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Rathore Vikas Tiwari Budhi Sagar Nema Sudhir Kumar 《Plasma Chemistry and Plasma Processing》2022,42(1):109-129
Plasma Chemistry and Plasma Processing - The present study has been carried to investigate the interaction and effect of plasma activated water (PAW) on pea seeds. PAW is produced with the... 相似文献
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Pritam Dolui Vikas Tiwari Parul Saini Dr. Tarak Karmakar Koushik Makhal Harshita Goel Dr. Anil J. Elias 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(43):e202200829
An efficient, metal-free, catalyst-free and solvent-free methodology for the reductive amination of levulinic acid with different anilines has been developed using HBpin as the reducing reagent. This protocol offers an excellent method to avoid solvents and added catalysts on the synthesis of different kinds of N-substituted pyrrolidones under metal free conditions. It is also the first report for the synthesis of different pyrrolidones by solvent-free as well as catalyst-free methods. The proposed mechanism for the formation of pyrrolidone has been supported by DFT calculations and control experiments. 相似文献
4.
Manish Kumar Bansal Devendra Kumar K. S. Nisar Jagdev Singh 《Mathematical Methods in the Applied Sciences》2020,43(8):5602-5614
In this paper, we study certain interesting and useful properties of incomplete -functions. The incomplete -function is an extension of the -function. We find several useful classical integral transforms of these functions. Further, we examine the fractional calculus with the incomplete -functions and point out several special cases. Finally, we give the applications of incomplete -functions in detecting glucose supply in human blood. 相似文献
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Heteroatom‐Guided,Palladium‐Catalyzed,Site‐Selective CH Arylation of 4H‐Chromenes: Diastereoselective Assembly of the Core Structure of Myristinin B through Dual CH Functionalization 下载免费PDF全文
Govind Goroba Pawar Virendra Kumar Tiwari Dr. Himanshu Sekhar Jena Dr. Manmohan Kapur 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(27):9905-9911
A highly site‐selective, heteroatom‐guided, palladium‐catalyzed direct arylation of 4H‐chromenes is reported. The C?H functionalization is driven not only by the substituents and structure of the substrate but also by the coupling partner being used. The diastereoselective assembly of the core structure of Myristinin B has been achieved by using a dual C?H functionalization strategy for regioselective direct arylation. 相似文献
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Shyam Sundar Mondal Namita Jaiswal Partha Sarathi Bera Ranjay K. Tiwari Jogendra Nath Behera Nripen Chanda Subhas Ghosal Tanmoy Kumar Saha 《应用有机金属化学》2021,35(1)
A series of copper (II) ( 1 and 3 ) and cobalt (II/III) ( 2 , 4 and 5 ) complexes comprising different imino‐phenolate ligands DCH , DTH and DBH 2 (where DCH = 2,4‐dichloro‐6‐((mesitylimino)methyl)phenol, DTH = 2,4‐di‐tert‐butyl‐6‐((mesitylimino)methyl) phenol and DBH 2 = 2,4‐dibromo‐6‐((mesitylimino)methyl)phenol) have been prepared with excellent yield and high purity. By utilizing different spectroscopic tools such as UV–visible, electrospray ionization (ESI)‐mass, Fourier‐transform infrared (FTIR) spectrometry and elemental analysis, the prepared complexes ( 1 – 5 ) were thoroughly characterized. The molecular structure of the synthesized complexes was ascertained by using single‐crystal X‐ray diffraction studies (SCXRDs). The experiment reveals that Complexes 1 – 5 bind to calf thymus DNA (CT‐DNA) through non‐intercalative way with good interacting abilities. However, 1 – 5 are excellent quenchers of the fluorescence intensity of bovine serum albumin (BSA) following the static pathway. Additionally, they had shown remarkable cytotoxic potential against MCF‐7 (mammary gland adenocarcinoma) and A549 (lung adenocarcinoma) cell lines. The IC50 values associated with these complexes were much lower than the conventional drug cisplatin. Apoptosis‐induced cell death was confirmed from the DNA fragmentation studies and Hoechst 33342 staining. The 2′,7′‐dichlorofluorescein diacetate (DCFDA) assay indicates that the complex mediated reactive oxygen species (ROS) generation is accountable for governing the apoptosis mechanism via oxidative cell distress. Apart from these studies, by carrying out density functional theory (DFT) method, highest occupied molecular orbital–lowest unoccupied molecular orbital (HOMO–LUMO) energy gap calculations and optimized structures of the synthesized complexes were accomplished. 相似文献
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Shovon Chatterjee Pritam Dey Nilimesh Das Khushubo Tiwari Dr. Tanmoy Maiti Prof. Pratik Sen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(7):1506-1510
An ultra-slow crystal growth over a period of 24 h of a newly synthesized CH3NH3Pb1/2Bi1/3I3 perovskite (MPBI) nanocrystal in non-polar toluene medium is reported here. From several spectroscopic techniques as well as from TEM analysis we found that the size of nanocrystals changes continuously with time, in spite of being capped by the ligands. Using a single molecular spectroscopic technique, we also found that this size change is not due to the stacking of nanocrystals but due to crystal growth. The notable temperature dependence and reversible nature of the nanocrystals growth is explained by the dynamic nature of the capping. The observed temperature-dependent ultra-slow growth is believed to be a pragmatic step towards controlling the size of perovskite NC in a systematic manner. 相似文献
9.
Devendra Kumar Jagdev Singh Dumitru Baleanu 《Mathematical Methods in the Applied Sciences》2020,43(1):443-457
The present article deals with a fractional extension of the vibration equation for very large membranes with distinct special cases. The fractional derivative is considered in Atangana-Baleanu sense. A numerical algorithm based on homotopic technique is employed to examine the fractional vibration equation. The stability analysis is conducted for the suggested scheme. The maple software package is utilized for numerical simulation. In order to illustrate the effects of space, time, and order of Atangana-Baleanu derivative on the displacement, the outcomes of this study are demonstrated graphically. The results revel that the Atangana-Baleanu fractional derivative is very efficient in describing vibrations in large membranes. 相似文献
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Yadav Devendra Kumar Ritesh Tiwary Badyanath Singh Pawan Kumar 《Journal of Thermal Analysis and Calorimetry》2021,143(2):1003-1019
Journal of Thermal Analysis and Calorimetry - In the present work, the rheological behaviour of three different categories of nanofluid samples, 25 nm CeO2/EG, 13 nm Al2O3/EG and... 相似文献