrahedrally within the framework and some are present octahedrally in extraframework position. Impregnation of Cu shifted Al to the extraframework position. The catalytic activity of the samples toward hydroxylation of phenol in aqueous medium was evaluated using H2O2 as the oxidant at 80 °C. The effects of reaction parameters such as temperature, catalyst amount, amount of H2O2, and solvent were also investigated. Sample containing 4 wt.% copper-loaded Al-MCM-41-100 showed high phenol conversion (78%) with 68% catechol and 32% hydroquinone selectivity. 相似文献
Using a standard high-temperature solid-state reaction technique, polycrystalline samples of (Bi1?x, Nax) (Fe1?x, Tax) O3 (x = 0.0, 0.5) were prepared. The formation of the desired materials was confirmed by X-ray diffraction. The surface texture of the prepared materials recorded by scanning electron microscope exhibits a uniform grain distribution with small voids suggesting the formation of high-density pellet samples. The impedance and dielectric properties of the materials were investigated as a function of temperature and frequency. The relative dielectric constant and loss tangent of BiFeO3 decrease on addition of NaTaO3 (x = 0.5). The effect of addition of NaTaO3 on grain and grain boundary contributions in the resistive and capacitive components of BiFeO3 was studied using complex impedance spectroscopy. The value of activation energy due to both grain and grain boundary of both the samples is nearly same. The nature of variation of dc conductivity confirms the Arrhenius behavior of the materials. Study of frequency dependence of ac conductivity suggests that the materials obey Jonscher’s universal power law and the presence of ionic conductivity. 相似文献