排序方式: 共有33条查询结果,搜索用时 15 毫秒
1.
Bekzat ABDIKADYR Alp KILI Onur ALEV Serkan BÜYÜKK
SE Zafer Ziya
ZTÜRK 《Turkish Journal of Chemistry》2021,45(2):295
Pristine and WO3 decorated TiO2 nanorods (NRs) were synthesised to investigate n-n-type heterojunction gas sensing properties. TiO2 NRs were fabricated via hydrothermal method on fluorine-doped tin oxide coated glass (FTO) substrates. Then, tungsten was sputtered on the TiO2 NRs and thermally oxidised to obtain WO3 nanoparticles. The heterostructure was characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray (EDX) spectroscopy. Fabricated sensor devices were exposed to VOCs such as toluene, xylene, acetone and ethanol, and humidity at different operation temperatures. Experimental results demonstrated that the heterostructure has better sensor response toward ethanol at 200 °C. Enhanced sensing properties are attributed to the heterojunction formation by decorating TiO2 NRs with WO3. 相似文献
2.
This paper presents an algorithm for the numerical approximation of spectral projectors onto the invariant subspaces corresponding
to the eigenvalues inside, on, and outside the unit circle of a symplectic matrix. The algorithm constructs iteratively three
matrix sequences from which the projectors are obtained. The convergence depends essentially on the gap between the unit circle
and the eigenvalues inside it. A larger gap leads to faster convergence. Theoretical and algorithmic aspects of the algorithm
are developed. Numerical results are reported. 相似文献
3.
In this study, methanol extracts (MEs) and essential oil (EO) of Angelica purpurascens (Avé-Lall.) Gill obtained from different parts (root, stem, leaf, and seed) were evaluated in terms of antioxidant activity, total phenolics, compositions of phenolic compound, and essential oil with the methods of 2,2-azino-bis(3ethylbenzo-thiazoline-6-sulfonic acid (ABTS•+), 2,2-diphenyl-1-picrylhydrazil (DPPH•) radical scavenging activities, and ferric reducing/antioxidant power (FRAP), the Folin–Ciocalteu, liquid chromatography−tandem mass spectrometry (LC−MS/MS), and gas chromatography-mass spectrometry (GC−MS), respectively. The root extract of A. purpurascens exhibited the highest ABTS•+, DPPH•, and FRAP activities (IC50: 0.05 ± 0.0001 mg/mL, IC50: 0.06 ± 0.002 mg/mL, 821.04 ± 15.96 µM TEAC (Trolox equivalent antioxidant capacity), respectively). Moreover, EO of A. purpurascens root displayed DPPH• scavenging activity (IC50: 2.95 ± 0.084 mg/mL). The root extract had the highest total phenolic content (438.75 ± 16.39 GAE (gallic acid equivalent), µg/mL)). Twenty compounds were identified by LC−MS/MS. The most abundant phenolics were ferulic acid (244.39 ± 15.64 μg/g extract), benzoic acid (138.18 ± 8.84 μg/g extract), oleuropein (78.04 ± 4.99 μg/g extract), and rutin (31.21 ± 2.00 μg/g extract) in seed, stem, root, and leaf extracts, respectively. According to the GC−MS analysis, the major components were determined as α-bisabolol (22.93%), cubebol (14.39%), α-pinene (11.63%), and α-limonene (9.41%) among 29 compounds. Consequently, the MEs and EO of A. purpurascens can be used as a natural antioxidant source. 相似文献
4.
Holland CW Nielsen PL Dettmer J Dosso S 《The Journal of the Acoustical Society of America》2012,131(2):1066-1078
Seabed geoacoustic variability is driven by geological processes that occur over a wide spectrum of space-time scales. While the acoustics community has some understanding of horizontal fine-scale geoacoustic variability, less than O(10(0)) m, and large-scale variability, greater than O(10(3)) m, there is a paucity of data resolving the geoacoustic meso-scale O(10(0)-10(3)) m. Measurements of the meso-scale along an ostensibly "benign" portion of the outer shelf reveal three classes of variability. The first class was expected and is due to horizontal variability of layer thicknesses: this was the only class that could be directly tied to seismic reflection data. The second class is due to rapid changes in layer properties and/or boundaries, occurring over scales of meters to hundreds of meters. The third class was observed as rapid variations of the angle/frequency dependent reflection coefficient within a single observation and is suggestive of variability at scales of meter or less. Though generally assumed to be negligible in acoustic modeling, the second and third classes are indicative of strong horizontal geoacoustic variability within a given layer. The observations give early insight into possible effects of horizontal geoacoustic variability on long-range acoustic propagation and reverberation. 相似文献
5.
