Extended breakdown of Simpleman approximation

In this letter, we solve three-dimensional time-dependent Newton equations for atoms interacting with a ten-cycle elliptically polarized laser pulse. The ionized electron momentum distributions show a tilt angle between the distribution density peak and the main polarization axis. The tilt angle’s behavior changes with an increasing laser intensity. We show that this behavior change is directly related to the release time of the electron from the atom.     

Schmidt analysis of pure-state entanglement

We examine the application of Schmidt mode analysis to pure-state entanglement. Several examples permitting exact analytic calculation of Schmidt eigenvalues and eigenfunctions are included, as well as evaluation of the associated degree of entanglement.     

Dynamical theory of an atom with two or three levels interacting with quantized cavity fields

We review the dynamical interaction of an atom with radiation in the framework of models of the Jaynes-Cummings type. The atom is restricted to a few energy levels and the radiation consists of quantized near-resonant loss-free modes. A general formalism is presented that allows a compact discussion of atom and field dynamics without approximations. Quantum wave packet collapse and revival phenomena, coherent trapping states, and some experimental prospects for two-level and three-level atoms are treated in detail, and some related effects are discussed more briefly.     

Localized single-photon wave functions in free space

We solve the joint open problems of photon localization and single-photon wave functions in the context of spontaneous emission from an excited atom in free space. Our wave functions are well-defined members of a discrete orthonormal function set. Both the degree and shape of the localization are controlled by entanglement mapping onto the atom wave function, even though the atom is remote from the photon.     

(Z)-3-p-tolylsulfinylacrylonitrile as a chiral dienophile: diels-alder reactions with furan and acyclic dienes

The behavior of (Z)-3-p-tolylsulfinylacrylonitrile (1) as a chiral dienophile has been evaluated from its reactions with furan and acyclic dienes. Electrostatic interactions of the cyano group with the sulfinyl one restrict the conformational mobility around the C-S bond, thus controlling the pi-facial selectivity, which is almost complete in all cases, the approach of the diene from the less-hindered face of the dienophile (that bearing the lone electron pair) in the predominant rotamer being the favored one. The regioselectivity is also completely controlled by the cyano group. Additionally, the reactivity of compound 1 as well as its endo-selectivity are both higher than those observed for the corresponding (Z)-3-sulfinylacrylates, thus proving the potential of sulfinylnitriles as chiral dienophiles.     

Immobilizing a Fluorescent Dye Offers Potential to Investigate the Glass/Resin Interface

Silane coupling agents are commonly applied to glass fibers to promote fiber/resin adhesion and enhance durability in composite parts. In this study, a coupling agent multilayer on glass was doped with trace levels of the dimethylaminonitrostilbene (DMANS) fluorophore. The fluorophore was immobilized on the glass surface by tethering the molecule to a triethoxy silane coupling agent, creating the DMANS/silane coupling agent molecule (DMSCA). DMSCA was then diluted with commonly used coupling agents and grafted to a glass microscope coverslip to create a model composite interface. A 53-nm blue shift in fluorescence from the immobilized DMSCA can be followed during cure of an epoxy resin overlayer, giving this technique potential to monitor the properties of the fiber/resin interface during composite processing. Contact angle measurements on these coupling agent layers were similar in the presence or absence of the DMSCA molecule, suggesting that trace levels of the fluorescent probe did not affect the structure of the layer. The immobilized DMSCA molecule behaved similarly to the DMANS precursor in solution. Both showed longer wavelength fluorescence in more polar environments. Copyright 2000 Academic Press.