Structuring of a plasma shell expanding into a magnetized plasma atsub-Alfvenic speed

The structuring of plasma shells expanding into a magnetized plasma at velocities less than the Alfven speed is considered. The structuring phenomenon is studied with hybrid simulations. The hybrid simulations are conducted for two characteristic parameter sets: one set representative of magnetized ion experiments and one set representative of unmagnetized ion experiment. A complementary theoretical study of structuring instabilities using nonlocal, two fluid theory is discussed. Under the conditions representative of the laser-target experiments, the simulation observed structuring with azimuthal wavelengths similar to those observed in the experiment. Fluid theory, on the other hand, predicts that the most rapidly growing azimuthal modes are much shorter than observations, a result consistent with previous theoretical analyses     

Characterisation and optimisation of an immunoprobe for triazines

The characterisation and optimisation of an optical immunoassay with label free detection based on Reflectometric Interference Spectroscopy (RIfS) is presented. The immunoprobe is operated in a sequential scheme, where Fab-fragments react with analyte molecules in a first step. In a second step the optical transducer is used to quantify the amount of unoccupied Fab- fragments in the reaction mixture binding to the hapten-modified transducer surface. For optimisation of the test, the Fab-fragment concentration was varied between 2x10(-8) mol/l and 2.5x 10(-9) mol/l. Down to a concentration of 5x10(-9) mol/l a reduction in the limit of detection has been observed. At the lowest concentration investigated no further improvement has been found due to a reduced binding of the analyte and a strong decrease of antibody binding at the transducer surface. This finding could be explained by the thermodynamics of the antigen-antibody reaction and the performance of the optical transducer used. The limit of detection obtained is discussed with respect to thermodynamics, transducer characteristics and immunoprobe test format.     

Single crystal EPR studies of the reduced active site of [NiFe] hydrogenase from Desulfovibrio vulgaris Miyazaki F

In the catalytic cycle of [NiFe] hydrogenase the paramagnetic Ni-C intermediate is of key importance, since it is believed to carry the substrate hydrogen, albeit in a yet unknown geometry. Upon illumination at low temperatures, Ni-C is converted to the so-called Ni-L state with markedly different spectroscopic parameters. It is suspected that Ni-L has lost the "substrate hydrogen". In this work, both paramagnetic states have been generated in single crystals obtained from the [NiFe] hydrogenase from Desulfovibrio vulgaris Miyazaki F. Evaluation of the orientation dependent spectra yielded the magnitudes of the g tensors and their orientations in the crystal axes system for both Ni-C and Ni-L. The g tensors could further be related to the atomic structure by comparison with the X-ray crystallographic structure of the reduced enzyme. Although the g tensor magnitudes of Ni-C and Ni-L are quite different, the orientations of the resulting g tensors are very similar but differ from those obtained earlier for Ni-A and Ni-B (Trofanchuk et al. J. Biol. Inorg. Chem. 2000, 5, 36-44). The g tensors were also calculated by density functional theory (DFT) methods using various structural models of the active site. The calculated g tensor of Ni-C is, concerning magnitudes and orientation, in good agreement with the experimental one for a formal Ni(III) oxidation state with a hydride (H(-)) bridge between the Ni and the Fe atom. Satisfying agreement is obtained for the Ni-L state when a formal Ni(I) oxidation state is assumed for this species with a proton (H(+)) removed from the bridge between the nickel and the iron atom.     

On the difference in material structure and fatigue properties of nylon specimens produced by injection molding and selective laser sintering

This paper describes the influence of dynamic tension/compression loading on notched and unnotched nylon specimens fabricated by Injection Molding (IM) and Selective Laser Sintering (SLS). The main objective of this work is to analyze and describe the differences in material structure and fatigue properties of as-built nylon parts produced by IM and SLM from the same polyamide 12 powder. The differences in dimensional quality, density, surface roughness, crystal structure and crystallinity are systematically measured and linked to the mechanical fatigue properties. The fatigue properties of the unnotched SLS specimens are found to be equal to those of the unnotched IM specimens. The presence of pores in the sintered samples does not lead to rapid failure, and the microvoid coalescence failure mechanism is delayed. The notched specimens show more brittle failure and increased fatigue resistance which is caused by local notch-strengthening. The results enable improved understanding of the difference in material structure and fatigue behavior of selective laser sintered and injection molded polyamide.     

Pulsed electron-electron double resonance on multinuclear metal clusters: assignment of spin projection factors based on the dipolar interaction

The interaction between two paramagnetic metal centers, a [3Fe-4S](+) cluster and a [NiFe] center, is investigated in the hydrogenase from Desulfovibrio vulgaris Miyazaki F by pulsed ELDOR (electron-electron double resonance). The distance between the metal centers is known from X-ray crystallography. The experimental dipolar spin-spin interaction deviates from the value expected for two point-dipoles located at the centers of the metal clusters. An extended spin-coupling model accounting for the spin coupling in the [3Fe-4S](+) cluster yields the observed interaction under the assumption of a particular magnetic coupling scheme for the three Fe ions. These results demonstrate that pulsed ELDOR can be used to gain insight into the inner structure of a multinuclear metal cluster.     

Lifetimes andg J factors of 6s7p and 5d6p levels of Ba I

Excited states of Ba have been investigated with optical double resonance and Hanle effect. The followingg _J factors and natural lifetimes (in 10^?9 sec) have been measured $$\begin{gathered} 6s7p\left\{ {\begin{array}{*{20}c} {^1 P_1 :g_J = 1.003(2)\tau = 13.5(6)} \\ {^3 P_1 :g_J = 1.4971(8)\tau = 85.0(8.0)} \\ \end{array} } \right. \hfill \\ 5d6p\left\{ {\begin{array}{*{20}c} {^1 P_1 :g_J = 1.004(2)\tau = 12.4(9)} \\ {^3 P_1 :g_J = 1.4847(15)\tau = 11.7(9)} \\ {^3 D_1 :g_J = 0.5064(3)\tau = 17.0(5).} \\ \end{array} } \right. \hfill \\ \end{gathered}$$ g _J is utilized to test the mixing coefficients of the wave functions in the intermediate coupling model. The lifetimes are converted into absolute transition probabilities for all the decays originating from the states investigated under the assumption that their branching ratios obtained elsewhere are correct. This assumption is not unquestionable, however.     

On Soccer Balls and Linearized Inverse Statistical Mechanics

The classical inverse statistical mechanics question involves inferring properties of pairwise interaction potentials from exhibited ground states. For patterns that concentrate near a sphere, the ground states can range from platonic solids for small numbers of particles to large systems of particles exhibiting very complex structures. In this setting, previous work (von Brecht et?al., Math. Models Methods Appl. Sci. 22, 2012) allows us to infer that the linear instabilities of the pairwise potential accurately characterize the resulting nonlinear ground states. Potentials with a small number of spherical harmonic instabilities may produce very complex patterns as a result. This leads naturally to the linearized inverse statistical mechanics question: given a finite set of unstable modes, can we construct a potential that possesses precisely these linear instabilities? If so, this would allow for the design of potentials with arbitrarily intricate spherical symmetries in the ground state. In this paper, we solve our linearized inverse problem in full, and present a wide variety of designed ground states.