Dr. Francesco Fasano Dr. Jacopo Dosso Dr. C. Grazia Bezzu Dr. Mariolino Carta François Kerff Dr. Nicola Demitri Prof. Dr. Bao-Lian Su Prof. Dr. Davide Bonifazi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(12):4124-4133
Building on the MOF approach to prepare porous materials, herein we report the engineering of porous BN-doped materials using tricarboxylic hexaarylborazine ligands, which are laterally decorated with functional groups at the full-carbon ‘inner shell’. Whilst an open porous 3D entangled structure could be obtained from the double interpenetration of two identical metal frameworks derived from the methyl substituted borazine, the chlorine-functionalised linker undergoes formation of a porous layered 2D honeycomb structure, as shown by single-crystal X-ray diffraction analysis. In this architecture, the borazine cores are rotated by 60° in alternating layers, thus generating large rhombohedral channels running perpendicular to the planes of the networks. An analogous unsubstituted full-carbon metal framework was synthesised for comparison. The resulting MOF revealed a crystalline 3D entangled porous structure, composed by three mutually interpenetrating networks, hence denser than those obtained from the borazine linkers. Their microporosity and CO2 uptake were investigated, with the porous 3D BN-MOF entangled structure exhibiting a large apparent BET specific surface area (1091 m2 g−1) and significant CO2 reversible adsorption (3.31 mmol g−1) at 1 bar and 273 K. 相似文献
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7.
Uncertainty estimation in simultaneous Bayesian tracking and environmental inversion 总被引:1,自引:0,他引:1
This paper develops a Bayesian approach for two related inverse problems: tracking an acoustic source when ocean environmental parameters are unknown, and determining environmental parameters using acoustic data from an unknown (moving) source. The formulation considers source and environmental parameters as unknown random variables constrained by noisy acoustic data and by prior information on parameter values (e.g., physical limits for environmental properties) and on inter-parameter relationships (limits on radial and vertical source speed). The goal is not simply to estimate parameter values, but to rigorously determine parameter uncertainty distributions, thereby quantifying the information content of the data/prior to resolve source and environmental parameters. Results are presented as marginal posterior probability densities (PPDs) for environmental parameters and joint marginal PPDs for source ranges and depths. Given the numerically intensive inversion, an efficient Markov-chain Monte Carlo importance-sampling approach is developed which combines Metropolis and heat-bath Gibbs' sampling, employs efficient proposal distributions based on a linearized PPD approximation, and considers nonunity sampling temperatures to ensure a complete parameter search. The approach is illustrated with two simulated examples representing tracking a quiet submerged source and geoacoustic inversion using noise from an unknown ship of opportunity. In both cases, source, seabed, and water-column parameters are unknown. 相似文献
8.
The geoacoustic properties of marine sediments, e.g., bulk density and compressional velocity, commonly exhibit large variations in depth near the water-sediment interface. This layer, termed the transition layer, is typically of 0(10(-1)-10(0)) m in thickness. Depth variations within the transition layer may have important implications for understanding and modeling acoustic interaction with the seabed, including propagation and reverberation. In addition, the variations may contain significant clues about the underlying depositional or erosional processes. Characteristics of the transition layer can be measured directly (e.g., coring) or remotely. Remote measurements have the advantage of sampling without disturbing the sediment properties; they also have the potential to be orders of magnitude faster and less expensive than direct methods. It is shown that broadband seabed reflection data can be exploited to remotely obtain the depth dependent density and velocity profiles in the transition layer to high accuracy. A Bayesian inversion approach, which accounts for correlated data errors, provides estimates and uncertainties for the geoacoustic properties. These properties agree with direct (i.e., core) measurements within the uncertainty estimates. 相似文献
9.
Fallat MR Nielsen PL Dosso SE 《The Journal of the Acoustical Society of America》2000,107(4):1967-1977
This paper describes an acoustic experiment (PROSIM'97) carried out to investigate inversion for seabed properties at a site off the west coast of Italy where previous acoustic and geophysical studies have been performed. Acoustic fields were measured at a vertical hydrophone array due to a swept-frequency source towed over weakly range-dependent bathymetry. Based on the known geology, the seabed is modeled as a sediment layer overlying a semi-infinite basement with unknown model parameters consisting of the sediment thickness, sediment and basement sound speeds, source range and depth, water depth at the source and array, and array tilt. A hybrid inversion algorithm is applied to determine the model values that minimize the mismatch with the measured acoustic fields. Multiple data sets are analyzed to examine the consistency of the inversion results. It is found that the low sound speed of the sediment layer, together with a large uncertainty in bathymetry, leads to strong correlations between the water depths and sediment thickness. This precludes reliable estimation of these parameters individually; however, the total depth to the basement can be estimated reliably. In addition, the basement speed and geometric parameters are estimated consistently, and all parameters compare favorably with the geophysical ground-truth information and with previous inversion results. 相似文献
10.